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1-(6-Chloro-1,3-benzothia­zol-2-yl)hydrazine

The asymmetric unit of the title compound, C(7)H(6)ClN(3)S, consists of two crystallographically independent mol­ecules (A and B). The dihedral angle between the benzothia­zole ring system and the hydrazine group is 8.71 (6)° in mol­ecule A and 7.16 (6)° in mol­ecule B. The N—N—C—N and N—N—C—S torsi...

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Autores principales: Fun, Hoong-Kun, Ooi, Chin Wei, Sarojini, B. K., Mohan, B. J., Narayana, B.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2012
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3295472/
https://www.ncbi.nlm.nih.gov/pubmed/22412583
http://dx.doi.org/10.1107/S1600536812005442
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author Fun, Hoong-Kun
Ooi, Chin Wei
Sarojini, B. K.
Mohan, B. J.
Narayana, B.
author_facet Fun, Hoong-Kun
Ooi, Chin Wei
Sarojini, B. K.
Mohan, B. J.
Narayana, B.
author_sort Fun, Hoong-Kun
collection PubMed
description The asymmetric unit of the title compound, C(7)H(6)ClN(3)S, consists of two crystallographically independent mol­ecules (A and B). The dihedral angle between the benzothia­zole ring system and the hydrazine group is 8.71 (6)° in mol­ecule A and 7.16 (6)° in mol­ecule B. The N—N—C—N and N—N—C—S torsion angles involving the hydrazine group are 170.89 (9) and −9.96 (13)°, respectively, in mol­ecule A and 172.50 (9) and −7.43 (13)°, respectively, in mol­ecule B. In the crystal, neighbouring mol­ecules are connected via pairs of N—H⋯N hydrogen bonds, generating R (2) (2)(8) ring motifs, and are connected further by N—H⋯N hydrogen bonds into sheets lying parallel to the ab plane. The crystal studied was an inversion twin, the refined ratio of the twin components being 0.50 (3):0.50 (3).
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spelling pubmed-32954722012-03-12 1-(6-Chloro-1,3-benzothia­zol-2-yl)hydrazine Fun, Hoong-Kun Ooi, Chin Wei Sarojini, B. K. Mohan, B. J. Narayana, B. Acta Crystallogr Sect E Struct Rep Online Organic Papers The asymmetric unit of the title compound, C(7)H(6)ClN(3)S, consists of two crystallographically independent mol­ecules (A and B). The dihedral angle between the benzothia­zole ring system and the hydrazine group is 8.71 (6)° in mol­ecule A and 7.16 (6)° in mol­ecule B. The N—N—C—N and N—N—C—S torsion angles involving the hydrazine group are 170.89 (9) and −9.96 (13)°, respectively, in mol­ecule A and 172.50 (9) and −7.43 (13)°, respectively, in mol­ecule B. In the crystal, neighbouring mol­ecules are connected via pairs of N—H⋯N hydrogen bonds, generating R (2) (2)(8) ring motifs, and are connected further by N—H⋯N hydrogen bonds into sheets lying parallel to the ab plane. The crystal studied was an inversion twin, the refined ratio of the twin components being 0.50 (3):0.50 (3). International Union of Crystallography 2012-02-17 /pmc/articles/PMC3295472/ /pubmed/22412583 http://dx.doi.org/10.1107/S1600536812005442 Text en © Fun et al. 2012 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Organic Papers
Fun, Hoong-Kun
Ooi, Chin Wei
Sarojini, B. K.
Mohan, B. J.
Narayana, B.
1-(6-Chloro-1,3-benzothia­zol-2-yl)hydrazine
title 1-(6-Chloro-1,3-benzothia­zol-2-yl)hydrazine
title_full 1-(6-Chloro-1,3-benzothia­zol-2-yl)hydrazine
title_fullStr 1-(6-Chloro-1,3-benzothia­zol-2-yl)hydrazine
title_full_unstemmed 1-(6-Chloro-1,3-benzothia­zol-2-yl)hydrazine
title_short 1-(6-Chloro-1,3-benzothia­zol-2-yl)hydrazine
title_sort 1-(6-chloro-1,3-benzothia­zol-2-yl)hydrazine
topic Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3295472/
https://www.ncbi.nlm.nih.gov/pubmed/22412583
http://dx.doi.org/10.1107/S1600536812005442
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