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(Acetylacetonato-κ(2) O,O′)(phthalocyaninato-κ(4) N)(phenanthroline-κ(2) N,N′)erbium(III)
The title complex, [Er(C(32)H(16)N(8))(C(5)H(7)O(2))(C(12)H(8)N(2))], possesses a mirror plane and the asymmetric unit is half of the molecule. The Er(III) cation, lying on the mirror plane, is eight-coordinated by two O atoms from acetylacetone, two N (N(phen)) atoms from 1,10-phenanthroline and...
| Autores principales: | , |
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| Formato: | Online Artículo Texto |
| Lenguaje: | English |
| Publicado: |
International Union of Crystallography
2012
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| Materias: | |
| Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3297219/ https://www.ncbi.nlm.nih.gov/pubmed/22412409 http://dx.doi.org/10.1107/S1600536812003972 |
| _version_ | 1782225841857495040 |
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| author | Li, Hong-Feng Yan, Peng-Fei |
| author_facet | Li, Hong-Feng Yan, Peng-Fei |
| author_sort | Li, Hong-Feng |
| collection | PubMed |
| description | The title complex, [Er(C(32)H(16)N(8))(C(5)H(7)O(2))(C(12)H(8)N(2))], possesses a mirror plane and the asymmetric unit is half of the molecule. The Er(III) cation, lying on the mirror plane, is eight-coordinated by two O atoms from acetylacetone, two N (N(phen)) atoms from 1,10-phenanthroline and four isoindole N (N(iso)) atoms from the phthalocyanine ligand in an antiprismatic geometry. The Er—N distances are in the range 2.376 (5)–2.529 (4) Å and the Er—O distance is 2.272 (3) Å. Notably, the Er—N(iso) bonds are shorter than the Er—N(phen) bonds, but longer than the Er—O bonds. |
| format | Online Article Text |
| id | pubmed-3297219 |
| institution | National Center for Biotechnology Information |
| language | English |
| publishDate | 2012 |
| publisher | International Union of Crystallography |
| record_format | MEDLINE/PubMed |
| spelling | pubmed-32972192012-03-12 (Acetylacetonato-κ(2) O,O′)(phthalocyaninato-κ(4) N)(phenanthroline-κ(2) N,N′)erbium(III) Li, Hong-Feng Yan, Peng-Fei Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers The title complex, [Er(C(32)H(16)N(8))(C(5)H(7)O(2))(C(12)H(8)N(2))], possesses a mirror plane and the asymmetric unit is half of the molecule. The Er(III) cation, lying on the mirror plane, is eight-coordinated by two O atoms from acetylacetone, two N (N(phen)) atoms from 1,10-phenanthroline and four isoindole N (N(iso)) atoms from the phthalocyanine ligand in an antiprismatic geometry. The Er—N distances are in the range 2.376 (5)–2.529 (4) Å and the Er—O distance is 2.272 (3) Å. Notably, the Er—N(iso) bonds are shorter than the Er—N(phen) bonds, but longer than the Er—O bonds. International Union of Crystallography 2012-02-04 /pmc/articles/PMC3297219/ /pubmed/22412409 http://dx.doi.org/10.1107/S1600536812003972 Text en © Li and Yan 2012 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
| spellingShingle | Metal-Organic Papers Li, Hong-Feng Yan, Peng-Fei (Acetylacetonato-κ(2) O,O′)(phthalocyaninato-κ(4) N)(phenanthroline-κ(2) N,N′)erbium(III) |
| title | (Acetylacetonato-κ(2)
O,O′)(phthalocyaninato-κ(4)
N)(phenanthroline-κ(2)
N,N′)erbium(III) |
| title_full | (Acetylacetonato-κ(2)
O,O′)(phthalocyaninato-κ(4)
N)(phenanthroline-κ(2)
N,N′)erbium(III) |
| title_fullStr | (Acetylacetonato-κ(2)
O,O′)(phthalocyaninato-κ(4)
N)(phenanthroline-κ(2)
N,N′)erbium(III) |
| title_full_unstemmed | (Acetylacetonato-κ(2)
O,O′)(phthalocyaninato-κ(4)
N)(phenanthroline-κ(2)
N,N′)erbium(III) |
| title_short | (Acetylacetonato-κ(2)
O,O′)(phthalocyaninato-κ(4)
N)(phenanthroline-κ(2)
N,N′)erbium(III) |
| title_sort | (acetylacetonato-κ(2)
o,o′)(phthalocyaninato-κ(4)
n)(phenanthroline-κ(2)
n,n′)erbium(iii) |
| topic | Metal-Organic Papers |
| url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3297219/ https://www.ncbi.nlm.nih.gov/pubmed/22412409 http://dx.doi.org/10.1107/S1600536812003972 |
| work_keys_str_mv | AT lihongfeng acetylacetonatok2oophthalocyaninatok4nphenanthrolinek2nnerbiumiii AT yanpengfei acetylacetonatok2oophthalocyaninatok4nphenanthrolinek2nnerbiumiii |