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(Dimethyl sulfoxide-κO)[2-({(ethyl­sulfan­yl)[2-(2-oxidobenzyl­idene-κO)hydrazin­yl­idene-κN (2)]meth­yl}­imino­meth­yl)­phenol­ato-κO]dioxidouranium(VI)

The U(VI) atom in the title complex, [U(C(17)H(15)N(3)O(2)S)O(2)(C(2)H(6)OS)], exists within a distorted penta­gonal–pyramidal geometry where the oxide atoms occupy axial positions [O—U—O = 177.84 (14)°] and the penta­gonal plane is defined by the N(2)O(2) atoms of the tetra­dentate Schiff base liga...

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Detalles Bibliográficos
Autores principales: Takjoo, Reza, Ng, Seik Weng, Tiekink, Edward R. T.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2012
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3297215/
https://www.ncbi.nlm.nih.gov/pubmed/22412405
http://dx.doi.org/10.1107/S1600536812003789
Descripción
Sumario:The U(VI) atom in the title complex, [U(C(17)H(15)N(3)O(2)S)O(2)(C(2)H(6)OS)], exists within a distorted penta­gonal–pyramidal geometry where the oxide atoms occupy axial positions [O—U—O = 177.84 (14)°] and the penta­gonal plane is defined by the N(2)O(2) atoms of the tetra­dentate Schiff base ligand and the O atom of the dimethyl sulfoxide mol­ecule. In the crystal, centrosymmetric aggregates are formed via pairs of C—H⋯O inter­actions. The azomethine C=N atoms and ethyl­thiolyl group are disordered over two orientations in a 0.828 (3):0.172 (3) ratio.