(7aS)-(–)-Dimeth­yl(1-oxido-3-oxo-5,6,7,7a-tetra­hydro-3H-pyrrolizin-2-yl)sulfonium

In the zwitterionic title compound, C(9)H(13)NO(2)S, the pyrrolidine heterocycle adopts an envelope conformation (with the C atom in the 7-position as the flap). The negative charge is delocalized over the two carbonyl groups and the C atom connecting them. The positive charge is located on the S at...

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Autores principales: Gutiérrez-Lazcano, Leonardo, Terán, Joel L., Juárez, Jorge R., Flores-Alamo, Marcos, Mendoza, Angel
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2012
Materias:
Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3295519/
https://www.ncbi.nlm.nih.gov/pubmed/22412630
http://dx.doi.org/10.1107/S1600536812003601
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author Gutiérrez-Lazcano, Leonardo
Terán, Joel L.
Juárez, Jorge R.
Flores-Alamo, Marcos
Mendoza, Angel
author_facet Gutiérrez-Lazcano, Leonardo
Terán, Joel L.
Juárez, Jorge R.
Flores-Alamo, Marcos
Mendoza, Angel
author_sort Gutiérrez-Lazcano, Leonardo
collection PubMed
description In the zwitterionic title compound, C(9)H(13)NO(2)S, the pyrrolidine heterocycle adopts an envelope conformation (with the C atom in the 7-position as the flap). The negative charge is delocalized over the two carbonyl groups and the C atom connecting them. The positive charge is located on the S atom. Two inter­molecular C—H⋯O inter­actions are observed. The molecular geometry at the S atom is trigonal pyramidal.
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spelling pubmed-32955192012-03-12 (7aS)-(–)-Dimeth­yl(1-oxido-3-oxo-5,6,7,7a-tetra­hydro-3H-pyrrolizin-2-yl)sulfonium Gutiérrez-Lazcano, Leonardo Terán, Joel L. Juárez, Jorge R. Flores-Alamo, Marcos Mendoza, Angel Acta Crystallogr Sect E Struct Rep Online Organic Papers In the zwitterionic title compound, C(9)H(13)NO(2)S, the pyrrolidine heterocycle adopts an envelope conformation (with the C atom in the 7-position as the flap). The negative charge is delocalized over the two carbonyl groups and the C atom connecting them. The positive charge is located on the S atom. Two inter­molecular C—H⋯O inter­actions are observed. The molecular geometry at the S atom is trigonal pyramidal. International Union of Crystallography 2012-02-17 /pmc/articles/PMC3295519/ /pubmed/22412630 http://dx.doi.org/10.1107/S1600536812003601 Text en © Gutiérrez-Lazcano et al. 2012 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Organic Papers
Gutiérrez-Lazcano, Leonardo
Terán, Joel L.
Juárez, Jorge R.
Flores-Alamo, Marcos
Mendoza, Angel
(7aS)-(–)-Dimeth­yl(1-oxido-3-oxo-5,6,7,7a-tetra­hydro-3H-pyrrolizin-2-yl)sulfonium
title (7aS)-(–)-Dimeth­yl(1-oxido-3-oxo-5,6,7,7a-tetra­hydro-3H-pyrrolizin-2-yl)sulfonium
title_full (7aS)-(–)-Dimeth­yl(1-oxido-3-oxo-5,6,7,7a-tetra­hydro-3H-pyrrolizin-2-yl)sulfonium
title_fullStr (7aS)-(–)-Dimeth­yl(1-oxido-3-oxo-5,6,7,7a-tetra­hydro-3H-pyrrolizin-2-yl)sulfonium
title_full_unstemmed (7aS)-(–)-Dimeth­yl(1-oxido-3-oxo-5,6,7,7a-tetra­hydro-3H-pyrrolizin-2-yl)sulfonium
title_short (7aS)-(–)-Dimeth­yl(1-oxido-3-oxo-5,6,7,7a-tetra­hydro-3H-pyrrolizin-2-yl)sulfonium
title_sort (7as)-(–)-dimeth­yl(1-oxido-3-oxo-5,6,7,7a-tetra­hydro-3h-pyrrolizin-2-yl)sulfonium
topic Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3295519/
https://www.ncbi.nlm.nih.gov/pubmed/22412630
http://dx.doi.org/10.1107/S1600536812003601
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