(E)-2-Chloro-N′-(4-hy­droxy­benzyl­idene)­benzohydrazide

The title hydrazone mol­ecule, C(14)H(11)ClN(2)O(2), has a trans conformation with respect to the methyl­idene unit. The dihedral angle between the two benzene rings is 37.6 (3)°. In the crystal, the presence of O—H⋯O, O—H⋯N and N—H⋯O hydrogen bonds leads to the formation of a three-dimensional netw...

Descripción completa

Detalles Bibliográficos
Autor principal: Li, Xiao-Yan
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2012
Materias:
Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3295484/
https://www.ncbi.nlm.nih.gov/pubmed/22412595
http://dx.doi.org/10.1107/S1600536812005661
_version_ 1782225588356907008
author Li, Xiao-Yan
author_facet Li, Xiao-Yan
author_sort Li, Xiao-Yan
collection PubMed
description The title hydrazone mol­ecule, C(14)H(11)ClN(2)O(2), has a trans conformation with respect to the methyl­idene unit. The dihedral angle between the two benzene rings is 37.6 (3)°. In the crystal, the presence of O—H⋯O, O—H⋯N and N—H⋯O hydrogen bonds leads to the formation of a three-dimensional network. The title compound crystallized in the chiral ortho­rhom­bic space group P2(1)2(1)2(1) and was refined as an inversion twin [Flack parameter = −0.20 (18)].
format Online
Article
Text
id pubmed-3295484
institution National Center for Biotechnology Information
language English
publishDate 2012
publisher International Union of Crystallography
record_format MEDLINE/PubMed
spelling pubmed-32954842012-03-12 (E)-2-Chloro-N′-(4-hy­droxy­benzyl­idene)­benzohydrazide Li, Xiao-Yan Acta Crystallogr Sect E Struct Rep Online Organic Papers The title hydrazone mol­ecule, C(14)H(11)ClN(2)O(2), has a trans conformation with respect to the methyl­idene unit. The dihedral angle between the two benzene rings is 37.6 (3)°. In the crystal, the presence of O—H⋯O, O—H⋯N and N—H⋯O hydrogen bonds leads to the formation of a three-dimensional network. The title compound crystallized in the chiral ortho­rhom­bic space group P2(1)2(1)2(1) and was refined as an inversion twin [Flack parameter = −0.20 (18)]. International Union of Crystallography 2012-02-17 /pmc/articles/PMC3295484/ /pubmed/22412595 http://dx.doi.org/10.1107/S1600536812005661 Text en © Xiao-Yan Li 2012 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Organic Papers
Li, Xiao-Yan
(E)-2-Chloro-N′-(4-hy­droxy­benzyl­idene)­benzohydrazide
title (E)-2-Chloro-N′-(4-hy­droxy­benzyl­idene)­benzohydrazide
title_full (E)-2-Chloro-N′-(4-hy­droxy­benzyl­idene)­benzohydrazide
title_fullStr (E)-2-Chloro-N′-(4-hy­droxy­benzyl­idene)­benzohydrazide
title_full_unstemmed (E)-2-Chloro-N′-(4-hy­droxy­benzyl­idene)­benzohydrazide
title_short (E)-2-Chloro-N′-(4-hy­droxy­benzyl­idene)­benzohydrazide
title_sort (e)-2-chloro-n′-(4-hy­droxy­benzyl­idene)­benzohydrazide
topic Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3295484/
https://www.ncbi.nlm.nih.gov/pubmed/22412595
http://dx.doi.org/10.1107/S1600536812005661
work_keys_str_mv AT lixiaoyan e2chloron4hydroxybenzylidenebenzohydrazide

Ejemplares similares