4-Chloro­anilinium tetra­fluoro­borate 18-crown-6 clathrate

In the title compound, C(6)H(7)ClN(+)·BF(4) (−)·C(12)H(24)O(6), the complete cation is generated by crystallographic mirror symmetry, with two C atoms and the N and Cl atoms lying on the mirror plane. The complete crown ether is also generated by mirror symmetry, as is the anion (in which the B and...

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Detalles Bibliográficos
Autores principales: Xu, Jie, Zhao, Min-Min
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2012
Materias:
Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3295507/
https://www.ncbi.nlm.nih.gov/pubmed/22412618
http://dx.doi.org/10.1107/S1600536812006216
Descripción
Sumario:In the title compound, C(6)H(7)ClN(+)·BF(4) (−)·C(12)H(24)O(6), the complete cation is generated by crystallographic mirror symmetry, with two C atoms and the N and Cl atoms lying on the mirror plane. The complete crown ether is also generated by mirror symmetry, as is the anion (in which the B and two F atoms lie on the mirror plane). The –NH(3) (+) group of the cation inserts into the crown-ether ring and forms bifurcated N—H⋯(O,O) hydrogen bonds. The H atoms of the –NH(3) (+) group were modelled as disordered across the mirror plane.

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