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catena-Poly[[(1,10-phenanthroline-κ(2) N,N′)lead(II)]-di-μ-nitrato-κ(3) O,O′:O′′;κ(3) O:O′,O′′-[(1,10-phenanthroline-κ(2) N,N′)lead(II)]-bis(μ-2,2,2-trichloroacetato-κ(2) O:O′)]
In the title Pb(II) complex, [Pb(2)(C(2)Cl(3)O(2))(2)(NO(3))(2)(C(12)H(8)N(2))(2)](n), the 1,10-phenanthroline ligand is chelating, the nitrate anion chelates one Pb(II) ion and simultaneously bridges a neighbouring Pb(II) ion via the third O atom, and the trichloroacetate anion is bidentate, bridg...
| Autores principales: | , , , |
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| Formato: | Online Artículo Texto |
| Lenguaje: | English |
| Publicado: |
International Union of Crystallography
2012
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| Materias: | |
| Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3297211/ https://www.ncbi.nlm.nih.gov/pubmed/22412401 http://dx.doi.org/10.1107/S1600536812003595 |
| _version_ | 1782225839992078336 |
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| author | Shahverdizadeh, Gholam Hossein Ng, Seik Weng Tiekink, Edward R. T. Mirtamizdoust, Babak |
| author_facet | Shahverdizadeh, Gholam Hossein Ng, Seik Weng Tiekink, Edward R. T. Mirtamizdoust, Babak |
| author_sort | Shahverdizadeh, Gholam Hossein |
| collection | PubMed |
| description | In the title Pb(II) complex, [Pb(2)(C(2)Cl(3)O(2))(2)(NO(3))(2)(C(12)H(8)N(2))(2)](n), the 1,10-phenanthroline ligand is chelating, the nitrate anion chelates one Pb(II) ion and simultaneously bridges a neighbouring Pb(II) ion via the third O atom, and the trichloroacetate anion is bidentate, bridging two Pb(II) ions. The coordination geometry is based on a pentagonal–bipramidal geometry defined by an N(2)O(5) donor set with no obvious stereochemical role for the lead-bound lone pair of electrons. The coordination polymer has a zigzag topology along [010] and comprises alternating eight-membered {PbONO}(2) and {PbOCO}(2) rings. |
| format | Online Article Text |
| id | pubmed-3297211 |
| institution | National Center for Biotechnology Information |
| language | English |
| publishDate | 2012 |
| publisher | International Union of Crystallography |
| record_format | MEDLINE/PubMed |
| spelling | pubmed-32972112012-03-12 catena-Poly[[(1,10-phenanthroline-κ(2) N,N′)lead(II)]-di-μ-nitrato-κ(3) O,O′:O′′;κ(3) O:O′,O′′-[(1,10-phenanthroline-κ(2) N,N′)lead(II)]-bis(μ-2,2,2-trichloroacetato-κ(2) O:O′)] Shahverdizadeh, Gholam Hossein Ng, Seik Weng Tiekink, Edward R. T. Mirtamizdoust, Babak Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the title Pb(II) complex, [Pb(2)(C(2)Cl(3)O(2))(2)(NO(3))(2)(C(12)H(8)N(2))(2)](n), the 1,10-phenanthroline ligand is chelating, the nitrate anion chelates one Pb(II) ion and simultaneously bridges a neighbouring Pb(II) ion via the third O atom, and the trichloroacetate anion is bidentate, bridging two Pb(II) ions. The coordination geometry is based on a pentagonal–bipramidal geometry defined by an N(2)O(5) donor set with no obvious stereochemical role for the lead-bound lone pair of electrons. The coordination polymer has a zigzag topology along [010] and comprises alternating eight-membered {PbONO}(2) and {PbOCO}(2) rings. International Union of Crystallography 2012-02-04 /pmc/articles/PMC3297211/ /pubmed/22412401 http://dx.doi.org/10.1107/S1600536812003595 Text en © Shahverdizadeh et al. 2012 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
| spellingShingle | Metal-Organic Papers Shahverdizadeh, Gholam Hossein Ng, Seik Weng Tiekink, Edward R. T. Mirtamizdoust, Babak catena-Poly[[(1,10-phenanthroline-κ(2) N,N′)lead(II)]-di-μ-nitrato-κ(3) O,O′:O′′;κ(3) O:O′,O′′-[(1,10-phenanthroline-κ(2) N,N′)lead(II)]-bis(μ-2,2,2-trichloroacetato-κ(2) O:O′)] |
| title |
catena-Poly[[(1,10-phenanthroline-κ(2)
N,N′)lead(II)]-di-μ-nitrato-κ(3)
O,O′:O′′;κ(3)
O:O′,O′′-[(1,10-phenanthroline-κ(2)
N,N′)lead(II)]-bis(μ-2,2,2-trichloroacetato-κ(2)
O:O′)] |
| title_full |
catena-Poly[[(1,10-phenanthroline-κ(2)
N,N′)lead(II)]-di-μ-nitrato-κ(3)
O,O′:O′′;κ(3)
O:O′,O′′-[(1,10-phenanthroline-κ(2)
N,N′)lead(II)]-bis(μ-2,2,2-trichloroacetato-κ(2)
O:O′)] |
| title_fullStr |
catena-Poly[[(1,10-phenanthroline-κ(2)
N,N′)lead(II)]-di-μ-nitrato-κ(3)
O,O′:O′′;κ(3)
O:O′,O′′-[(1,10-phenanthroline-κ(2)
N,N′)lead(II)]-bis(μ-2,2,2-trichloroacetato-κ(2)
O:O′)] |
| title_full_unstemmed |
catena-Poly[[(1,10-phenanthroline-κ(2)
N,N′)lead(II)]-di-μ-nitrato-κ(3)
O,O′:O′′;κ(3)
O:O′,O′′-[(1,10-phenanthroline-κ(2)
N,N′)lead(II)]-bis(μ-2,2,2-trichloroacetato-κ(2)
O:O′)] |
| title_short |
catena-Poly[[(1,10-phenanthroline-κ(2)
N,N′)lead(II)]-di-μ-nitrato-κ(3)
O,O′:O′′;κ(3)
O:O′,O′′-[(1,10-phenanthroline-κ(2)
N,N′)lead(II)]-bis(μ-2,2,2-trichloroacetato-κ(2)
O:O′)] |
| title_sort | catena-poly[[(1,10-phenanthroline-κ(2)
n,n′)lead(ii)]-di-μ-nitrato-κ(3)
o,o′:o′′;κ(3)
o:o′,o′′-[(1,10-phenanthroline-κ(2)
n,n′)lead(ii)]-bis(μ-2,2,2-trichloroacetato-κ(2)
o:o′)] |
| topic | Metal-Organic Papers |
| url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3297211/ https://www.ncbi.nlm.nih.gov/pubmed/22412401 http://dx.doi.org/10.1107/S1600536812003595 |
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