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1,4-Bis(thiophen-2-yl)butane-1,4-dione
In the centrosymmetric title compound, C(12)H(10)O(2)S(2), the alkyl chains adopt a fully extended all-trans conformation with respect to the C(thiophene)—C bond. The non-H atoms of the molecule are nearly planar, with a maximum deviation of 0.063 (2) Å from the mean plane of the constituent atoms...
Autores principales: | , , |
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Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
International Union of Crystallography
2012
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3295471/ https://www.ncbi.nlm.nih.gov/pubmed/22412582 http://dx.doi.org/10.1107/S1600536812005338 |
Sumario: | In the centrosymmetric title compound, C(12)H(10)O(2)S(2), the alkyl chains adopt a fully extended all-trans conformation with respect to the C(thiophene)—C bond. The non-H atoms of the molecule are nearly planar, with a maximum deviation of 0.063 (2) Å from the mean plane of the constituent atoms. In the crystal, symmetry-related molecules are linked via pairs of C—H⋯π contacts [H–centroid distances of the thiophene units = 2.79 (9) and 2.82 (4) Å], in turn interdigitating with each other along the bc plane, thus leading to an interwoven two-dimensional network. |
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