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Didysprosium hepta­nickel

The title compound, Dy(2)Ni(7), adopts the β-Gd(2)Co(7)-type structure type. The asymmetric unit contains two Dy sites (both site symmetry 3m) and five Ni sites (site symmetries .m, .2/m and -3m, and two 3m). The four different Ni coordination polyhedra are Frank–Kasper icosa­hedra formed by five Dy...

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Autores principales: Levytskyy, Volodymyr, Babizhetskyy, Volodymyr, Kotur, Bohdan, Smetana, Volodymyr
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2012
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3297205/
https://www.ncbi.nlm.nih.gov/pubmed/22412395
http://dx.doi.org/10.1107/S1600536812007611
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author Levytskyy, Volodymyr
Babizhetskyy, Volodymyr
Kotur, Bohdan
Smetana, Volodymyr
author_facet Levytskyy, Volodymyr
Babizhetskyy, Volodymyr
Kotur, Bohdan
Smetana, Volodymyr
author_sort Levytskyy, Volodymyr
collection PubMed
description The title compound, Dy(2)Ni(7), adopts the β-Gd(2)Co(7)-type structure type. The asymmetric unit contains two Dy sites (both site symmetry 3m) and five Ni sites (site symmetries .m, .2/m and -3m, and two 3m). The four different Ni coordination polyhedra are Frank–Kasper icosa­hedra formed by five Dy and seven Ni atoms, four Dy and eight Ni, three Dy and nine Ni, and six Dy and six Ni atoms, respectively. The two different Dy coordination polyhedra are either pseudo Frank–Kasper icosa­hedra formed by two Dy and 18 Ni atoms or normal Frank–Kasper icosa­hedra formed by four Dy and 12 Ni atoms.
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spelling pubmed-32972052012-03-12 Didysprosium hepta­nickel Levytskyy, Volodymyr Babizhetskyy, Volodymyr Kotur, Bohdan Smetana, Volodymyr Acta Crystallogr Sect E Struct Rep Online Inorganic Papers The title compound, Dy(2)Ni(7), adopts the β-Gd(2)Co(7)-type structure type. The asymmetric unit contains two Dy sites (both site symmetry 3m) and five Ni sites (site symmetries .m, .2/m and -3m, and two 3m). The four different Ni coordination polyhedra are Frank–Kasper icosa­hedra formed by five Dy and seven Ni atoms, four Dy and eight Ni, three Dy and nine Ni, and six Dy and six Ni atoms, respectively. The two different Dy coordination polyhedra are either pseudo Frank–Kasper icosa­hedra formed by two Dy and 18 Ni atoms or normal Frank–Kasper icosa­hedra formed by four Dy and 12 Ni atoms. International Union of Crystallography 2012-02-24 /pmc/articles/PMC3297205/ /pubmed/22412395 http://dx.doi.org/10.1107/S1600536812007611 Text en © Levytskyy et al. 2012 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Inorganic Papers
Levytskyy, Volodymyr
Babizhetskyy, Volodymyr
Kotur, Bohdan
Smetana, Volodymyr
Didysprosium hepta­nickel
title Didysprosium hepta­nickel
title_full Didysprosium hepta­nickel
title_fullStr Didysprosium hepta­nickel
title_full_unstemmed Didysprosium hepta­nickel
title_short Didysprosium hepta­nickel
title_sort didysprosium hepta­nickel
topic Inorganic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3297205/
https://www.ncbi.nlm.nih.gov/pubmed/22412395
http://dx.doi.org/10.1107/S1600536812007611
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