2-Chloro-N-(3-methyl­phen­yl)benzamide

In the structure of the title compound, C(14)H(12)ClNO, the ortho-Cl atom in the benzoyl ring is positioned syn to the C=O bond, while the meta-methyl group in the aniline ring is positioned anti to the N—H bond. The amide group forms dihedral angles of 60.1 (1) and 22.0 (1)°, respectively, with the...

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Autores principales: Rodrigues, Vinola Z., Gowda, B. Thimme, Vrábel, Viktor, Kožíšek, Jozef
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2012
Materias:
Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3295494/
https://www.ncbi.nlm.nih.gov/pubmed/22412605
http://dx.doi.org/10.1107/S1600536812005739
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author Rodrigues, Vinola Z.
Gowda, B. Thimme
Vrábel, Viktor
Kožíšek, Jozef
author_facet Rodrigues, Vinola Z.
Gowda, B. Thimme
Vrábel, Viktor
Kožíšek, Jozef
author_sort Rodrigues, Vinola Z.
collection PubMed
description In the structure of the title compound, C(14)H(12)ClNO, the ortho-Cl atom in the benzoyl ring is positioned syn to the C=O bond, while the meta-methyl group in the aniline ring is positioned anti to the N—H bond. The amide group forms dihedral angles of 60.1 (1) and 22.0 (1)°, respectively, with the benzoyl and aniline rings, while the angle between these rings is 38.7 (1)°. The crystal structure is stabilized by N—H⋯O hydrogen bonds, which give rise to infinite chains running along the c axis.
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spelling pubmed-32954942012-03-12 2-Chloro-N-(3-methyl­phen­yl)benzamide Rodrigues, Vinola Z. Gowda, B. Thimme Vrábel, Viktor Kožíšek, Jozef Acta Crystallogr Sect E Struct Rep Online Organic Papers In the structure of the title compound, C(14)H(12)ClNO, the ortho-Cl atom in the benzoyl ring is positioned syn to the C=O bond, while the meta-methyl group in the aniline ring is positioned anti to the N—H bond. The amide group forms dihedral angles of 60.1 (1) and 22.0 (1)°, respectively, with the benzoyl and aniline rings, while the angle between these rings is 38.7 (1)°. The crystal structure is stabilized by N—H⋯O hydrogen bonds, which give rise to infinite chains running along the c axis. International Union of Crystallography 2012-02-17 /pmc/articles/PMC3295494/ /pubmed/22412605 http://dx.doi.org/10.1107/S1600536812005739 Text en © Rodrigues et al. 2012 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Organic Papers
Rodrigues, Vinola Z.
Gowda, B. Thimme
Vrábel, Viktor
Kožíšek, Jozef
2-Chloro-N-(3-methyl­phen­yl)benzamide
title 2-Chloro-N-(3-methyl­phen­yl)benzamide
title_full 2-Chloro-N-(3-methyl­phen­yl)benzamide
title_fullStr 2-Chloro-N-(3-methyl­phen­yl)benzamide
title_full_unstemmed 2-Chloro-N-(3-methyl­phen­yl)benzamide
title_short 2-Chloro-N-(3-methyl­phen­yl)benzamide
title_sort 2-chloro-n-(3-methyl­phen­yl)benzamide
topic Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3295494/
https://www.ncbi.nlm.nih.gov/pubmed/22412605
http://dx.doi.org/10.1107/S1600536812005739
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AT vrabelviktor 2chloron3methylphenylbenzamide
AT kozisekjozef 2chloron3methylphenylbenzamide

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