(Dimethyl sulfoxide-κO)[2-({(ethyl­sulfan­yl)[2-(2-oxidobenzyl­idene-κO)hydrazin­yl­idene-κN (2)]meth­yl}­imino­meth­yl)­phenol­ato-κO]dioxidouranium(VI)

The U(VI) atom in the title complex, [U(C(17)H(15)N(3)O(2)S)O(2)(C(2)H(6)OS)], exists within a distorted penta­gonal–pyramidal geometry where the oxide atoms occupy axial positions [O—U—O = 177.84 (14)°] and the penta­gonal plane is defined by the N(2)O(2) atoms of the tetra­dentate Schiff base liga...

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Detalles Bibliográficos
Autores principales: Takjoo, Reza, Ng, Seik Weng, Tiekink, Edward R. T.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2012
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3297215/
https://www.ncbi.nlm.nih.gov/pubmed/22412405
http://dx.doi.org/10.1107/S1600536812003789
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author Takjoo, Reza
Ng, Seik Weng
Tiekink, Edward R. T.
author_facet Takjoo, Reza
Ng, Seik Weng
Tiekink, Edward R. T.
author_sort Takjoo, Reza
collection PubMed
description The U(VI) atom in the title complex, [U(C(17)H(15)N(3)O(2)S)O(2)(C(2)H(6)OS)], exists within a distorted penta­gonal–pyramidal geometry where the oxide atoms occupy axial positions [O—U—O = 177.84 (14)°] and the penta­gonal plane is defined by the N(2)O(2) atoms of the tetra­dentate Schiff base ligand and the O atom of the dimethyl sulfoxide mol­ecule. In the crystal, centrosymmetric aggregates are formed via pairs of C—H⋯O inter­actions. The azomethine C=N atoms and ethyl­thiolyl group are disordered over two orientations in a 0.828 (3):0.172 (3) ratio.
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spelling pubmed-32972152012-03-12 (Dimethyl sulfoxide-κO)[2-({(ethyl­sulfan­yl)[2-(2-oxidobenzyl­idene-κO)hydrazin­yl­idene-κN (2)]meth­yl}­imino­meth­yl)­phenol­ato-κO]dioxidouranium(VI) Takjoo, Reza Ng, Seik Weng Tiekink, Edward R. T. Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers The U(VI) atom in the title complex, [U(C(17)H(15)N(3)O(2)S)O(2)(C(2)H(6)OS)], exists within a distorted penta­gonal–pyramidal geometry where the oxide atoms occupy axial positions [O—U—O = 177.84 (14)°] and the penta­gonal plane is defined by the N(2)O(2) atoms of the tetra­dentate Schiff base ligand and the O atom of the dimethyl sulfoxide mol­ecule. In the crystal, centrosymmetric aggregates are formed via pairs of C—H⋯O inter­actions. The azomethine C=N atoms and ethyl­thiolyl group are disordered over two orientations in a 0.828 (3):0.172 (3) ratio. International Union of Crystallography 2012-02-04 /pmc/articles/PMC3297215/ /pubmed/22412405 http://dx.doi.org/10.1107/S1600536812003789 Text en © Takjoo et al. 2012 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Takjoo, Reza
Ng, Seik Weng
Tiekink, Edward R. T.
(Dimethyl sulfoxide-κO)[2-({(ethyl­sulfan­yl)[2-(2-oxidobenzyl­idene-κO)hydrazin­yl­idene-κN (2)]meth­yl}­imino­meth­yl)­phenol­ato-κO]dioxidouranium(VI)
title (Dimethyl sulfoxide-κO)[2-({(ethyl­sulfan­yl)[2-(2-oxidobenzyl­idene-κO)hydrazin­yl­idene-κN (2)]meth­yl}­imino­meth­yl)­phenol­ato-κO]dioxidouranium(VI)
title_full (Dimethyl sulfoxide-κO)[2-({(ethyl­sulfan­yl)[2-(2-oxidobenzyl­idene-κO)hydrazin­yl­idene-κN (2)]meth­yl}­imino­meth­yl)­phenol­ato-κO]dioxidouranium(VI)
title_fullStr (Dimethyl sulfoxide-κO)[2-({(ethyl­sulfan­yl)[2-(2-oxidobenzyl­idene-κO)hydrazin­yl­idene-κN (2)]meth­yl}­imino­meth­yl)­phenol­ato-κO]dioxidouranium(VI)
title_full_unstemmed (Dimethyl sulfoxide-κO)[2-({(ethyl­sulfan­yl)[2-(2-oxidobenzyl­idene-κO)hydrazin­yl­idene-κN (2)]meth­yl}­imino­meth­yl)­phenol­ato-κO]dioxidouranium(VI)
title_short (Dimethyl sulfoxide-κO)[2-({(ethyl­sulfan­yl)[2-(2-oxidobenzyl­idene-κO)hydrazin­yl­idene-κN (2)]meth­yl}­imino­meth­yl)­phenol­ato-κO]dioxidouranium(VI)
title_sort (dimethyl sulfoxide-κo)[2-({(ethyl­sulfan­yl)[2-(2-oxidobenzyl­idene-κo)hydrazin­yl­idene-κn (2)]meth­yl}­imino­meth­yl)­phenol­ato-κo]dioxidouranium(vi)
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3297215/
https://www.ncbi.nlm.nih.gov/pubmed/22412405
http://dx.doi.org/10.1107/S1600536812003789
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AT ngseikweng dimethylsulfoxideko2ethylsulfanyl22oxidobenzylidenekohydrazinylidenekn2methyliminomethylphenolatokodioxidouraniumvi
AT tiekinkedwardrt dimethylsulfoxideko2ethylsulfanyl22oxidobenzylidenekohydrazinylidenekn2methyliminomethylphenolatokodioxidouraniumvi

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