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catena-Poly[[(μ-3-hy­droxy­benzoato-κ(3) O (1),O (1′):O (3))(μ-3-hy­droxy­benzoato-κ(3) O (1),O (1′):O (1))(isonicotinamide-κN (1))­lead(II)] monohydrate]

In the crystal of the title polymeric compound, {[Pb(C(7)H(5)O(3))(2)(C(6)H(6)N(2)O)]·H(2)O}(n), the Pb(II) ion is chelated by two carboxyl­ate groups of 3-hy­droxy­benzoate (HB) anions, and coordinated by one isonicotinamide mol­ecule; a carboxyl­ate O atom and a hy­droxy O atom from adjacent HB an...

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Detalles Bibliográficos
Autores principales: Zaman, Ibrahim Göker, Çaylak Delibaş, Nagihan, Necefoğlu, Hacali, Hökelek, Tuncer
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2012
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3297223/
https://www.ncbi.nlm.nih.gov/pubmed/22412413
http://dx.doi.org/10.1107/S1600536812004357
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author Zaman, Ibrahim Göker
Çaylak Delibaş, Nagihan
Necefoğlu, Hacali
Hökelek, Tuncer
author_facet Zaman, Ibrahim Göker
Çaylak Delibaş, Nagihan
Necefoğlu, Hacali
Hökelek, Tuncer
author_sort Zaman, Ibrahim Göker
collection PubMed
description In the crystal of the title polymeric compound, {[Pb(C(7)H(5)O(3))(2)(C(6)H(6)N(2)O)]·H(2)O}(n), the Pb(II) ion is chelated by two carboxyl­ate groups of 3-hy­droxy­benzoate (HB) anions, and coordinated by one isonicotinamide mol­ecule; a carboxyl­ate O atom and a hy­droxy O atom from adjacent HB anions bridge the Pb(II) ion to form polymeric chains along [100], in which the Pb(II) ion is in an irregular seven-coordination geometry. The carboxyl­ate groups of the HB ions are slightly twisted away from the attached benzene rings by 2.84 (15) and 4.8 (2)°. The planes of the two benzene rings of the HB ions are oriented with respect to each other at a dihedral angle of 84.41 (8)°. In the crystal, adjacent polymeric chains inter­act via O—H⋯O, N—H⋯O and weak C—H⋯O hydrogen bonds. The solvent water mol­ecule links with the polymeric chains via O—H⋯O hydrogen bonding. π–π stacking between the benzene and pyridine rings and between the benzene rings [centroid–centroid distances = 3.731 (2) and 3.353 (2) Å] are present in the crystal.
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spelling pubmed-32972232012-03-12 catena-Poly[[(μ-3-hy­droxy­benzoato-κ(3) O (1),O (1′):O (3))(μ-3-hy­droxy­benzoato-κ(3) O (1),O (1′):O (1))(isonicotinamide-κN (1))­lead(II)] monohydrate] Zaman, Ibrahim Göker Çaylak Delibaş, Nagihan Necefoğlu, Hacali Hökelek, Tuncer Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the crystal of the title polymeric compound, {[Pb(C(7)H(5)O(3))(2)(C(6)H(6)N(2)O)]·H(2)O}(n), the Pb(II) ion is chelated by two carboxyl­ate groups of 3-hy­droxy­benzoate (HB) anions, and coordinated by one isonicotinamide mol­ecule; a carboxyl­ate O atom and a hy­droxy O atom from adjacent HB anions bridge the Pb(II) ion to form polymeric chains along [100], in which the Pb(II) ion is in an irregular seven-coordination geometry. The carboxyl­ate groups of the HB ions are slightly twisted away from the attached benzene rings by 2.84 (15) and 4.8 (2)°. The planes of the two benzene rings of the HB ions are oriented with respect to each other at a dihedral angle of 84.41 (8)°. In the crystal, adjacent polymeric chains inter­act via O—H⋯O, N—H⋯O and weak C—H⋯O hydrogen bonds. The solvent water mol­ecule links with the polymeric chains via O—H⋯O hydrogen bonding. π–π stacking between the benzene and pyridine rings and between the benzene rings [centroid–centroid distances = 3.731 (2) and 3.353 (2) Å] are present in the crystal. International Union of Crystallography 2012-02-10 /pmc/articles/PMC3297223/ /pubmed/22412413 http://dx.doi.org/10.1107/S1600536812004357 Text en © Zaman et al. 2012 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Zaman, Ibrahim Göker
Çaylak Delibaş, Nagihan
Necefoğlu, Hacali
Hökelek, Tuncer
catena-Poly[[(μ-3-hy­droxy­benzoato-κ(3) O (1),O (1′):O (3))(μ-3-hy­droxy­benzoato-κ(3) O (1),O (1′):O (1))(isonicotinamide-κN (1))­lead(II)] monohydrate]
title catena-Poly[[(μ-3-hy­droxy­benzoato-κ(3) O (1),O (1′):O (3))(μ-3-hy­droxy­benzoato-κ(3) O (1),O (1′):O (1))(isonicotinamide-κN (1))­lead(II)] monohydrate]
title_full catena-Poly[[(μ-3-hy­droxy­benzoato-κ(3) O (1),O (1′):O (3))(μ-3-hy­droxy­benzoato-κ(3) O (1),O (1′):O (1))(isonicotinamide-κN (1))­lead(II)] monohydrate]
title_fullStr catena-Poly[[(μ-3-hy­droxy­benzoato-κ(3) O (1),O (1′):O (3))(μ-3-hy­droxy­benzoato-κ(3) O (1),O (1′):O (1))(isonicotinamide-κN (1))­lead(II)] monohydrate]
title_full_unstemmed catena-Poly[[(μ-3-hy­droxy­benzoato-κ(3) O (1),O (1′):O (3))(μ-3-hy­droxy­benzoato-κ(3) O (1),O (1′):O (1))(isonicotinamide-κN (1))­lead(II)] monohydrate]
title_short catena-Poly[[(μ-3-hy­droxy­benzoato-κ(3) O (1),O (1′):O (3))(μ-3-hy­droxy­benzoato-κ(3) O (1),O (1′):O (1))(isonicotinamide-κN (1))­lead(II)] monohydrate]
title_sort catena-poly[[(μ-3-hy­droxy­benzoato-κ(3) o (1),o (1′):o (3))(μ-3-hy­droxy­benzoato-κ(3) o (1),o (1′):o (1))(isonicotinamide-κn (1))­lead(ii)] monohydrate]
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3297223/
https://www.ncbi.nlm.nih.gov/pubmed/22412413
http://dx.doi.org/10.1107/S1600536812004357
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