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Tris(2,2′-bipyridine-κ(2) N,N′)cobalt(III) tris(oxalato-κ(2) O (1),O (2))ferrate(III) monohydrate
The title compound, [Co(C(10)H(8)N(2))(3)][Fe(C(2)O(4))(3)]·H(2)O, consists of two discrete tris(chelate) metal ions (Co(III)N(6) and Fe(III)O(6) chromophores) and a water molecule. The structure is highly symmetrical; the Co(III) and Fe(III) ions occupy positions with site symmetry 3.2. The coor...
| Autores principales: | , , , , |
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| Formato: | Online Artículo Texto |
| Lenguaje: | English |
| Publicado: |
International Union of Crystallography
2012
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| Materias: | |
| Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3297208/ https://www.ncbi.nlm.nih.gov/pubmed/22412398 http://dx.doi.org/10.1107/S1600536812003224 |
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| author | Chygorin, Eduard N. Petrusenko, Svitlana R. Kokozay, Volodymyr N. Omelchenko, Irina V. Shishkin, Oleg V. |
| author_facet | Chygorin, Eduard N. Petrusenko, Svitlana R. Kokozay, Volodymyr N. Omelchenko, Irina V. Shishkin, Oleg V. |
| author_sort | Chygorin, Eduard N. |
| collection | PubMed |
| description | The title compound, [Co(C(10)H(8)N(2))(3)][Fe(C(2)O(4))(3)]·H(2)O, consists of two discrete tris(chelate) metal ions (Co(III)N(6) and Fe(III)O(6) chromophores) and a water molecule. The structure is highly symmetrical; the Co(III) and Fe(III) ions occupy positions with site symmetry 3.2. The coordination polyhedra of the metal atoms have a nearly octahedral geometry with noticeable trigonal distortions. The Co—N and Fe—O bond lengths are equal by symmetry, viz. 1.981 (2) and 1.998 (4) Å, respectively. The cations and anions are arranged alternately along their threefold rotation axes parallel to [001], forming chains that are packed in a hexagonal manner. The water molecules occupy voids between the chains. The crystal under investigation was an inversion twin. |
| format | Online Article Text |
| id | pubmed-3297208 |
| institution | National Center for Biotechnology Information |
| language | English |
| publishDate | 2012 |
| publisher | International Union of Crystallography |
| record_format | MEDLINE/PubMed |
| spelling | pubmed-32972082012-03-12 Tris(2,2′-bipyridine-κ(2) N,N′)cobalt(III) tris(oxalato-κ(2) O (1),O (2))ferrate(III) monohydrate Chygorin, Eduard N. Petrusenko, Svitlana R. Kokozay, Volodymyr N. Omelchenko, Irina V. Shishkin, Oleg V. Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers The title compound, [Co(C(10)H(8)N(2))(3)][Fe(C(2)O(4))(3)]·H(2)O, consists of two discrete tris(chelate) metal ions (Co(III)N(6) and Fe(III)O(6) chromophores) and a water molecule. The structure is highly symmetrical; the Co(III) and Fe(III) ions occupy positions with site symmetry 3.2. The coordination polyhedra of the metal atoms have a nearly octahedral geometry with noticeable trigonal distortions. The Co—N and Fe—O bond lengths are equal by symmetry, viz. 1.981 (2) and 1.998 (4) Å, respectively. The cations and anions are arranged alternately along their threefold rotation axes parallel to [001], forming chains that are packed in a hexagonal manner. The water molecules occupy voids between the chains. The crystal under investigation was an inversion twin. International Union of Crystallography 2012-02-04 /pmc/articles/PMC3297208/ /pubmed/22412398 http://dx.doi.org/10.1107/S1600536812003224 Text en © Chygorin et al. 2012 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
| spellingShingle | Metal-Organic Papers Chygorin, Eduard N. Petrusenko, Svitlana R. Kokozay, Volodymyr N. Omelchenko, Irina V. Shishkin, Oleg V. Tris(2,2′-bipyridine-κ(2) N,N′)cobalt(III) tris(oxalato-κ(2) O (1),O (2))ferrate(III) monohydrate |
| title | Tris(2,2′-bipyridine-κ(2)
N,N′)cobalt(III) tris(oxalato-κ(2)
O
(1),O
(2))ferrate(III) monohydrate |
| title_full | Tris(2,2′-bipyridine-κ(2)
N,N′)cobalt(III) tris(oxalato-κ(2)
O
(1),O
(2))ferrate(III) monohydrate |
| title_fullStr | Tris(2,2′-bipyridine-κ(2)
N,N′)cobalt(III) tris(oxalato-κ(2)
O
(1),O
(2))ferrate(III) monohydrate |
| title_full_unstemmed | Tris(2,2′-bipyridine-κ(2)
N,N′)cobalt(III) tris(oxalato-κ(2)
O
(1),O
(2))ferrate(III) monohydrate |
| title_short | Tris(2,2′-bipyridine-κ(2)
N,N′)cobalt(III) tris(oxalato-κ(2)
O
(1),O
(2))ferrate(III) monohydrate |
| title_sort | tris(2,2′-bipyridine-κ(2)
n,n′)cobalt(iii) tris(oxalato-κ(2)
o
(1),o
(2))ferrate(iii) monohydrate |
| topic | Metal-Organic Papers |
| url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3297208/ https://www.ncbi.nlm.nih.gov/pubmed/22412398 http://dx.doi.org/10.1107/S1600536812003224 |
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