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{μ-2-[4-(1,3-Benzothiazol-2-yl)phenyl]-2-azapropane-1,3-dithiolato-κ(4) S,S′:S,S′}bis[tricarbonyliron(I)]
The title compound, [Fe(2)(C(15)H(12)N(2)S(3))(CO)(6)], was prepared as an azadithiolatodiiron model for the active site of [FeFe]-hydrogenase. The Fe(2)S(2) core adopts a butterfly shape, with each metal having a pseudo square-pyramidal geometry. The N-substituted azadithiolate is μ(2)-κ(4) S,S...
| Autores principales: | , , |
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| Formato: | Online Artículo Texto |
| Lenguaje: | English |
| Publicado: |
International Union of Crystallography
2012
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| Materias: | |
| Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3297217/ https://www.ncbi.nlm.nih.gov/pubmed/22412407 http://dx.doi.org/10.1107/S1600536812003753 |