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Dichlorido[(1R,2R)-N-(pyridin-2-yl­methyl)cyclo­hexane-1,2-diamine-κ(3) N,N′,N′′]mercury(II)

In the title compound, [HgCl(2)(C(12)H(19)N(3))], the Hg(II) ion is coordinated by three N atoms of the (1R,2R)-N-(pyridin-2-ylmeth­yl)cyclo­hexane-1,2-diamine ligand and by a Cl atom in the basal plane, and by a second Cl atom in the apical position, within a distorted square-pyramidal geometry. Th...

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Detalles Bibliográficos
Autores principales: Gao, Chuan-Zhu, Zhang, Xiu-Ying, Cheng, Lin
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2012
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3297209/
https://www.ncbi.nlm.nih.gov/pubmed/22412399
http://dx.doi.org/10.1107/S1600536812003340
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author Gao, Chuan-Zhu
Zhang, Xiu-Ying
Cheng, Lin
author_facet Gao, Chuan-Zhu
Zhang, Xiu-Ying
Cheng, Lin
author_sort Gao, Chuan-Zhu
collection PubMed
description In the title compound, [HgCl(2)(C(12)H(19)N(3))], the Hg(II) ion is coordinated by three N atoms of the (1R,2R)-N-(pyridin-2-ylmeth­yl)cyclo­hexane-1,2-diamine ligand and by a Cl atom in the basal plane, and by a second Cl atom in the apical position, within a distorted square-pyramidal geometry. The coordination of the enanti­opure ligand to the metal atom renders the central N atom chiral with an S configuration, so the complex is enanti­omerically pure and corresponds to the S,R,R diastereoisomer. Mol­ecules are linked via weak N—H⋯Cl hydrogen bonds into a one-dimensional hydrogen-bonding supramolecular chain along the crystallographic b axis.
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spelling pubmed-32972092012-03-12 Dichlorido[(1R,2R)-N-(pyridin-2-yl­methyl)cyclo­hexane-1,2-diamine-κ(3) N,N′,N′′]mercury(II) Gao, Chuan-Zhu Zhang, Xiu-Ying Cheng, Lin Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the title compound, [HgCl(2)(C(12)H(19)N(3))], the Hg(II) ion is coordinated by three N atoms of the (1R,2R)-N-(pyridin-2-ylmeth­yl)cyclo­hexane-1,2-diamine ligand and by a Cl atom in the basal plane, and by a second Cl atom in the apical position, within a distorted square-pyramidal geometry. The coordination of the enanti­opure ligand to the metal atom renders the central N atom chiral with an S configuration, so the complex is enanti­omerically pure and corresponds to the S,R,R diastereoisomer. Mol­ecules are linked via weak N—H⋯Cl hydrogen bonds into a one-dimensional hydrogen-bonding supramolecular chain along the crystallographic b axis. International Union of Crystallography 2012-02-04 /pmc/articles/PMC3297209/ /pubmed/22412399 http://dx.doi.org/10.1107/S1600536812003340 Text en © Gao et al. 2012 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Gao, Chuan-Zhu
Zhang, Xiu-Ying
Cheng, Lin
Dichlorido[(1R,2R)-N-(pyridin-2-yl­methyl)cyclo­hexane-1,2-diamine-κ(3) N,N′,N′′]mercury(II)
title Dichlorido[(1R,2R)-N-(pyridin-2-yl­methyl)cyclo­hexane-1,2-diamine-κ(3) N,N′,N′′]mercury(II)
title_full Dichlorido[(1R,2R)-N-(pyridin-2-yl­methyl)cyclo­hexane-1,2-diamine-κ(3) N,N′,N′′]mercury(II)
title_fullStr Dichlorido[(1R,2R)-N-(pyridin-2-yl­methyl)cyclo­hexane-1,2-diamine-κ(3) N,N′,N′′]mercury(II)
title_full_unstemmed Dichlorido[(1R,2R)-N-(pyridin-2-yl­methyl)cyclo­hexane-1,2-diamine-κ(3) N,N′,N′′]mercury(II)
title_short Dichlorido[(1R,2R)-N-(pyridin-2-yl­methyl)cyclo­hexane-1,2-diamine-κ(3) N,N′,N′′]mercury(II)
title_sort dichlorido[(1r,2r)-n-(pyridin-2-yl­methyl)cyclo­hexane-1,2-diamine-κ(3) n,n′,n′′]mercury(ii)
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3297209/
https://www.ncbi.nlm.nih.gov/pubmed/22412399
http://dx.doi.org/10.1107/S1600536812003340
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