6-Meth­oxy-2-phenyl-4,4a,6,7,8,8a-hexa­hydro-2H-pyrano[3,2-d][1,3]dioxine-7,8-diyl bis­(4-methyl­benzene-1-sulfonate)

In the title α-D-glucopyran­oside derivative, C(28)H(30)O(10)S(2), each heterocyclic ring adopts a chair conformation. In the tri­substituted ring, the meth­oxy and one sulfonate group occupy axial positions, whereas the second sulfonate group occupies an axial position. The phenyl group on the othe...

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Detalles Bibliográficos
Autores principales: Wardell, James L., Tiekink, Edward R. T.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2012
Materias:
Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3295524/
https://www.ncbi.nlm.nih.gov/pubmed/22412635
http://dx.doi.org/10.1107/S1600536812006186
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author Wardell, James L.
Tiekink, Edward R. T.
author_facet Wardell, James L.
Tiekink, Edward R. T.
author_sort Wardell, James L.
collection PubMed
description In the title α-D-glucopyran­oside derivative, C(28)H(30)O(10)S(2), each heterocyclic ring adopts a chair conformation. In the tri­substituted ring, the meth­oxy and one sulfonate group occupy axial positions, whereas the second sulfonate group occupies an axial position. The phenyl group on the other ring is in an equatorial position. In the crystal, supra­molecular chains propagating along [100] are formed through C—H⋯O and C—H⋯π inter­actions.
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spelling pubmed-32955242012-03-12 6-Meth­oxy-2-phenyl-4,4a,6,7,8,8a-hexa­hydro-2H-pyrano[3,2-d][1,3]dioxine-7,8-diyl bis­(4-methyl­benzene-1-sulfonate) Wardell, James L. Tiekink, Edward R. T. Acta Crystallogr Sect E Struct Rep Online Organic Papers In the title α-D-glucopyran­oside derivative, C(28)H(30)O(10)S(2), each heterocyclic ring adopts a chair conformation. In the tri­substituted ring, the meth­oxy and one sulfonate group occupy axial positions, whereas the second sulfonate group occupies an axial position. The phenyl group on the other ring is in an equatorial position. In the crystal, supra­molecular chains propagating along [100] are formed through C—H⋯O and C—H⋯π inter­actions. International Union of Crystallography 2012-02-17 /pmc/articles/PMC3295524/ /pubmed/22412635 http://dx.doi.org/10.1107/S1600536812006186 Text en © Wardell and Tiekink 2012 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Organic Papers
Wardell, James L.
Tiekink, Edward R. T.
6-Meth­oxy-2-phenyl-4,4a,6,7,8,8a-hexa­hydro-2H-pyrano[3,2-d][1,3]dioxine-7,8-diyl bis­(4-methyl­benzene-1-sulfonate)
title 6-Meth­oxy-2-phenyl-4,4a,6,7,8,8a-hexa­hydro-2H-pyrano[3,2-d][1,3]dioxine-7,8-diyl bis­(4-methyl­benzene-1-sulfonate)
title_full 6-Meth­oxy-2-phenyl-4,4a,6,7,8,8a-hexa­hydro-2H-pyrano[3,2-d][1,3]dioxine-7,8-diyl bis­(4-methyl­benzene-1-sulfonate)
title_fullStr 6-Meth­oxy-2-phenyl-4,4a,6,7,8,8a-hexa­hydro-2H-pyrano[3,2-d][1,3]dioxine-7,8-diyl bis­(4-methyl­benzene-1-sulfonate)
title_full_unstemmed 6-Meth­oxy-2-phenyl-4,4a,6,7,8,8a-hexa­hydro-2H-pyrano[3,2-d][1,3]dioxine-7,8-diyl bis­(4-methyl­benzene-1-sulfonate)
title_short 6-Meth­oxy-2-phenyl-4,4a,6,7,8,8a-hexa­hydro-2H-pyrano[3,2-d][1,3]dioxine-7,8-diyl bis­(4-methyl­benzene-1-sulfonate)
title_sort 6-meth­oxy-2-phenyl-4,4a,6,7,8,8a-hexa­hydro-2h-pyrano[3,2-d][1,3]dioxine-7,8-diyl bis­(4-methyl­benzene-1-sulfonate)
topic Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3295524/
https://www.ncbi.nlm.nih.gov/pubmed/22412635
http://dx.doi.org/10.1107/S1600536812006186
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