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trans-Tetraaquabis(isonicotinamide-κN (1))cobalt(II) bis(3-hydroxybenzoate) tetrahydrate
The asymmetric unit of the title compound, [Co(C(6)H(6)N(2)O)(2)(H(2)O)(4)](C(7)H(5)O(3))(2)·4H(2)O, contains one-half of the complex cation with the Co(II) ion located on an inversion center, a 3-hydroxybenzoate counter-anion and two uncoordinated water molecules. Four water O atoms in the equat...
Autores principales: | , , , |
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Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
International Union of Crystallography
2012
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3297218/ https://www.ncbi.nlm.nih.gov/pubmed/22412408 http://dx.doi.org/10.1107/S1600536812003911 |
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author | Zaman, İIbrahim Göker Çaylak Delibaş, Nagihan Necefoğlu, Hacali Hökelek, Tuncer |
author_facet | Zaman, İIbrahim Göker Çaylak Delibaş, Nagihan Necefoğlu, Hacali Hökelek, Tuncer |
author_sort | Zaman, İIbrahim Göker |
collection | PubMed |
description | The asymmetric unit of the title compound, [Co(C(6)H(6)N(2)O)(2)(H(2)O)(4)](C(7)H(5)O(3))(2)·4H(2)O, contains one-half of the complex cation with the Co(II) ion located on an inversion center, a 3-hydroxybenzoate counter-anion and two uncoordinated water molecules. Four water O atoms in the equatorial plane around the Co(II) ion [Co—O = 2.0593 (16) and 2.1118 (16) Å] form a slightly distorted square-planar arrangement, and the distorted octahedral geometry is completed by the two N atoms [Co—N = 2.1306 (18) Å] from two isonicotinamide ligands. In the anion, the carboxylate group is twisted from the attached benzene ring at 8.84 (17)°. In the crystal, a three-dimensional hydrogen-bonding network, formed by classical O—H⋯O and N—H⋯O hydrogen bonds, consolidates the crystal packing, which exhibits π–π interactions between the benzene and pyridine rings, with centroid–centroid distances of 3.458 (1) and 3.606 (1) Å, respectively. |
format | Online Article Text |
id | pubmed-3297218 |
institution | National Center for Biotechnology Information |
language | English |
publishDate | 2012 |
publisher | International Union of Crystallography |
record_format | MEDLINE/PubMed |
spelling | pubmed-32972182012-03-12 trans-Tetraaquabis(isonicotinamide-κN (1))cobalt(II) bis(3-hydroxybenzoate) tetrahydrate Zaman, İIbrahim Göker Çaylak Delibaş, Nagihan Necefoğlu, Hacali Hökelek, Tuncer Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers The asymmetric unit of the title compound, [Co(C(6)H(6)N(2)O)(2)(H(2)O)(4)](C(7)H(5)O(3))(2)·4H(2)O, contains one-half of the complex cation with the Co(II) ion located on an inversion center, a 3-hydroxybenzoate counter-anion and two uncoordinated water molecules. Four water O atoms in the equatorial plane around the Co(II) ion [Co—O = 2.0593 (16) and 2.1118 (16) Å] form a slightly distorted square-planar arrangement, and the distorted octahedral geometry is completed by the two N atoms [Co—N = 2.1306 (18) Å] from two isonicotinamide ligands. In the anion, the carboxylate group is twisted from the attached benzene ring at 8.84 (17)°. In the crystal, a three-dimensional hydrogen-bonding network, formed by classical O—H⋯O and N—H⋯O hydrogen bonds, consolidates the crystal packing, which exhibits π–π interactions between the benzene and pyridine rings, with centroid–centroid distances of 3.458 (1) and 3.606 (1) Å, respectively. International Union of Crystallography 2012-02-04 /pmc/articles/PMC3297218/ /pubmed/22412408 http://dx.doi.org/10.1107/S1600536812003911 Text en © Zaman et al. 2012 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
spellingShingle | Metal-Organic Papers Zaman, İIbrahim Göker Çaylak Delibaş, Nagihan Necefoğlu, Hacali Hökelek, Tuncer trans-Tetraaquabis(isonicotinamide-κN (1))cobalt(II) bis(3-hydroxybenzoate) tetrahydrate |
title |
trans-Tetraaquabis(isonicotinamide-κN
(1))cobalt(II) bis(3-hydroxybenzoate) tetrahydrate |
title_full |
trans-Tetraaquabis(isonicotinamide-κN
(1))cobalt(II) bis(3-hydroxybenzoate) tetrahydrate |
title_fullStr |
trans-Tetraaquabis(isonicotinamide-κN
(1))cobalt(II) bis(3-hydroxybenzoate) tetrahydrate |
title_full_unstemmed |
trans-Tetraaquabis(isonicotinamide-κN
(1))cobalt(II) bis(3-hydroxybenzoate) tetrahydrate |
title_short |
trans-Tetraaquabis(isonicotinamide-κN
(1))cobalt(II) bis(3-hydroxybenzoate) tetrahydrate |
title_sort | trans-tetraaquabis(isonicotinamide-κn
(1))cobalt(ii) bis(3-hydroxybenzoate) tetrahydrate |
topic | Metal-Organic Papers |
url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3297218/ https://www.ncbi.nlm.nih.gov/pubmed/22412408 http://dx.doi.org/10.1107/S1600536812003911 |
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