rac-3-[(Anilino)(naphthalen-2-yl)­methyl]thian-4-one

In the title compound, C(22)H(21)NOS, the thio­pyran­one ring adopts a chair-like conformation with the substituent in the axial position. The relative configuration of the racemic compound is 3R,7S according to the numbering scheme used in this publication. In the crystal packing, centrosymmetric d...

Descripción completa

Detalles Bibliográficos
Autores principales: Harms, Klaus, Abaee, M. Saeed, Mojtahedi, Mohammad M., Mesbah, A. Wahid
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2012
Materias:
Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3295517/
https://www.ncbi.nlm.nih.gov/pubmed/22412628
http://dx.doi.org/10.1107/S1600536812005983
_version_ 1782225595990540288
author Harms, Klaus
Abaee, M. Saeed
Mojtahedi, Mohammad M.
Mesbah, A. Wahid
author_facet Harms, Klaus
Abaee, M. Saeed
Mojtahedi, Mohammad M.
Mesbah, A. Wahid
author_sort Harms, Klaus
collection PubMed
description In the title compound, C(22)H(21)NOS, the thio­pyran­one ring adopts a chair-like conformation with the substituent in the axial position. The relative configuration of the racemic compound is 3R,7S according to the numbering scheme used in this publication. In the crystal packing, centrosymmetric dimers are built up via N—H⋯O hydrogen bonds, with graph set R (2) (2)(8).
format Online
Article
Text
id pubmed-3295517
institution National Center for Biotechnology Information
language English
publishDate 2012
publisher International Union of Crystallography
record_format MEDLINE/PubMed
spelling pubmed-32955172012-03-12 rac-3-[(Anilino)(naphthalen-2-yl)­methyl]thian-4-one Harms, Klaus Abaee, M. Saeed Mojtahedi, Mohammad M. Mesbah, A. Wahid Acta Crystallogr Sect E Struct Rep Online Organic Papers In the title compound, C(22)H(21)NOS, the thio­pyran­one ring adopts a chair-like conformation with the substituent in the axial position. The relative configuration of the racemic compound is 3R,7S according to the numbering scheme used in this publication. In the crystal packing, centrosymmetric dimers are built up via N—H⋯O hydrogen bonds, with graph set R (2) (2)(8). International Union of Crystallography 2012-02-17 /pmc/articles/PMC3295517/ /pubmed/22412628 http://dx.doi.org/10.1107/S1600536812005983 Text en © Harms et al. 2012 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Organic Papers
Harms, Klaus
Abaee, M. Saeed
Mojtahedi, Mohammad M.
Mesbah, A. Wahid
rac-3-[(Anilino)(naphthalen-2-yl)­methyl]thian-4-one
title rac-3-[(Anilino)(naphthalen-2-yl)­methyl]thian-4-one
title_full rac-3-[(Anilino)(naphthalen-2-yl)­methyl]thian-4-one
title_fullStr rac-3-[(Anilino)(naphthalen-2-yl)­methyl]thian-4-one
title_full_unstemmed rac-3-[(Anilino)(naphthalen-2-yl)­methyl]thian-4-one
title_short rac-3-[(Anilino)(naphthalen-2-yl)­methyl]thian-4-one
title_sort rac-3-[(anilino)(naphthalen-2-yl)­methyl]thian-4-one
topic Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3295517/
https://www.ncbi.nlm.nih.gov/pubmed/22412628
http://dx.doi.org/10.1107/S1600536812005983
work_keys_str_mv AT harmsklaus rac3anilinonaphthalen2ylmethylthian4one
AT abaeemsaeed rac3anilinonaphthalen2ylmethylthian4one
AT mojtahedimohammadm rac3anilinonaphthalen2ylmethylthian4one
AT mesbahawahid rac3anilinonaphthalen2ylmethylthian4one

Ejemplares similares