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trans-Tetra­aqua­bis­(isonicotinamide-κN (1))cobalt(II) bis­(3-hy­droxy­benzoate) tetra­hydrate

The asymmetric unit of the title compound, [Co(C(6)H(6)N(2)O)(2)(H(2)O)(4)](C(7)H(5)O(3))(2)·4H(2)O, contains one-half of the complex cation with the Co(II) ion located on an inversion center, a 3-hy­droxy­benzoate counter-anion and two uncoordinated water mol­ecules. Four water O atoms in the equat...

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Autores principales: Zaman, İIbrahim Göker, Çaylak Delibaş, Nagihan, Necefoğlu, Hacali, Hökelek, Tuncer
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2012
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3297218/
https://www.ncbi.nlm.nih.gov/pubmed/22412408
http://dx.doi.org/10.1107/S1600536812003911
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author Zaman, İIbrahim Göker
Çaylak Delibaş, Nagihan
Necefoğlu, Hacali
Hökelek, Tuncer
author_facet Zaman, İIbrahim Göker
Çaylak Delibaş, Nagihan
Necefoğlu, Hacali
Hökelek, Tuncer
author_sort Zaman, İIbrahim Göker
collection PubMed
description The asymmetric unit of the title compound, [Co(C(6)H(6)N(2)O)(2)(H(2)O)(4)](C(7)H(5)O(3))(2)·4H(2)O, contains one-half of the complex cation with the Co(II) ion located on an inversion center, a 3-hy­droxy­benzoate counter-anion and two uncoordinated water mol­ecules. Four water O atoms in the equatorial plane around the Co(II) ion [Co—O = 2.0593 (16) and 2.1118 (16) Å] form a slightly distorted square-planar arrangement, and the distorted octahedral geometry is completed by the two N atoms [Co—N = 2.1306 (18) Å] from two isonicotinamide ligands. In the anion, the carboxyl­ate group is twisted from the attached benzene ring at 8.84 (17)°. In the crystal, a three-dimensional hydrogen-bonding network, formed by classical O—H⋯O and N—H⋯O hydrogen bonds, consolidates the crystal packing, which exhibits π–π inter­actions between the benzene and pyridine rings, with centroid–centroid distances of 3.458 (1) and 3.606 (1) Å, respectively.
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spelling pubmed-32972182012-03-12 trans-Tetra­aqua­bis­(isonicotinamide-κN (1))cobalt(II) bis­(3-hy­droxy­benzoate) tetra­hydrate Zaman, İIbrahim Göker Çaylak Delibaş, Nagihan Necefoğlu, Hacali Hökelek, Tuncer Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers The asymmetric unit of the title compound, [Co(C(6)H(6)N(2)O)(2)(H(2)O)(4)](C(7)H(5)O(3))(2)·4H(2)O, contains one-half of the complex cation with the Co(II) ion located on an inversion center, a 3-hy­droxy­benzoate counter-anion and two uncoordinated water mol­ecules. Four water O atoms in the equatorial plane around the Co(II) ion [Co—O = 2.0593 (16) and 2.1118 (16) Å] form a slightly distorted square-planar arrangement, and the distorted octahedral geometry is completed by the two N atoms [Co—N = 2.1306 (18) Å] from two isonicotinamide ligands. In the anion, the carboxyl­ate group is twisted from the attached benzene ring at 8.84 (17)°. In the crystal, a three-dimensional hydrogen-bonding network, formed by classical O—H⋯O and N—H⋯O hydrogen bonds, consolidates the crystal packing, which exhibits π–π inter­actions between the benzene and pyridine rings, with centroid–centroid distances of 3.458 (1) and 3.606 (1) Å, respectively. International Union of Crystallography 2012-02-04 /pmc/articles/PMC3297218/ /pubmed/22412408 http://dx.doi.org/10.1107/S1600536812003911 Text en © Zaman et al. 2012 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Zaman, İIbrahim Göker
Çaylak Delibaş, Nagihan
Necefoğlu, Hacali
Hökelek, Tuncer
trans-Tetra­aqua­bis­(isonicotinamide-κN (1))cobalt(II) bis­(3-hy­droxy­benzoate) tetra­hydrate
title trans-Tetra­aqua­bis­(isonicotinamide-κN (1))cobalt(II) bis­(3-hy­droxy­benzoate) tetra­hydrate
title_full trans-Tetra­aqua­bis­(isonicotinamide-κN (1))cobalt(II) bis­(3-hy­droxy­benzoate) tetra­hydrate
title_fullStr trans-Tetra­aqua­bis­(isonicotinamide-κN (1))cobalt(II) bis­(3-hy­droxy­benzoate) tetra­hydrate
title_full_unstemmed trans-Tetra­aqua­bis­(isonicotinamide-κN (1))cobalt(II) bis­(3-hy­droxy­benzoate) tetra­hydrate
title_short trans-Tetra­aqua­bis­(isonicotinamide-κN (1))cobalt(II) bis­(3-hy­droxy­benzoate) tetra­hydrate
title_sort trans-tetra­aqua­bis­(isonicotinamide-κn (1))cobalt(ii) bis­(3-hy­droxy­benzoate) tetra­hydrate
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3297218/
https://www.ncbi.nlm.nih.gov/pubmed/22412408
http://dx.doi.org/10.1107/S1600536812003911
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