(7aS)-(–)-Dimeth­yl(1-oxido-3-oxo-5,6,7,7a-tetra­hydro-3H-pyrrolizin-2-yl)sulfonium

In the zwitterionic title compound, C(9)H(13)NO(2)S, the pyrrolidine heterocycle adopts an envelope conformation (with the C atom in the 7-position as the flap). The negative charge is delocalized over the two carbonyl groups and the C atom connecting them. The positive charge is located on the S at...

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Detalles Bibliográficos
Autores principales: Gutiérrez-Lazcano, Leonardo, Terán, Joel L., Juárez, Jorge R., Flores-Alamo, Marcos, Mendoza, Angel
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2012
Materias:
Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3295519/
https://www.ncbi.nlm.nih.gov/pubmed/22412630
http://dx.doi.org/10.1107/S1600536812003601
Descripción
Sumario:In the zwitterionic title compound, C(9)H(13)NO(2)S, the pyrrolidine heterocycle adopts an envelope conformation (with the C atom in the 7-position as the flap). The negative charge is delocalized over the two carbonyl groups and the C atom connecting them. The positive charge is located on the S atom. Two inter­molecular C—H⋯O inter­actions are observed. The molecular geometry at the S atom is trigonal pyramidal.

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