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cis-Dioxido[N′-(2-oxidobenzylidene)pyridinium-4-carbohydrazidato-κ(3) O,N′,O′]vanadium(V)
The title Schiff base complex, [V(C(13)H(10)N(3)O(2))O(2)], features a square-pyramidal coordination geometry defined by the O,N′,O′-donors of the tridentate Schiff base ligand and two oxide O atoms; one oxide O atom occupies the apical position. In the crystal, pyridinium–oxide N—H⋯O hydrogen bonds...
| Autores principales: | , , , |
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| Formato: | Online Artículo Texto |
| Lenguaje: | English |
| Publicado: |
International Union of Crystallography
2012
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| Materias: | |
| Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3297210/ https://www.ncbi.nlm.nih.gov/pubmed/22412400 http://dx.doi.org/10.1107/S1600536812003637 |
| _version_ | 1782225839748808704 |
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| author | Shahverdizadeh, Gholam Hossein Ng, Seik Weng Tiekink, Edward R. T. Mirtamizdoust, Babak |
| author_facet | Shahverdizadeh, Gholam Hossein Ng, Seik Weng Tiekink, Edward R. T. Mirtamizdoust, Babak |
| author_sort | Shahverdizadeh, Gholam Hossein |
| collection | PubMed |
| description | The title Schiff base complex, [V(C(13)H(10)N(3)O(2))O(2)], features a square-pyramidal coordination geometry defined by the O,N′,O′-donors of the tridentate Schiff base ligand and two oxide O atoms; one oxide O atom occupies the apical position. In the crystal, pyridinium–oxide N—H⋯O hydrogen bonds lead to zigzag supramolecular chains with a flattened topology along [101]. The investigated crystal was twinned by nonmerohedry; the minor component refined to 18.5 (5)%. |
| format | Online Article Text |
| id | pubmed-3297210 |
| institution | National Center for Biotechnology Information |
| language | English |
| publishDate | 2012 |
| publisher | International Union of Crystallography |
| record_format | MEDLINE/PubMed |
| spelling | pubmed-32972102012-03-12 cis-Dioxido[N′-(2-oxidobenzylidene)pyridinium-4-carbohydrazidato-κ(3) O,N′,O′]vanadium(V) Shahverdizadeh, Gholam Hossein Ng, Seik Weng Tiekink, Edward R. T. Mirtamizdoust, Babak Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers The title Schiff base complex, [V(C(13)H(10)N(3)O(2))O(2)], features a square-pyramidal coordination geometry defined by the O,N′,O′-donors of the tridentate Schiff base ligand and two oxide O atoms; one oxide O atom occupies the apical position. In the crystal, pyridinium–oxide N—H⋯O hydrogen bonds lead to zigzag supramolecular chains with a flattened topology along [101]. The investigated crystal was twinned by nonmerohedry; the minor component refined to 18.5 (5)%. International Union of Crystallography 2012-02-04 /pmc/articles/PMC3297210/ /pubmed/22412400 http://dx.doi.org/10.1107/S1600536812003637 Text en © Shahverdizadeh et al. 2012 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
| spellingShingle | Metal-Organic Papers Shahverdizadeh, Gholam Hossein Ng, Seik Weng Tiekink, Edward R. T. Mirtamizdoust, Babak cis-Dioxido[N′-(2-oxidobenzylidene)pyridinium-4-carbohydrazidato-κ(3) O,N′,O′]vanadium(V) |
| title |
cis-Dioxido[N′-(2-oxidobenzylidene)pyridinium-4-carbohydrazidato-κ(3)
O,N′,O′]vanadium(V) |
| title_full |
cis-Dioxido[N′-(2-oxidobenzylidene)pyridinium-4-carbohydrazidato-κ(3)
O,N′,O′]vanadium(V) |
| title_fullStr |
cis-Dioxido[N′-(2-oxidobenzylidene)pyridinium-4-carbohydrazidato-κ(3)
O,N′,O′]vanadium(V) |
| title_full_unstemmed |
cis-Dioxido[N′-(2-oxidobenzylidene)pyridinium-4-carbohydrazidato-κ(3)
O,N′,O′]vanadium(V) |
| title_short |
cis-Dioxido[N′-(2-oxidobenzylidene)pyridinium-4-carbohydrazidato-κ(3)
O,N′,O′]vanadium(V) |
| title_sort | cis-dioxido[n′-(2-oxidobenzylidene)pyridinium-4-carbohydrazidato-κ(3)
o,n′,o′]vanadium(v) |
| topic | Metal-Organic Papers |
| url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3297210/ https://www.ncbi.nlm.nih.gov/pubmed/22412400 http://dx.doi.org/10.1107/S1600536812003637 |
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