Cargando…
Poly[[diaqua(1,10-phenanthroline-κ(2) N,N′)(μ(3)-4-sulfonatobenzene-1,2-dicarboxylato-κ(4) O (1):O (2) ,O (2′):O (4))dysprosium(III)] dihydrate]
The 4-sulfophthalate trianion in the polymeric title complex, {[Dy(C(8)H(3)O(7)S)(C(12)H(8)N(2))(H(2)O)(2)]·2H(2)O}(n), bridges three water/phenanthroline-coordinated Dy(III) atoms to form a three-dimensional network architecture. The metal atom is further chelated by a carboxylate group and is cov...
| Autores principales: | , , |
|---|---|
| Formato: | Online Artículo Texto |
| Lenguaje: | English |
| Publicado: |
International Union of Crystallography
2012
|
| Materias: | |
| Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3297213/ https://www.ncbi.nlm.nih.gov/pubmed/22412403 http://dx.doi.org/10.1107/S1600536812003613 |
| _version_ | 1782225840479666176 |
|---|---|
| author | Zhang, Kou-Lin Lin, Jian-Guo Ng, Seik Weng |
| author_facet | Zhang, Kou-Lin Lin, Jian-Guo Ng, Seik Weng |
| author_sort | Zhang, Kou-Lin |
| collection | PubMed |
| description | The 4-sulfophthalate trianion in the polymeric title complex, {[Dy(C(8)H(3)O(7)S)(C(12)H(8)N(2))(H(2)O)(2)]·2H(2)O}(n), bridges three water/phenanthroline-coordinated Dy(III) atoms to form a three-dimensional network architecture. The metal atom is further chelated by a carboxylate group and is covalently bonded to a monodentate carboxylate group and to a monodentate sulfonate group in a distorted square-antiprismatic geometry. The coordinating and the solvent water molecules are hydrogen bonded to the network. In the crystal, one solvent water molecule is disordered over two positions [major component = 59 (3)%]. |
| format | Online Article Text |
| id | pubmed-3297213 |
| institution | National Center for Biotechnology Information |
| language | English |
| publishDate | 2012 |
| publisher | International Union of Crystallography |
| record_format | MEDLINE/PubMed |
| spelling | pubmed-32972132012-03-12 Poly[[diaqua(1,10-phenanthroline-κ(2) N,N′)(μ(3)-4-sulfonatobenzene-1,2-dicarboxylato-κ(4) O (1):O (2) ,O (2′):O (4))dysprosium(III)] dihydrate] Zhang, Kou-Lin Lin, Jian-Guo Ng, Seik Weng Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers The 4-sulfophthalate trianion in the polymeric title complex, {[Dy(C(8)H(3)O(7)S)(C(12)H(8)N(2))(H(2)O)(2)]·2H(2)O}(n), bridges three water/phenanthroline-coordinated Dy(III) atoms to form a three-dimensional network architecture. The metal atom is further chelated by a carboxylate group and is covalently bonded to a monodentate carboxylate group and to a monodentate sulfonate group in a distorted square-antiprismatic geometry. The coordinating and the solvent water molecules are hydrogen bonded to the network. In the crystal, one solvent water molecule is disordered over two positions [major component = 59 (3)%]. International Union of Crystallography 2012-02-04 /pmc/articles/PMC3297213/ /pubmed/22412403 http://dx.doi.org/10.1107/S1600536812003613 Text en © Zhang et al. 2012 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
| spellingShingle | Metal-Organic Papers Zhang, Kou-Lin Lin, Jian-Guo Ng, Seik Weng Poly[[diaqua(1,10-phenanthroline-κ(2) N,N′)(μ(3)-4-sulfonatobenzene-1,2-dicarboxylato-κ(4) O (1):O (2) ,O (2′):O (4))dysprosium(III)] dihydrate] |
| title | Poly[[diaqua(1,10-phenanthroline-κ(2)
N,N′)(μ(3)-4-sulfonatobenzene-1,2-dicarboxylato-κ(4)
O
(1):O
(2)
,O
(2′):O
(4))dysprosium(III)] dihydrate] |
| title_full | Poly[[diaqua(1,10-phenanthroline-κ(2)
N,N′)(μ(3)-4-sulfonatobenzene-1,2-dicarboxylato-κ(4)
O
(1):O
(2)
,O
(2′):O
(4))dysprosium(III)] dihydrate] |
| title_fullStr | Poly[[diaqua(1,10-phenanthroline-κ(2)
N,N′)(μ(3)-4-sulfonatobenzene-1,2-dicarboxylato-κ(4)
O
(1):O
(2)
,O
(2′):O
(4))dysprosium(III)] dihydrate] |
| title_full_unstemmed | Poly[[diaqua(1,10-phenanthroline-κ(2)
N,N′)(μ(3)-4-sulfonatobenzene-1,2-dicarboxylato-κ(4)
O
(1):O
(2)
,O
(2′):O
(4))dysprosium(III)] dihydrate] |
| title_short | Poly[[diaqua(1,10-phenanthroline-κ(2)
N,N′)(μ(3)-4-sulfonatobenzene-1,2-dicarboxylato-κ(4)
O
(1):O
(2)
,O
(2′):O
(4))dysprosium(III)] dihydrate] |
| title_sort | poly[[diaqua(1,10-phenanthroline-κ(2)
n,n′)(μ(3)-4-sulfonatobenzene-1,2-dicarboxylato-κ(4)
o
(1):o
(2)
,o
(2′):o
(4))dysprosium(iii)] dihydrate] |
| topic | Metal-Organic Papers |
| url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3297213/ https://www.ncbi.nlm.nih.gov/pubmed/22412403 http://dx.doi.org/10.1107/S1600536812003613 |
| work_keys_str_mv | AT zhangkoulin polydiaqua110phenanthrolinek2nnm34sulfonatobenzene12dicarboxylatok4o1o2o2o4dysprosiumiiidihydrate AT linjianguo polydiaqua110phenanthrolinek2nnm34sulfonatobenzene12dicarboxylatok4o1o2o2o4dysprosiumiiidihydrate AT ngseikweng polydiaqua110phenanthrolinek2nnm34sulfonatobenzene12dicarboxylatok4o1o2o2o4dysprosiumiiidihydrate |