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(Acetylacetonato-κ(2) O,O′)(phthalocyaninato-κ(4) N)(phenanthroline-κ(2) N,N′)erbium(III)
The title complex, [Er(C(32)H(16)N(8))(C(5)H(7)O(2))(C(12)H(8)N(2))], possesses a mirror plane and the asymmetric unit is half of the molecule. The Er(III) cation, lying on the mirror plane, is eight-coordinated by two O atoms from acetylacetone, two N (N(phen)) atoms from 1,10-phenanthroline and...
Autores principales: | , |
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Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
International Union of Crystallography
2012
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3297219/ https://www.ncbi.nlm.nih.gov/pubmed/22412409 http://dx.doi.org/10.1107/S1600536812003972 |
Sumario: | The title complex, [Er(C(32)H(16)N(8))(C(5)H(7)O(2))(C(12)H(8)N(2))], possesses a mirror plane and the asymmetric unit is half of the molecule. The Er(III) cation, lying on the mirror plane, is eight-coordinated by two O atoms from acetylacetone, two N (N(phen)) atoms from 1,10-phenanthroline and four isoindole N (N(iso)) atoms from the phthalocyanine ligand in an antiprismatic geometry. The Er—N distances are in the range 2.376 (5)–2.529 (4) Å and the Er—O distance is 2.272 (3) Å. Notably, the Er—N(iso) bonds are shorter than the Er—N(phen) bonds, but longer than the Er—O bonds. |
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