2,4,5-Trichloro­anilinium perchlorate 18-crown-6 clathrate

In the title compound, C(6)H(5)Cl(3)N(+)·ClO(4) (−)·C(12)H(24)O(6), the perchlorate anion is disordered over two orientations in a 0.666 (17):0.334 (17) ratio. The ammonium group of the organic cation inserts into the crown ether ring and forms three bifurcated N—H⋯(O,O) hydrogen bonds to generate a...

Descripción completa

Detalles Bibliográficos
Autor principal: Xu, Jie
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2012
Materias:
Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3295508/
https://www.ncbi.nlm.nih.gov/pubmed/22412619
http://dx.doi.org/10.1107/S1600536812006162
_version_ 1782225593909116928
author Xu, Jie
author_facet Xu, Jie
author_sort Xu, Jie
collection PubMed
description In the title compound, C(6)H(5)Cl(3)N(+)·ClO(4) (−)·C(12)H(24)O(6), the perchlorate anion is disordered over two orientations in a 0.666 (17):0.334 (17) ratio. The ammonium group of the organic cation inserts into the crown ether ring and forms three bifurcated N—H⋯(O,O) hydrogen bonds to generate a supra­molecular complex. The macrocycle has approximate D (3d) local symmetry.
format Online
Article
Text
id pubmed-3295508
institution National Center for Biotechnology Information
language English
publishDate 2012
publisher International Union of Crystallography
record_format MEDLINE/PubMed
spelling pubmed-32955082012-03-12 2,4,5-Trichloro­anilinium perchlorate 18-crown-6 clathrate Xu, Jie Acta Crystallogr Sect E Struct Rep Online Organic Papers In the title compound, C(6)H(5)Cl(3)N(+)·ClO(4) (−)·C(12)H(24)O(6), the perchlorate anion is disordered over two orientations in a 0.666 (17):0.334 (17) ratio. The ammonium group of the organic cation inserts into the crown ether ring and forms three bifurcated N—H⋯(O,O) hydrogen bonds to generate a supra­molecular complex. The macrocycle has approximate D (3d) local symmetry. International Union of Crystallography 2012-02-17 /pmc/articles/PMC3295508/ /pubmed/22412619 http://dx.doi.org/10.1107/S1600536812006162 Text en © Jie Xu 2012 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Organic Papers
Xu, Jie
2,4,5-Trichloro­anilinium perchlorate 18-crown-6 clathrate
title 2,4,5-Trichloro­anilinium perchlorate 18-crown-6 clathrate
title_full 2,4,5-Trichloro­anilinium perchlorate 18-crown-6 clathrate
title_fullStr 2,4,5-Trichloro­anilinium perchlorate 18-crown-6 clathrate
title_full_unstemmed 2,4,5-Trichloro­anilinium perchlorate 18-crown-6 clathrate
title_short 2,4,5-Trichloro­anilinium perchlorate 18-crown-6 clathrate
title_sort 2,4,5-trichloro­anilinium perchlorate 18-crown-6 clathrate
topic Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3295508/
https://www.ncbi.nlm.nih.gov/pubmed/22412619
http://dx.doi.org/10.1107/S1600536812006162
work_keys_str_mv AT xujie 245trichloroaniliniumperchlorate18crown6clathrate

Ejemplares similares