1-{2-[(4-Chloro­benzyl­idene)amino]phen­yl}-3-phenyl­thio­urea

The asymmetric unit of the title compound, C(20)H(16)ClN(3)S, contains two independent mol­ecules, A and B. In mol­ecule A, the dihedral angles between the central benzene ring and the pendant chloro­benzene and phenyl rings are 6.37 (15) and 64.79 (15)°, respectively. The corresponding values in mo...

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Detalles Bibliográficos
Autores principales: Liu, Peng-Gang, Wang, Xiao-Ning, Yang, Yong-An, Zhu, Hai-Liang
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2012
Materias:
Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3295530/
https://www.ncbi.nlm.nih.gov/pubmed/22412641
http://dx.doi.org/10.1107/S1600536812006228
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author Liu, Peng-Gang
Wang, Xiao-Ning
Yang, Yong-An
Zhu, Hai-Liang
author_facet Liu, Peng-Gang
Wang, Xiao-Ning
Yang, Yong-An
Zhu, Hai-Liang
author_sort Liu, Peng-Gang
collection PubMed
description The asymmetric unit of the title compound, C(20)H(16)ClN(3)S, contains two independent mol­ecules, A and B. In mol­ecule A, the dihedral angles between the central benzene ring and the pendant chloro­benzene and phenyl rings are 6.37 (15) and 64.79 (15)°, respectively. The corresponding values in mol­ecule B are 28.21 (14) and 82.11 (16)°, respectively. Each mol­ecule features an intra­molecular N—H⋯N hydrogen bond, which generates an S(5) ring. In the crystal, mol­ecules A and B form dimers, being linked by two N—H⋯S hydrogen bonds with graph-set notation R (2) (2)(8).
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spelling pubmed-32955302012-03-12 1-{2-[(4-Chloro­benzyl­idene)amino]phen­yl}-3-phenyl­thio­urea Liu, Peng-Gang Wang, Xiao-Ning Yang, Yong-An Zhu, Hai-Liang Acta Crystallogr Sect E Struct Rep Online Organic Papers The asymmetric unit of the title compound, C(20)H(16)ClN(3)S, contains two independent mol­ecules, A and B. In mol­ecule A, the dihedral angles between the central benzene ring and the pendant chloro­benzene and phenyl rings are 6.37 (15) and 64.79 (15)°, respectively. The corresponding values in mol­ecule B are 28.21 (14) and 82.11 (16)°, respectively. Each mol­ecule features an intra­molecular N—H⋯N hydrogen bond, which generates an S(5) ring. In the crystal, mol­ecules A and B form dimers, being linked by two N—H⋯S hydrogen bonds with graph-set notation R (2) (2)(8). International Union of Crystallography 2012-02-17 /pmc/articles/PMC3295530/ /pubmed/22412641 http://dx.doi.org/10.1107/S1600536812006228 Text en © Liu et al. 2012 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Organic Papers
Liu, Peng-Gang
Wang, Xiao-Ning
Yang, Yong-An
Zhu, Hai-Liang
1-{2-[(4-Chloro­benzyl­idene)amino]phen­yl}-3-phenyl­thio­urea
title 1-{2-[(4-Chloro­benzyl­idene)amino]phen­yl}-3-phenyl­thio­urea
title_full 1-{2-[(4-Chloro­benzyl­idene)amino]phen­yl}-3-phenyl­thio­urea
title_fullStr 1-{2-[(4-Chloro­benzyl­idene)amino]phen­yl}-3-phenyl­thio­urea
title_full_unstemmed 1-{2-[(4-Chloro­benzyl­idene)amino]phen­yl}-3-phenyl­thio­urea
title_short 1-{2-[(4-Chloro­benzyl­idene)amino]phen­yl}-3-phenyl­thio­urea
title_sort 1-{2-[(4-chloro­benzyl­idene)amino]phen­yl}-3-phenyl­thio­urea
topic Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3295530/
https://www.ncbi.nlm.nih.gov/pubmed/22412641
http://dx.doi.org/10.1107/S1600536812006228
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AT wangxiaoning 124chlorobenzylideneaminophenyl3phenylthiourea
AT yangyongan 124chlorobenzylideneaminophenyl3phenylthiourea
AT zhuhailiang 124chlorobenzylideneaminophenyl3phenylthiourea

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