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6-Meth­oxy-2-phenyl-4,4a,6,7,8,8a-hexa­hydro-2H-pyrano[3,2-d][1,3]dioxine-7,8-diyl bis­(4-methyl­benzene-1-sulfonate)

In the title α-D-glucopyran­oside derivative, C(28)H(30)O(10)S(2), each heterocyclic ring adopts a chair conformation. In the tri­substituted ring, the meth­oxy and one sulfonate group occupy axial positions, whereas the second sulfonate group occupies an axial position. The phenyl group on the othe...

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Detalles Bibliográficos
Autores principales: Wardell, James L., Tiekink, Edward R. T.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2012
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3295524/
https://www.ncbi.nlm.nih.gov/pubmed/22412635
http://dx.doi.org/10.1107/S1600536812006186
Descripción
Sumario:In the title α-D-glucopyran­oside derivative, C(28)H(30)O(10)S(2), each heterocyclic ring adopts a chair conformation. In the tri­substituted ring, the meth­oxy and one sulfonate group occupy axial positions, whereas the second sulfonate group occupies an axial position. The phenyl group on the other ring is in an equatorial position. In the crystal, supra­molecular chains propagating along [100] are formed through C—H⋯O and C—H⋯π inter­actions.