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catena-Poly[[(triphenyl­phosphane-κP)copper(I)]-di-μ-bromido-[(triphenyl­phos­phane-κP)copper(I)]-μ-1,3-bis(pyridin-4-yl)­propane-κ(2) N:N′]

Through a diffusion reaction, cuprous bromide, triphenyl­phosphane and 1,3-bis­(pyridin-4-yl)propane (bpp) were self-assembled to form the one-dimensional title compound, [Cu(2)Br(2)(C(13)H(14)N(2))(C(18)H(15)P)(2)](n). Each Cu(I) atom is coordinated by two Br atoms, one P atom from a triphenyl­phos...

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Detalles Bibliográficos
Autores principales: Huang, Wenjiang, Zhang, Jinfang, Zhang, Chi
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2012
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3297220/
https://www.ncbi.nlm.nih.gov/pubmed/22412410
http://dx.doi.org/10.1107/S1600536812004084
Descripción
Sumario:Through a diffusion reaction, cuprous bromide, triphenyl­phosphane and 1,3-bis­(pyridin-4-yl)propane (bpp) were self-assembled to form the one-dimensional title compound, [Cu(2)Br(2)(C(13)H(14)N(2))(C(18)H(15)P)(2)](n). Each Cu(I) atom is coordinated by two Br atoms, one P atom from a triphenyl­phosphane ligand and one N atom from a bpp mol­ecule in a distorted tetra­hedral geometry. Two μ(2)-Br bridges connect two [Cu(PPh(3))](+) units to form neutral [CuBr(PPh(3))](2) dimers, which are linked by the flexible bridging bpp ligands to form a one-dimensional chain structure parallel to the c axis. The dihedral angle between the pyridine rings of the bpp ligand is 34.59 (14)°.