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Di-μ-chlorido-bis[(1,10-phenanthroline-κ(2) N,N′)(trichloroacetato-κO)copper(II)]
The title compound, [Cu(2)(C(2)Cl(3)O(2))(2)Cl(2)(C(12)H(8)N(2))(2)], features a centrosymmetric binuclear complex. The coordination geometry around the Cu(II) atom is square-pyramidal, comprising two N atoms from a symmetrically chelating 1,10-phenanthroline ligand, one O atom from a trichloroacet...
Autores principales: | , , , |
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Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
International Union of Crystallography
2012
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3297214/ https://www.ncbi.nlm.nih.gov/pubmed/22412404 http://dx.doi.org/10.1107/S1600536812003947 |
Sumario: | The title compound, [Cu(2)(C(2)Cl(3)O(2))(2)Cl(2)(C(12)H(8)N(2))(2)], features a centrosymmetric binuclear complex. The coordination geometry around the Cu(II) atom is square-pyramidal, comprising two N atoms from a symmetrically chelating 1,10-phenanthroline ligand, one O atom from a trichloroacetate ligand and two Cl(−) anions. In addition, there is a weak intramolecular Cu⋯O interaction of 2.9403 (14) Å involving the carbonyl O atom of the trichloroacetate ligand. The central Cu(2)Cl(2) core takes the form of a rhombus, owing to the disparate Cu—Cl bond lengths. Molecules are connected in the crystal structure by C—H⋯Cl and C—H⋯O interactions. |
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