Di-μ-chlorido-bis­[(1,10-phenanthroline-κ(2) N,N′)(trichloro­acetato-κO)copper(II)]

The title compound, [Cu(2)(C(2)Cl(3)O(2))(2)Cl(2)(C(12)H(8)N(2))(2)], features a centrosymmetric binuclear complex. The coordination geometry around the Cu(II) atom is square-pyramidal, comprising two N atoms from a symmetrically chelating 1,10-phenanthroline ligand, one O atom from a trichloro­acet...

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Autores principales: Shahverdizadeh, Gholam Hossein, Ng, Seik Weng, Tiekink, Edward R. T., Mirtamizdoust, Babak
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2012
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3297214/
https://www.ncbi.nlm.nih.gov/pubmed/22412404
http://dx.doi.org/10.1107/S1600536812003947
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author Shahverdizadeh, Gholam Hossein
Ng, Seik Weng
Tiekink, Edward R. T.
Mirtamizdoust, Babak
author_facet Shahverdizadeh, Gholam Hossein
Ng, Seik Weng
Tiekink, Edward R. T.
Mirtamizdoust, Babak
author_sort Shahverdizadeh, Gholam Hossein
collection PubMed
description The title compound, [Cu(2)(C(2)Cl(3)O(2))(2)Cl(2)(C(12)H(8)N(2))(2)], features a centrosymmetric binuclear complex. The coordination geometry around the Cu(II) atom is square-pyramidal, comprising two N atoms from a symmetrically chelating 1,10-phenanthroline ligand, one O atom from a trichloro­acetate ligand and two Cl(−) anions. In addition, there is a weak intra­molecular Cu⋯O inter­action of 2.9403 (14) Å involving the carbonyl O atom of the trichloro­acetate ligand. The central Cu(2)Cl(2) core takes the form of a rhombus, owing to the disparate Cu—Cl bond lengths. Mol­ecules are connected in the crystal structure by C—H⋯Cl and C—H⋯O inter­actions.
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spelling pubmed-32972142012-03-12 Di-μ-chlorido-bis­[(1,10-phenanthroline-κ(2) N,N′)(trichloro­acetato-κO)copper(II)] Shahverdizadeh, Gholam Hossein Ng, Seik Weng Tiekink, Edward R. T. Mirtamizdoust, Babak Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers The title compound, [Cu(2)(C(2)Cl(3)O(2))(2)Cl(2)(C(12)H(8)N(2))(2)], features a centrosymmetric binuclear complex. The coordination geometry around the Cu(II) atom is square-pyramidal, comprising two N atoms from a symmetrically chelating 1,10-phenanthroline ligand, one O atom from a trichloro­acetate ligand and two Cl(−) anions. In addition, there is a weak intra­molecular Cu⋯O inter­action of 2.9403 (14) Å involving the carbonyl O atom of the trichloro­acetate ligand. The central Cu(2)Cl(2) core takes the form of a rhombus, owing to the disparate Cu—Cl bond lengths. Mol­ecules are connected in the crystal structure by C—H⋯Cl and C—H⋯O inter­actions. International Union of Crystallography 2012-02-04 /pmc/articles/PMC3297214/ /pubmed/22412404 http://dx.doi.org/10.1107/S1600536812003947 Text en © Shahverdizadeh et al. 2012 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Shahverdizadeh, Gholam Hossein
Ng, Seik Weng
Tiekink, Edward R. T.
Mirtamizdoust, Babak
Di-μ-chlorido-bis­[(1,10-phenanthroline-κ(2) N,N′)(trichloro­acetato-κO)copper(II)]
title Di-μ-chlorido-bis­[(1,10-phenanthroline-κ(2) N,N′)(trichloro­acetato-κO)copper(II)]
title_full Di-μ-chlorido-bis­[(1,10-phenanthroline-κ(2) N,N′)(trichloro­acetato-κO)copper(II)]
title_fullStr Di-μ-chlorido-bis­[(1,10-phenanthroline-κ(2) N,N′)(trichloro­acetato-κO)copper(II)]
title_full_unstemmed Di-μ-chlorido-bis­[(1,10-phenanthroline-κ(2) N,N′)(trichloro­acetato-κO)copper(II)]
title_short Di-μ-chlorido-bis­[(1,10-phenanthroline-κ(2) N,N′)(trichloro­acetato-κO)copper(II)]
title_sort di-μ-chlorido-bis­[(1,10-phenanthroline-κ(2) n,n′)(trichloro­acetato-κo)copper(ii)]
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3297214/
https://www.ncbi.nlm.nih.gov/pubmed/22412404
http://dx.doi.org/10.1107/S1600536812003947
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AT tiekinkedwardrt dimchloridobis110phenanthrolinek2nntrichloroacetatokocopperii
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