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catena-Poly[[(triphenylphosphane-κP)copper(I)]-di-μ-bromido-[(triphenylphosphane-κP)copper(I)]-μ-1,3-bis(pyridin-4-yl)propane-κ(2) N:N′]
Through a diffusion reaction, cuprous bromide, triphenylphosphane and 1,3-bis(pyridin-4-yl)propane (bpp) were self-assembled to form the one-dimensional title compound, [Cu(2)Br(2)(C(13)H(14)N(2))(C(18)H(15)P)(2)](n). Each Cu(I) atom is coordinated by two Br atoms, one P atom from a triphenylphos...
Autores principales: | , , |
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Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
International Union of Crystallography
2012
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3297220/ https://www.ncbi.nlm.nih.gov/pubmed/22412410 http://dx.doi.org/10.1107/S1600536812004084 |
Sumario: | Through a diffusion reaction, cuprous bromide, triphenylphosphane and 1,3-bis(pyridin-4-yl)propane (bpp) were self-assembled to form the one-dimensional title compound, [Cu(2)Br(2)(C(13)H(14)N(2))(C(18)H(15)P)(2)](n). Each Cu(I) atom is coordinated by two Br atoms, one P atom from a triphenylphosphane ligand and one N atom from a bpp molecule in a distorted tetrahedral geometry. Two μ(2)-Br bridges connect two [Cu(PPh(3))](+) units to form neutral [CuBr(PPh(3))](2) dimers, which are linked by the flexible bridging bpp ligands to form a one-dimensional chain structure parallel to the c axis. The dihedral angle between the pyridine rings of the bpp ligand is 34.59 (14)°. |
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