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6,6′-Dimethyl-2,2′-[1,3-diazinane-1,3-diylbis(methylene)]diphenol
In the molecule of the title compound, C(20)H(26)N(2)O(2), the 1,3-diazinane ring adopts a slightly distorted chair conformation and the hydroxybenzyl substituents occupy equatorial positions on the N atoms of the heterocyclic ring. There are two intramolecular O—H⋯N hydrogen bonds between the N...
Autores principales: | , , , , |
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Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
International Union of Crystallography
2012
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3295478/ https://www.ncbi.nlm.nih.gov/pubmed/22412589 http://dx.doi.org/10.1107/S1600536812005284 |
Sumario: | In the molecule of the title compound, C(20)H(26)N(2)O(2), the 1,3-diazinane ring adopts a slightly distorted chair conformation and the hydroxybenzyl substituents occupy equatorial positions on the N atoms of the heterocyclic ring. There are two intramolecular O—H⋯N hydrogen bonds between the N atoms of the 1,3-diazinane ring and the hydroxy groups of the aromatic rings, with an S(6) set-graph motif. However, the two observed intramolecular hydrogen-bond distances were different. Considering that both N atoms experience the same chemical environment, it is surprising to see the difference in O⋯N distances [2.6771 (14) and 2.8123 (12) Å]. The crystal structure is further stabilized by a C—H⋯π interaction. |
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