4-Chloro­anilinium tetra­fluoro­borate 18-crown-6 clathrate

In the title compound, C(6)H(7)ClN(+)·BF(4) (−)·C(12)H(24)O(6), the complete cation is generated by crystallographic mirror symmetry, with two C atoms and the N and Cl atoms lying on the mirror plane. The complete crown ether is also generated by mirror symmetry, as is the anion (in which the B and...

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Autores principales: Xu, Jie, Zhao, Min-Min
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2012
Materias:
Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3295507/
https://www.ncbi.nlm.nih.gov/pubmed/22412618
http://dx.doi.org/10.1107/S1600536812006216
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author Xu, Jie
Zhao, Min-Min
author_facet Xu, Jie
Zhao, Min-Min
author_sort Xu, Jie
collection PubMed
description In the title compound, C(6)H(7)ClN(+)·BF(4) (−)·C(12)H(24)O(6), the complete cation is generated by crystallographic mirror symmetry, with two C atoms and the N and Cl atoms lying on the mirror plane. The complete crown ether is also generated by mirror symmetry, as is the anion (in which the B and two F atoms lie on the mirror plane). The –NH(3) (+) group of the cation inserts into the crown-ether ring and forms bifurcated N—H⋯(O,O) hydrogen bonds. The H atoms of the –NH(3) (+) group were modelled as disordered across the mirror plane.
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spelling pubmed-32955072012-03-12 4-Chloro­anilinium tetra­fluoro­borate 18-crown-6 clathrate Xu, Jie Zhao, Min-Min Acta Crystallogr Sect E Struct Rep Online Organic Papers In the title compound, C(6)H(7)ClN(+)·BF(4) (−)·C(12)H(24)O(6), the complete cation is generated by crystallographic mirror symmetry, with two C atoms and the N and Cl atoms lying on the mirror plane. The complete crown ether is also generated by mirror symmetry, as is the anion (in which the B and two F atoms lie on the mirror plane). The –NH(3) (+) group of the cation inserts into the crown-ether ring and forms bifurcated N—H⋯(O,O) hydrogen bonds. The H atoms of the –NH(3) (+) group were modelled as disordered across the mirror plane. International Union of Crystallography 2012-02-17 /pmc/articles/PMC3295507/ /pubmed/22412618 http://dx.doi.org/10.1107/S1600536812006216 Text en © Xu and Zhao 2012 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Organic Papers
Xu, Jie
Zhao, Min-Min
4-Chloro­anilinium tetra­fluoro­borate 18-crown-6 clathrate
title 4-Chloro­anilinium tetra­fluoro­borate 18-crown-6 clathrate
title_full 4-Chloro­anilinium tetra­fluoro­borate 18-crown-6 clathrate
title_fullStr 4-Chloro­anilinium tetra­fluoro­borate 18-crown-6 clathrate
title_full_unstemmed 4-Chloro­anilinium tetra­fluoro­borate 18-crown-6 clathrate
title_short 4-Chloro­anilinium tetra­fluoro­borate 18-crown-6 clathrate
title_sort 4-chloro­anilinium tetra­fluoro­borate 18-crown-6 clathrate
topic Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3295507/
https://www.ncbi.nlm.nih.gov/pubmed/22412618
http://dx.doi.org/10.1107/S1600536812006216
work_keys_str_mv AT xujie 4chloroaniliniumtetrafluoroborate18crown6clathrate
AT zhaominmin 4chloroaniliniumtetrafluoroborate18crown6clathrate

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