Cargando…
(Z)-3-(1H-Indol-3-yl)-2-(3,4,5-trimethoxyphenyl)acrylonitrile
In the title compound, C(20)H(18)N(2)O(3), the C=C bond of the acrylonitrile group that links the indole and the 3,4,5-trimethoxyphenyl rings has Z geometry, with dihedral angles between the plane of the acrylonitrile unit and the planes of the benzene and indole ring systems of 21.96 (5) and 38.9...
Autores principales: | , , |
---|---|
Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
International Union of Crystallography
2012
|
Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3295500/ https://www.ncbi.nlm.nih.gov/pubmed/22412611 http://dx.doi.org/10.1107/S1600536812005855 |
_version_ | 1782225592083546112 |
---|---|
author | Penthala, Narsimha Reddy Parkin, Sean Crooks, Peter A. |
author_facet | Penthala, Narsimha Reddy Parkin, Sean Crooks, Peter A. |
author_sort | Penthala, Narsimha Reddy |
collection | PubMed |
description | In the title compound, C(20)H(18)N(2)O(3), the C=C bond of the acrylonitrile group that links the indole and the 3,4,5-trimethoxyphenyl rings has Z geometry, with dihedral angles between the plane of the acrylonitrile unit and the planes of the benzene and indole ring systems of 21.96 (5) and 38.94 (7)°, respectively. The acrylonitrile group is planar (r.m.s. deviation from planarity = 0.037 Å). Molecules are linked into head-to-tail chains that propagate along the b-axis direction by bifurcated N—H⋯O intermolecular hydrogen bonds, which form an R (1) (2)(5) motif between the indole NH group and the two methoxy O atoms furthest from the nitrile group. |
format | Online Article Text |
id | pubmed-3295500 |
institution | National Center for Biotechnology Information |
language | English |
publishDate | 2012 |
publisher | International Union of Crystallography |
record_format | MEDLINE/PubMed |
spelling | pubmed-32955002012-03-12 (Z)-3-(1H-Indol-3-yl)-2-(3,4,5-trimethoxyphenyl)acrylonitrile Penthala, Narsimha Reddy Parkin, Sean Crooks, Peter A. Acta Crystallogr Sect E Struct Rep Online Organic Papers In the title compound, C(20)H(18)N(2)O(3), the C=C bond of the acrylonitrile group that links the indole and the 3,4,5-trimethoxyphenyl rings has Z geometry, with dihedral angles between the plane of the acrylonitrile unit and the planes of the benzene and indole ring systems of 21.96 (5) and 38.94 (7)°, respectively. The acrylonitrile group is planar (r.m.s. deviation from planarity = 0.037 Å). Molecules are linked into head-to-tail chains that propagate along the b-axis direction by bifurcated N—H⋯O intermolecular hydrogen bonds, which form an R (1) (2)(5) motif between the indole NH group and the two methoxy O atoms furthest from the nitrile group. International Union of Crystallography 2012-02-17 /pmc/articles/PMC3295500/ /pubmed/22412611 http://dx.doi.org/10.1107/S1600536812005855 Text en © Penthala et al. 2012 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
spellingShingle | Organic Papers Penthala, Narsimha Reddy Parkin, Sean Crooks, Peter A. (Z)-3-(1H-Indol-3-yl)-2-(3,4,5-trimethoxyphenyl)acrylonitrile |
title | (Z)-3-(1H-Indol-3-yl)-2-(3,4,5-trimethoxyphenyl)acrylonitrile |
title_full | (Z)-3-(1H-Indol-3-yl)-2-(3,4,5-trimethoxyphenyl)acrylonitrile |
title_fullStr | (Z)-3-(1H-Indol-3-yl)-2-(3,4,5-trimethoxyphenyl)acrylonitrile |
title_full_unstemmed | (Z)-3-(1H-Indol-3-yl)-2-(3,4,5-trimethoxyphenyl)acrylonitrile |
title_short | (Z)-3-(1H-Indol-3-yl)-2-(3,4,5-trimethoxyphenyl)acrylonitrile |
title_sort | (z)-3-(1h-indol-3-yl)-2-(3,4,5-trimethoxyphenyl)acrylonitrile |
topic | Organic Papers |
url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3295500/ https://www.ncbi.nlm.nih.gov/pubmed/22412611 http://dx.doi.org/10.1107/S1600536812005855 |
work_keys_str_mv | AT penthalanarsimhareddy z31hindol3yl2345trimethoxyphenylacrylonitrile AT parkinsean z31hindol3yl2345trimethoxyphenylacrylonitrile AT crookspetera z31hindol3yl2345trimethoxyphenylacrylonitrile |