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trans-Tetra­aqua­bis­(isonicotinamide-κN (1))cobalt(II) bis­(3-hy­droxy­benzoate) tetra­hydrate

The asymmetric unit of the title compound, [Co(C(6)H(6)N(2)O)(2)(H(2)O)(4)](C(7)H(5)O(3))(2)·4H(2)O, contains one-half of the complex cation with the Co(II) ion located on an inversion center, a 3-hy­droxy­benzoate counter-anion and two uncoordinated water mol­ecules. Four water O atoms in the equat...

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Detalles Bibliográficos
Autores principales: Zaman, İIbrahim Göker, Çaylak Delibaş, Nagihan, Necefoğlu, Hacali, Hökelek, Tuncer
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2012
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3297218/
https://www.ncbi.nlm.nih.gov/pubmed/22412408
http://dx.doi.org/10.1107/S1600536812003911
Descripción
Sumario:The asymmetric unit of the title compound, [Co(C(6)H(6)N(2)O)(2)(H(2)O)(4)](C(7)H(5)O(3))(2)·4H(2)O, contains one-half of the complex cation with the Co(II) ion located on an inversion center, a 3-hy­droxy­benzoate counter-anion and two uncoordinated water mol­ecules. Four water O atoms in the equatorial plane around the Co(II) ion [Co—O = 2.0593 (16) and 2.1118 (16) Å] form a slightly distorted square-planar arrangement, and the distorted octahedral geometry is completed by the two N atoms [Co—N = 2.1306 (18) Å] from two isonicotinamide ligands. In the anion, the carboxyl­ate group is twisted from the attached benzene ring at 8.84 (17)°. In the crystal, a three-dimensional hydrogen-bonding network, formed by classical O—H⋯O and N—H⋯O hydrogen bonds, consolidates the crystal packing, which exhibits π–π inter­actions between the benzene and pyridine rings, with centroid–centroid distances of 3.458 (1) and 3.606 (1) Å, respectively.