catena-Poly[[bis­(dimethyl­formamide-κO)cadmium]-bis­(μ-4-nitro­phenyl­cyanamido-κ(2) N (1):N (3))]

In the title coordination polymer, [Cd(C(7)H(4)N(3)O(2))(2)(C(3)H(7)NO)(2)](n), the Cd(II) atom, lying on an inversion center, is six-coordinated in a distorted N(4)O(2) octa­hedral geometry. The N atoms of the 4-nitrophenylcyanamide anions form the equatorial plane and the O atoms of the dimethyl­f...

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Detalles Bibliográficos
Autores principales: Chiniforoshan, Hossein, Jazestani, Mehdi, Notash, Behrouz
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2012
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3297207/
https://www.ncbi.nlm.nih.gov/pubmed/22412397
http://dx.doi.org/10.1107/S1600536812001924
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author Chiniforoshan, Hossein
Jazestani, Mehdi
Notash, Behrouz
author_facet Chiniforoshan, Hossein
Jazestani, Mehdi
Notash, Behrouz
author_sort Chiniforoshan, Hossein
collection PubMed
description In the title coordination polymer, [Cd(C(7)H(4)N(3)O(2))(2)(C(3)H(7)NO)(2)](n), the Cd(II) atom, lying on an inversion center, is six-coordinated in a distorted N(4)O(2) octa­hedral geometry. The N atoms of the 4-nitrophenylcyanamide anions form the equatorial plane and the O atoms of the dimethyl­formamide mol­ecules occupy the axial positions. The anions act as bridging ligands, connecting the Cd atoms into a one-dimensional coordination polymer along [100].
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spelling pubmed-32972072012-03-12 catena-Poly[[bis­(dimethyl­formamide-κO)cadmium]-bis­(μ-4-nitro­phenyl­cyanamido-κ(2) N (1):N (3))] Chiniforoshan, Hossein Jazestani, Mehdi Notash, Behrouz Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the title coordination polymer, [Cd(C(7)H(4)N(3)O(2))(2)(C(3)H(7)NO)(2)](n), the Cd(II) atom, lying on an inversion center, is six-coordinated in a distorted N(4)O(2) octa­hedral geometry. The N atoms of the 4-nitrophenylcyanamide anions form the equatorial plane and the O atoms of the dimethyl­formamide mol­ecules occupy the axial positions. The anions act as bridging ligands, connecting the Cd atoms into a one-dimensional coordination polymer along [100]. International Union of Crystallography 2012-02-04 /pmc/articles/PMC3297207/ /pubmed/22412397 http://dx.doi.org/10.1107/S1600536812001924 Text en © Chiniforoshan et al. 2012 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Chiniforoshan, Hossein
Jazestani, Mehdi
Notash, Behrouz
catena-Poly[[bis­(dimethyl­formamide-κO)cadmium]-bis­(μ-4-nitro­phenyl­cyanamido-κ(2) N (1):N (3))]
title catena-Poly[[bis­(dimethyl­formamide-κO)cadmium]-bis­(μ-4-nitro­phenyl­cyanamido-κ(2) N (1):N (3))]
title_full catena-Poly[[bis­(dimethyl­formamide-κO)cadmium]-bis­(μ-4-nitro­phenyl­cyanamido-κ(2) N (1):N (3))]
title_fullStr catena-Poly[[bis­(dimethyl­formamide-κO)cadmium]-bis­(μ-4-nitro­phenyl­cyanamido-κ(2) N (1):N (3))]
title_full_unstemmed catena-Poly[[bis­(dimethyl­formamide-κO)cadmium]-bis­(μ-4-nitro­phenyl­cyanamido-κ(2) N (1):N (3))]
title_short catena-Poly[[bis­(dimethyl­formamide-κO)cadmium]-bis­(μ-4-nitro­phenyl­cyanamido-κ(2) N (1):N (3))]
title_sort catena-poly[[bis­(dimethyl­formamide-κo)cadmium]-bis­(μ-4-nitro­phenyl­cyanamido-κ(2) n (1):n (3))]
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3297207/
https://www.ncbi.nlm.nih.gov/pubmed/22412397
http://dx.doi.org/10.1107/S1600536812001924
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