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Dichlorido{1-[N-(5-chloro-2-oxidophen­yl)carboximido­yl]naphthalen-2-olato-κ(3) O,N,O′}(methanol-κO)tin(IV)

In the title complex, [Sn(C(17)H(10)ClNO(2))Cl(2)(CH(3)OH)], the Sn(IV) atom features a distorted octa­hedral geometry defined by the O,N,O′-donors of the dianion, two Cl atoms and the methanol O atom. The six-membered chelate ring has a half-chair conformation with the Sn atom lying 0.449 (4) Å out...

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Autores principales: Shahverdizadeh, Gholam Hossein, Ng, Seik Weng, Tiekink, Edward R. T., Mirtamizdoust, Babak
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2012
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3297216/
https://www.ncbi.nlm.nih.gov/pubmed/22412406
http://dx.doi.org/10.1107/S160053681200390X
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author Shahverdizadeh, Gholam Hossein
Ng, Seik Weng
Tiekink, Edward R. T.
Mirtamizdoust, Babak
author_facet Shahverdizadeh, Gholam Hossein
Ng, Seik Weng
Tiekink, Edward R. T.
Mirtamizdoust, Babak
author_sort Shahverdizadeh, Gholam Hossein
collection PubMed
description In the title complex, [Sn(C(17)H(10)ClNO(2))Cl(2)(CH(3)OH)], the Sn(IV) atom features a distorted octa­hedral geometry defined by the O,N,O′-donors of the dianion, two Cl atoms and the methanol O atom. The six-membered chelate ring has a half-chair conformation with the Sn atom lying 0.449 (4) Å out of the plane defined by the remaining atoms (r.m.s. deviation = 0.0238 Å). Supra­molecular helical chains along [100], mediated by O—H⋯O hydrogen bonds, feature in the crystal packing. Chains are linked by C—H⋯O, C—H⋯Cl and π–π [centroid–centroid distance = 3.598 (2) Å] inter­actions.
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spelling pubmed-32972162012-03-12 Dichlorido{1-[N-(5-chloro-2-oxidophen­yl)carboximido­yl]naphthalen-2-olato-κ(3) O,N,O′}(methanol-κO)tin(IV) Shahverdizadeh, Gholam Hossein Ng, Seik Weng Tiekink, Edward R. T. Mirtamizdoust, Babak Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the title complex, [Sn(C(17)H(10)ClNO(2))Cl(2)(CH(3)OH)], the Sn(IV) atom features a distorted octa­hedral geometry defined by the O,N,O′-donors of the dianion, two Cl atoms and the methanol O atom. The six-membered chelate ring has a half-chair conformation with the Sn atom lying 0.449 (4) Å out of the plane defined by the remaining atoms (r.m.s. deviation = 0.0238 Å). Supra­molecular helical chains along [100], mediated by O—H⋯O hydrogen bonds, feature in the crystal packing. Chains are linked by C—H⋯O, C—H⋯Cl and π–π [centroid–centroid distance = 3.598 (2) Å] inter­actions. International Union of Crystallography 2012-02-04 /pmc/articles/PMC3297216/ /pubmed/22412406 http://dx.doi.org/10.1107/S160053681200390X Text en © Shahverdizadeh et al. 2012 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Shahverdizadeh, Gholam Hossein
Ng, Seik Weng
Tiekink, Edward R. T.
Mirtamizdoust, Babak
Dichlorido{1-[N-(5-chloro-2-oxidophen­yl)carboximido­yl]naphthalen-2-olato-κ(3) O,N,O′}(methanol-κO)tin(IV)
title Dichlorido{1-[N-(5-chloro-2-oxidophen­yl)carboximido­yl]naphthalen-2-olato-κ(3) O,N,O′}(methanol-κO)tin(IV)
title_full Dichlorido{1-[N-(5-chloro-2-oxidophen­yl)carboximido­yl]naphthalen-2-olato-κ(3) O,N,O′}(methanol-κO)tin(IV)
title_fullStr Dichlorido{1-[N-(5-chloro-2-oxidophen­yl)carboximido­yl]naphthalen-2-olato-κ(3) O,N,O′}(methanol-κO)tin(IV)
title_full_unstemmed Dichlorido{1-[N-(5-chloro-2-oxidophen­yl)carboximido­yl]naphthalen-2-olato-κ(3) O,N,O′}(methanol-κO)tin(IV)
title_short Dichlorido{1-[N-(5-chloro-2-oxidophen­yl)carboximido­yl]naphthalen-2-olato-κ(3) O,N,O′}(methanol-κO)tin(IV)
title_sort dichlorido{1-[n-(5-chloro-2-oxidophen­yl)carboximido­yl]naphthalen-2-olato-κ(3) o,n,o′}(methanol-κo)tin(iv)
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3297216/
https://www.ncbi.nlm.nih.gov/pubmed/22412406
http://dx.doi.org/10.1107/S160053681200390X
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