catena-Poly[[(triphenyl­phosphane-κP)copper(I)]-di-μ-bromido-[(triphenyl­phos­phane-κP)copper(I)]-μ-1,3-bis(pyridin-4-yl)­propane-κ(2) N:N′]

Through a diffusion reaction, cuprous bromide, triphenyl­phosphane and 1,3-bis­(pyridin-4-yl)propane (bpp) were self-assembled to form the one-dimensional title compound, [Cu(2)Br(2)(C(13)H(14)N(2))(C(18)H(15)P)(2)](n). Each Cu(I) atom is coordinated by two Br atoms, one P atom from a triphenyl­phos...

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Detalles Bibliográficos
Autores principales: Huang, Wenjiang, Zhang, Jinfang, Zhang, Chi
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2012
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3297220/
https://www.ncbi.nlm.nih.gov/pubmed/22412410
http://dx.doi.org/10.1107/S1600536812004084
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author Huang, Wenjiang
Zhang, Jinfang
Zhang, Chi
author_facet Huang, Wenjiang
Zhang, Jinfang
Zhang, Chi
author_sort Huang, Wenjiang
collection PubMed
description Through a diffusion reaction, cuprous bromide, triphenyl­phosphane and 1,3-bis­(pyridin-4-yl)propane (bpp) were self-assembled to form the one-dimensional title compound, [Cu(2)Br(2)(C(13)H(14)N(2))(C(18)H(15)P)(2)](n). Each Cu(I) atom is coordinated by two Br atoms, one P atom from a triphenyl­phosphane ligand and one N atom from a bpp mol­ecule in a distorted tetra­hedral geometry. Two μ(2)-Br bridges connect two [Cu(PPh(3))](+) units to form neutral [CuBr(PPh(3))](2) dimers, which are linked by the flexible bridging bpp ligands to form a one-dimensional chain structure parallel to the c axis. The dihedral angle between the pyridine rings of the bpp ligand is 34.59 (14)°.
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spelling pubmed-32972202012-03-12 catena-Poly[[(triphenyl­phosphane-κP)copper(I)]-di-μ-bromido-[(triphenyl­phos­phane-κP)copper(I)]-μ-1,3-bis(pyridin-4-yl)­propane-κ(2) N:N′] Huang, Wenjiang Zhang, Jinfang Zhang, Chi Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers Through a diffusion reaction, cuprous bromide, triphenyl­phosphane and 1,3-bis­(pyridin-4-yl)propane (bpp) were self-assembled to form the one-dimensional title compound, [Cu(2)Br(2)(C(13)H(14)N(2))(C(18)H(15)P)(2)](n). Each Cu(I) atom is coordinated by two Br atoms, one P atom from a triphenyl­phosphane ligand and one N atom from a bpp mol­ecule in a distorted tetra­hedral geometry. Two μ(2)-Br bridges connect two [Cu(PPh(3))](+) units to form neutral [CuBr(PPh(3))](2) dimers, which are linked by the flexible bridging bpp ligands to form a one-dimensional chain structure parallel to the c axis. The dihedral angle between the pyridine rings of the bpp ligand is 34.59 (14)°. International Union of Crystallography 2012-02-04 /pmc/articles/PMC3297220/ /pubmed/22412410 http://dx.doi.org/10.1107/S1600536812004084 Text en © Huang et al. 2012 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Huang, Wenjiang
Zhang, Jinfang
Zhang, Chi
catena-Poly[[(triphenyl­phosphane-κP)copper(I)]-di-μ-bromido-[(triphenyl­phos­phane-κP)copper(I)]-μ-1,3-bis(pyridin-4-yl)­propane-κ(2) N:N′]
title catena-Poly[[(triphenyl­phosphane-κP)copper(I)]-di-μ-bromido-[(triphenyl­phos­phane-κP)copper(I)]-μ-1,3-bis(pyridin-4-yl)­propane-κ(2) N:N′]
title_full catena-Poly[[(triphenyl­phosphane-κP)copper(I)]-di-μ-bromido-[(triphenyl­phos­phane-κP)copper(I)]-μ-1,3-bis(pyridin-4-yl)­propane-κ(2) N:N′]
title_fullStr catena-Poly[[(triphenyl­phosphane-κP)copper(I)]-di-μ-bromido-[(triphenyl­phos­phane-κP)copper(I)]-μ-1,3-bis(pyridin-4-yl)­propane-κ(2) N:N′]
title_full_unstemmed catena-Poly[[(triphenyl­phosphane-κP)copper(I)]-di-μ-bromido-[(triphenyl­phos­phane-κP)copper(I)]-μ-1,3-bis(pyridin-4-yl)­propane-κ(2) N:N′]
title_short catena-Poly[[(triphenyl­phosphane-κP)copper(I)]-di-μ-bromido-[(triphenyl­phos­phane-κP)copper(I)]-μ-1,3-bis(pyridin-4-yl)­propane-κ(2) N:N′]
title_sort catena-poly[[(triphenyl­phosphane-κp)copper(i)]-di-μ-bromido-[(triphenyl­phos­phane-κp)copper(i)]-μ-1,3-bis(pyridin-4-yl)­propane-κ(2) n:n′]
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3297220/
https://www.ncbi.nlm.nih.gov/pubmed/22412410
http://dx.doi.org/10.1107/S1600536812004084
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