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N-(2-Iodophenyl)benzenecarboximidamide
The title compound, C(13)H(11)IN(2), crystallizes with two independent molecules (A and B) in the asymmetric unit. The two aromatic rings are inclined to one another by 73.3 (2)° in molecule A, and by 74.4 (1)° in molecule B. In molecule A, the iodophenyl and the phenyl rings are inlclined to the N=...
Autores principales: | , , , |
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Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
International Union of Crystallography
2012
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3295497/ https://www.ncbi.nlm.nih.gov/pubmed/22412608 http://dx.doi.org/10.1107/S160053681200596X |
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author | Zhang, Yin-jun Wang, Dong Zhang, Hai-Liang Wang, Yu-Guang |
author_facet | Zhang, Yin-jun Wang, Dong Zhang, Hai-Liang Wang, Yu-Guang |
author_sort | Zhang, Yin-jun |
collection | PubMed |
description | The title compound, C(13)H(11)IN(2), crystallizes with two independent molecules (A and B) in the asymmetric unit. The two aromatic rings are inclined to one another by 73.3 (2)° in molecule A, and by 74.4 (1)° in molecule B. In molecule A, the iodophenyl and the phenyl rings are inlclined to the N=C—N plane by 88.0 (4) and 19.0 (4)°, respectively. In molecule B the corresponding angles are 85.0 (4) and 20.7 (4)°, respectively. In the crystal, the two molecules are not parallel but have a dihedral angle between the iodophenyl rings of 8.6 (1)°, and 44.5 (2)° between the phenyl rings. The A and B molecules are linked vvia N—H⋯N hydrogen bonds to form –A–B–A–B– chains propagating along direction [100]. |
format | Online Article Text |
id | pubmed-3295497 |
institution | National Center for Biotechnology Information |
language | English |
publishDate | 2012 |
publisher | International Union of Crystallography |
record_format | MEDLINE/PubMed |
spelling | pubmed-32954972012-03-12 N-(2-Iodophenyl)benzenecarboximidamide Zhang, Yin-jun Wang, Dong Zhang, Hai-Liang Wang, Yu-Guang Acta Crystallogr Sect E Struct Rep Online Organic Papers The title compound, C(13)H(11)IN(2), crystallizes with two independent molecules (A and B) in the asymmetric unit. The two aromatic rings are inclined to one another by 73.3 (2)° in molecule A, and by 74.4 (1)° in molecule B. In molecule A, the iodophenyl and the phenyl rings are inlclined to the N=C—N plane by 88.0 (4) and 19.0 (4)°, respectively. In molecule B the corresponding angles are 85.0 (4) and 20.7 (4)°, respectively. In the crystal, the two molecules are not parallel but have a dihedral angle between the iodophenyl rings of 8.6 (1)°, and 44.5 (2)° between the phenyl rings. The A and B molecules are linked vvia N—H⋯N hydrogen bonds to form –A–B–A–B– chains propagating along direction [100]. International Union of Crystallography 2012-02-17 /pmc/articles/PMC3295497/ /pubmed/22412608 http://dx.doi.org/10.1107/S160053681200596X Text en © Zhang et al. 2012 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
spellingShingle | Organic Papers Zhang, Yin-jun Wang, Dong Zhang, Hai-Liang Wang, Yu-Guang N-(2-Iodophenyl)benzenecarboximidamide |
title |
N-(2-Iodophenyl)benzenecarboximidamide |
title_full |
N-(2-Iodophenyl)benzenecarboximidamide |
title_fullStr |
N-(2-Iodophenyl)benzenecarboximidamide |
title_full_unstemmed |
N-(2-Iodophenyl)benzenecarboximidamide |
title_short |
N-(2-Iodophenyl)benzenecarboximidamide |
title_sort | n-(2-iodophenyl)benzenecarboximidamide |
topic | Organic Papers |
url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3295497/ https://www.ncbi.nlm.nih.gov/pubmed/22412608 http://dx.doi.org/10.1107/S160053681200596X |
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