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6,6′-Dimethyl-2,2′-[1,3-diazinane-1,3-diyl­bis(methyl­ene)]diphenol

In the mol­ecule of the title compound, C(20)H(26)N(2)O(2), the 1,3-diazinane ring adopts a slightly distorted chair conformation and the hy­droxy­benzyl substituents occupy equatorial positions on the N atoms of the heterocyclic ring. There are two intra­molecular O—H⋯N hydrogen bonds between the N...

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Detalles Bibliográficos
Autores principales: Rivera, Augusto, González, Derly Marcela, Ríos-Motta, Jaime, Fejfarová, Karla, Dušek, Michal
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2012
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3295478/
https://www.ncbi.nlm.nih.gov/pubmed/22412589
http://dx.doi.org/10.1107/S1600536812005284
Descripción
Sumario:In the mol­ecule of the title compound, C(20)H(26)N(2)O(2), the 1,3-diazinane ring adopts a slightly distorted chair conformation and the hy­droxy­benzyl substituents occupy equatorial positions on the N atoms of the heterocyclic ring. There are two intra­molecular O—H⋯N hydrogen bonds between the N atoms of the 1,3-diazinane ring and the hy­droxy groups of the aromatic rings, with an S(6) set-graph motif. However, the two observed intra­molecular hydrogen-bond distances were different. Considering that both N atoms experience the same chemical environment, it is surprising to see the difference in O⋯N distances [2.6771 (14) and 2.8123 (12) Å]. The crystal structure is further stabilized by a C—H⋯π interaction.