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catena-Poly[[(μ-3-hydroxybenzoato-κ(3) O (1),O (1′):O (3))(μ-3-hydroxybenzoato-κ(3) O (1),O (1′):O (1))(isonicotinamide-κN (1))lead(II)] monohydrate]
In the crystal of the title polymeric compound, {[Pb(C(7)H(5)O(3))(2)(C(6)H(6)N(2)O)]·H(2)O}(n), the Pb(II) ion is chelated by two carboxylate groups of 3-hydroxybenzoate (HB) anions, and coordinated by one isonicotinamide molecule; a carboxylate O atom and a hydroxy O atom from adjacent HB an...
Autores principales: | , , , |
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Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
International Union of Crystallography
2012
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3297223/ https://www.ncbi.nlm.nih.gov/pubmed/22412413 http://dx.doi.org/10.1107/S1600536812004357 |
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author | Zaman, Ibrahim Göker Çaylak Delibaş, Nagihan Necefoğlu, Hacali Hökelek, Tuncer |
author_facet | Zaman, Ibrahim Göker Çaylak Delibaş, Nagihan Necefoğlu, Hacali Hökelek, Tuncer |
author_sort | Zaman, Ibrahim Göker |
collection | PubMed |
description | In the crystal of the title polymeric compound, {[Pb(C(7)H(5)O(3))(2)(C(6)H(6)N(2)O)]·H(2)O}(n), the Pb(II) ion is chelated by two carboxylate groups of 3-hydroxybenzoate (HB) anions, and coordinated by one isonicotinamide molecule; a carboxylate O atom and a hydroxy O atom from adjacent HB anions bridge the Pb(II) ion to form polymeric chains along [100], in which the Pb(II) ion is in an irregular seven-coordination geometry. The carboxylate groups of the HB ions are slightly twisted away from the attached benzene rings by 2.84 (15) and 4.8 (2)°. The planes of the two benzene rings of the HB ions are oriented with respect to each other at a dihedral angle of 84.41 (8)°. In the crystal, adjacent polymeric chains interact via O—H⋯O, N—H⋯O and weak C—H⋯O hydrogen bonds. The solvent water molecule links with the polymeric chains via O—H⋯O hydrogen bonding. π–π stacking between the benzene and pyridine rings and between the benzene rings [centroid–centroid distances = 3.731 (2) and 3.353 (2) Å] are present in the crystal. |
format | Online Article Text |
id | pubmed-3297223 |
institution | National Center for Biotechnology Information |
language | English |
publishDate | 2012 |
publisher | International Union of Crystallography |
record_format | MEDLINE/PubMed |
spelling | pubmed-32972232012-03-12 catena-Poly[[(μ-3-hydroxybenzoato-κ(3) O (1),O (1′):O (3))(μ-3-hydroxybenzoato-κ(3) O (1),O (1′):O (1))(isonicotinamide-κN (1))lead(II)] monohydrate] Zaman, Ibrahim Göker Çaylak Delibaş, Nagihan Necefoğlu, Hacali Hökelek, Tuncer Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the crystal of the title polymeric compound, {[Pb(C(7)H(5)O(3))(2)(C(6)H(6)N(2)O)]·H(2)O}(n), the Pb(II) ion is chelated by two carboxylate groups of 3-hydroxybenzoate (HB) anions, and coordinated by one isonicotinamide molecule; a carboxylate O atom and a hydroxy O atom from adjacent HB anions bridge the Pb(II) ion to form polymeric chains along [100], in which the Pb(II) ion is in an irregular seven-coordination geometry. The carboxylate groups of the HB ions are slightly twisted away from the attached benzene rings by 2.84 (15) and 4.8 (2)°. The planes of the two benzene rings of the HB ions are oriented with respect to each other at a dihedral angle of 84.41 (8)°. In the crystal, adjacent polymeric chains interact via O—H⋯O, N—H⋯O and weak C—H⋯O hydrogen bonds. The solvent water molecule links with the polymeric chains via O—H⋯O hydrogen bonding. π–π stacking between the benzene and pyridine rings and between the benzene rings [centroid–centroid distances = 3.731 (2) and 3.353 (2) Å] are present in the crystal. International Union of Crystallography 2012-02-10 /pmc/articles/PMC3297223/ /pubmed/22412413 http://dx.doi.org/10.1107/S1600536812004357 Text en © Zaman et al. 2012 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
spellingShingle | Metal-Organic Papers Zaman, Ibrahim Göker Çaylak Delibaş, Nagihan Necefoğlu, Hacali Hökelek, Tuncer catena-Poly[[(μ-3-hydroxybenzoato-κ(3) O (1),O (1′):O (3))(μ-3-hydroxybenzoato-κ(3) O (1),O (1′):O (1))(isonicotinamide-κN (1))lead(II)] monohydrate] |
title |
catena-Poly[[(μ-3-hydroxybenzoato-κ(3)
O
(1),O
(1′):O
(3))(μ-3-hydroxybenzoato-κ(3)
O
(1),O
(1′):O
(1))(isonicotinamide-κN
(1))lead(II)] monohydrate] |
title_full |
catena-Poly[[(μ-3-hydroxybenzoato-κ(3)
O
(1),O
(1′):O
(3))(μ-3-hydroxybenzoato-κ(3)
O
(1),O
(1′):O
(1))(isonicotinamide-κN
(1))lead(II)] monohydrate] |
title_fullStr |
catena-Poly[[(μ-3-hydroxybenzoato-κ(3)
O
(1),O
(1′):O
(3))(μ-3-hydroxybenzoato-κ(3)
O
(1),O
(1′):O
(1))(isonicotinamide-κN
(1))lead(II)] monohydrate] |
title_full_unstemmed |
catena-Poly[[(μ-3-hydroxybenzoato-κ(3)
O
(1),O
(1′):O
(3))(μ-3-hydroxybenzoato-κ(3)
O
(1),O
(1′):O
(1))(isonicotinamide-κN
(1))lead(II)] monohydrate] |
title_short |
catena-Poly[[(μ-3-hydroxybenzoato-κ(3)
O
(1),O
(1′):O
(3))(μ-3-hydroxybenzoato-κ(3)
O
(1),O
(1′):O
(1))(isonicotinamide-κN
(1))lead(II)] monohydrate] |
title_sort | catena-poly[[(μ-3-hydroxybenzoato-κ(3)
o
(1),o
(1′):o
(3))(μ-3-hydroxybenzoato-κ(3)
o
(1),o
(1′):o
(1))(isonicotinamide-κn
(1))lead(ii)] monohydrate] |
topic | Metal-Organic Papers |
url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3297223/ https://www.ncbi.nlm.nih.gov/pubmed/22412413 http://dx.doi.org/10.1107/S1600536812004357 |
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