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1-(6-Chloro-1,3-benzothiazol-2-yl)hydrazine
The asymmetric unit of the title compound, C(7)H(6)ClN(3)S, consists of two crystallographically independent molecules (A and B). The dihedral angle between the benzothiazole ring system and the hydrazine group is 8.71 (6)° in molecule A and 7.16 (6)° in molecule B. The N—N—C—N and N—N—C—S torsi...
Autores principales: | , , , , |
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Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
International Union of Crystallography
2012
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3295472/ https://www.ncbi.nlm.nih.gov/pubmed/22412583 http://dx.doi.org/10.1107/S1600536812005442 |
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author | Fun, Hoong-Kun Ooi, Chin Wei Sarojini, B. K. Mohan, B. J. Narayana, B. |
author_facet | Fun, Hoong-Kun Ooi, Chin Wei Sarojini, B. K. Mohan, B. J. Narayana, B. |
author_sort | Fun, Hoong-Kun |
collection | PubMed |
description | The asymmetric unit of the title compound, C(7)H(6)ClN(3)S, consists of two crystallographically independent molecules (A and B). The dihedral angle between the benzothiazole ring system and the hydrazine group is 8.71 (6)° in molecule A and 7.16 (6)° in molecule B. The N—N—C—N and N—N—C—S torsion angles involving the hydrazine group are 170.89 (9) and −9.96 (13)°, respectively, in molecule A and 172.50 (9) and −7.43 (13)°, respectively, in molecule B. In the crystal, neighbouring molecules are connected via pairs of N—H⋯N hydrogen bonds, generating R (2) (2)(8) ring motifs, and are connected further by N—H⋯N hydrogen bonds into sheets lying parallel to the ab plane. The crystal studied was an inversion twin, the refined ratio of the twin components being 0.50 (3):0.50 (3). |
format | Online Article Text |
id | pubmed-3295472 |
institution | National Center for Biotechnology Information |
language | English |
publishDate | 2012 |
publisher | International Union of Crystallography |
record_format | MEDLINE/PubMed |
spelling | pubmed-32954722012-03-12 1-(6-Chloro-1,3-benzothiazol-2-yl)hydrazine Fun, Hoong-Kun Ooi, Chin Wei Sarojini, B. K. Mohan, B. J. Narayana, B. Acta Crystallogr Sect E Struct Rep Online Organic Papers The asymmetric unit of the title compound, C(7)H(6)ClN(3)S, consists of two crystallographically independent molecules (A and B). The dihedral angle between the benzothiazole ring system and the hydrazine group is 8.71 (6)° in molecule A and 7.16 (6)° in molecule B. The N—N—C—N and N—N—C—S torsion angles involving the hydrazine group are 170.89 (9) and −9.96 (13)°, respectively, in molecule A and 172.50 (9) and −7.43 (13)°, respectively, in molecule B. In the crystal, neighbouring molecules are connected via pairs of N—H⋯N hydrogen bonds, generating R (2) (2)(8) ring motifs, and are connected further by N—H⋯N hydrogen bonds into sheets lying parallel to the ab plane. The crystal studied was an inversion twin, the refined ratio of the twin components being 0.50 (3):0.50 (3). International Union of Crystallography 2012-02-17 /pmc/articles/PMC3295472/ /pubmed/22412583 http://dx.doi.org/10.1107/S1600536812005442 Text en © Fun et al. 2012 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
spellingShingle | Organic Papers Fun, Hoong-Kun Ooi, Chin Wei Sarojini, B. K. Mohan, B. J. Narayana, B. 1-(6-Chloro-1,3-benzothiazol-2-yl)hydrazine |
title | 1-(6-Chloro-1,3-benzothiazol-2-yl)hydrazine |
title_full | 1-(6-Chloro-1,3-benzothiazol-2-yl)hydrazine |
title_fullStr | 1-(6-Chloro-1,3-benzothiazol-2-yl)hydrazine |
title_full_unstemmed | 1-(6-Chloro-1,3-benzothiazol-2-yl)hydrazine |
title_short | 1-(6-Chloro-1,3-benzothiazol-2-yl)hydrazine |
title_sort | 1-(6-chloro-1,3-benzothiazol-2-yl)hydrazine |
topic | Organic Papers |
url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3295472/ https://www.ncbi.nlm.nih.gov/pubmed/22412583 http://dx.doi.org/10.1107/S1600536812005442 |
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