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Dichlorido[(1R,2R)-N-(pyridin-2-ylmethyl)cyclohexane-1,2-diamine-κ(3) N,N′,N′′]mercury(II)
In the title compound, [HgCl(2)(C(12)H(19)N(3))], the Hg(II) ion is coordinated by three N atoms of the (1R,2R)-N-(pyridin-2-ylmethyl)cyclohexane-1,2-diamine ligand and by a Cl atom in the basal plane, and by a second Cl atom in the apical position, within a distorted square-pyramidal geometry. Th...
Autores principales: | , , |
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Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
International Union of Crystallography
2012
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3297209/ https://www.ncbi.nlm.nih.gov/pubmed/22412399 http://dx.doi.org/10.1107/S1600536812003340 |
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author | Gao, Chuan-Zhu Zhang, Xiu-Ying Cheng, Lin |
author_facet | Gao, Chuan-Zhu Zhang, Xiu-Ying Cheng, Lin |
author_sort | Gao, Chuan-Zhu |
collection | PubMed |
description | In the title compound, [HgCl(2)(C(12)H(19)N(3))], the Hg(II) ion is coordinated by three N atoms of the (1R,2R)-N-(pyridin-2-ylmethyl)cyclohexane-1,2-diamine ligand and by a Cl atom in the basal plane, and by a second Cl atom in the apical position, within a distorted square-pyramidal geometry. The coordination of the enantiopure ligand to the metal atom renders the central N atom chiral with an S configuration, so the complex is enantiomerically pure and corresponds to the S,R,R diastereoisomer. Molecules are linked via weak N—H⋯Cl hydrogen bonds into a one-dimensional hydrogen-bonding supramolecular chain along the crystallographic b axis. |
format | Online Article Text |
id | pubmed-3297209 |
institution | National Center for Biotechnology Information |
language | English |
publishDate | 2012 |
publisher | International Union of Crystallography |
record_format | MEDLINE/PubMed |
spelling | pubmed-32972092012-03-12 Dichlorido[(1R,2R)-N-(pyridin-2-ylmethyl)cyclohexane-1,2-diamine-κ(3) N,N′,N′′]mercury(II) Gao, Chuan-Zhu Zhang, Xiu-Ying Cheng, Lin Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the title compound, [HgCl(2)(C(12)H(19)N(3))], the Hg(II) ion is coordinated by three N atoms of the (1R,2R)-N-(pyridin-2-ylmethyl)cyclohexane-1,2-diamine ligand and by a Cl atom in the basal plane, and by a second Cl atom in the apical position, within a distorted square-pyramidal geometry. The coordination of the enantiopure ligand to the metal atom renders the central N atom chiral with an S configuration, so the complex is enantiomerically pure and corresponds to the S,R,R diastereoisomer. Molecules are linked via weak N—H⋯Cl hydrogen bonds into a one-dimensional hydrogen-bonding supramolecular chain along the crystallographic b axis. International Union of Crystallography 2012-02-04 /pmc/articles/PMC3297209/ /pubmed/22412399 http://dx.doi.org/10.1107/S1600536812003340 Text en © Gao et al. 2012 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
spellingShingle | Metal-Organic Papers Gao, Chuan-Zhu Zhang, Xiu-Ying Cheng, Lin Dichlorido[(1R,2R)-N-(pyridin-2-ylmethyl)cyclohexane-1,2-diamine-κ(3) N,N′,N′′]mercury(II) |
title | Dichlorido[(1R,2R)-N-(pyridin-2-ylmethyl)cyclohexane-1,2-diamine-κ(3)
N,N′,N′′]mercury(II) |
title_full | Dichlorido[(1R,2R)-N-(pyridin-2-ylmethyl)cyclohexane-1,2-diamine-κ(3)
N,N′,N′′]mercury(II) |
title_fullStr | Dichlorido[(1R,2R)-N-(pyridin-2-ylmethyl)cyclohexane-1,2-diamine-κ(3)
N,N′,N′′]mercury(II) |
title_full_unstemmed | Dichlorido[(1R,2R)-N-(pyridin-2-ylmethyl)cyclohexane-1,2-diamine-κ(3)
N,N′,N′′]mercury(II) |
title_short | Dichlorido[(1R,2R)-N-(pyridin-2-ylmethyl)cyclohexane-1,2-diamine-κ(3)
N,N′,N′′]mercury(II) |
title_sort | dichlorido[(1r,2r)-n-(pyridin-2-ylmethyl)cyclohexane-1,2-diamine-κ(3)
n,n′,n′′]mercury(ii) |
topic | Metal-Organic Papers |
url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3297209/ https://www.ncbi.nlm.nih.gov/pubmed/22412399 http://dx.doi.org/10.1107/S1600536812003340 |
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