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1-{2-[(4-Chloro­benzyl­idene)amino]phen­yl}-3-phenyl­thio­urea

The asymmetric unit of the title compound, C(20)H(16)ClN(3)S, contains two independent mol­ecules, A and B. In mol­ecule A, the dihedral angles between the central benzene ring and the pendant chloro­benzene and phenyl rings are 6.37 (15) and 64.79 (15)°, respectively. The corresponding values in mo...

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Detalles Bibliográficos
Autores principales: Liu, Peng-Gang, Wang, Xiao-Ning, Yang, Yong-An, Zhu, Hai-Liang
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2012
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3295530/
https://www.ncbi.nlm.nih.gov/pubmed/22412641
http://dx.doi.org/10.1107/S1600536812006228
Descripción
Sumario:The asymmetric unit of the title compound, C(20)H(16)ClN(3)S, contains two independent mol­ecules, A and B. In mol­ecule A, the dihedral angles between the central benzene ring and the pendant chloro­benzene and phenyl rings are 6.37 (15) and 64.79 (15)°, respectively. The corresponding values in mol­ecule B are 28.21 (14) and 82.11 (16)°, respectively. Each mol­ecule features an intra­molecular N—H⋯N hydrogen bond, which generates an S(5) ring. In the crystal, mol­ecules A and B form dimers, being linked by two N—H⋯S hydrogen bonds with graph-set notation R (2) (2)(8).