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N-(2-Iodo­phen­yl)benzene­carbox­imid­amide

The title compound, C(13)H(11)IN(2), crystallizes with two independent molecules (A and B) in the asymmetric unit. The two aromatic rings are inclined to one another by 73.3 (2)° in molecule A, and by 74.4 (1)° in molecule B. In molecule A, the iodophenyl and the phenyl rings are inlclined to the N=...

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Detalles Bibliográficos
Autores principales: Zhang, Yin-jun, Wang, Dong, Zhang, Hai-Liang, Wang, Yu-Guang
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2012
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3295497/
https://www.ncbi.nlm.nih.gov/pubmed/22412608
http://dx.doi.org/10.1107/S160053681200596X
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author Zhang, Yin-jun
Wang, Dong
Zhang, Hai-Liang
Wang, Yu-Guang
author_facet Zhang, Yin-jun
Wang, Dong
Zhang, Hai-Liang
Wang, Yu-Guang
author_sort Zhang, Yin-jun
collection PubMed
description The title compound, C(13)H(11)IN(2), crystallizes with two independent molecules (A and B) in the asymmetric unit. The two aromatic rings are inclined to one another by 73.3 (2)° in molecule A, and by 74.4 (1)° in molecule B. In molecule A, the iodophenyl and the phenyl rings are inlclined to the N=C—N plane by 88.0 (4) and 19.0 (4)°, respectively. In molecule B the corresponding angles are 85.0 (4) and 20.7 (4)°, respectively. In the crystal, the two molecules are not parallel but have a dihedral angle between the iodophenyl rings of 8.6 (1)°, and 44.5 (2)° between the phenyl rings. The A and B molecules are linked vvia N—H⋯N hydrogen bonds to form –A–B–A–B– chains propagating along direction [100].
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spelling pubmed-32954972012-03-12 N-(2-Iodo­phen­yl)benzene­carbox­imid­amide Zhang, Yin-jun Wang, Dong Zhang, Hai-Liang Wang, Yu-Guang Acta Crystallogr Sect E Struct Rep Online Organic Papers The title compound, C(13)H(11)IN(2), crystallizes with two independent molecules (A and B) in the asymmetric unit. The two aromatic rings are inclined to one another by 73.3 (2)° in molecule A, and by 74.4 (1)° in molecule B. In molecule A, the iodophenyl and the phenyl rings are inlclined to the N=C—N plane by 88.0 (4) and 19.0 (4)°, respectively. In molecule B the corresponding angles are 85.0 (4) and 20.7 (4)°, respectively. In the crystal, the two molecules are not parallel but have a dihedral angle between the iodophenyl rings of 8.6 (1)°, and 44.5 (2)° between the phenyl rings. The A and B molecules are linked vvia N—H⋯N hydrogen bonds to form –A–B–A–B– chains propagating along direction [100]. International Union of Crystallography 2012-02-17 /pmc/articles/PMC3295497/ /pubmed/22412608 http://dx.doi.org/10.1107/S160053681200596X Text en © Zhang et al. 2012 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Organic Papers
Zhang, Yin-jun
Wang, Dong
Zhang, Hai-Liang
Wang, Yu-Guang
N-(2-Iodo­phen­yl)benzene­carbox­imid­amide
title N-(2-Iodo­phen­yl)benzene­carbox­imid­amide
title_full N-(2-Iodo­phen­yl)benzene­carbox­imid­amide
title_fullStr N-(2-Iodo­phen­yl)benzene­carbox­imid­amide
title_full_unstemmed N-(2-Iodo­phen­yl)benzene­carbox­imid­amide
title_short N-(2-Iodo­phen­yl)benzene­carbox­imid­amide
title_sort n-(2-iodo­phen­yl)benzene­carbox­imid­amide
topic Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3295497/
https://www.ncbi.nlm.nih.gov/pubmed/22412608
http://dx.doi.org/10.1107/S160053681200596X
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