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catena-Poly[[bis(1-methyl-1H-imidazole-κN (3))zinc]-μ-3-nitrophthalato-κ(2) O (1):O(2)]
In the title complex, [Zn(C(8)H(3)NO(6))(C(4)H(6)N(2))(2)](n), the carboxylate groups of the 3-nitrophthalate dianion ligand coordinate the Zn(II) ion in a bis-monodentate mode. The Zn(II) ion shows distorted tetrahedral coordination as it is bonded to two O atoms from the carboxylate groups of...
| Autores principales: | , |
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| Formato: | Online Artículo Texto |
| Lenguaje: | English |
| Publicado: |
International Union of Crystallography
2012
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| Materias: | |
| Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3297226/ https://www.ncbi.nlm.nih.gov/pubmed/22412416 http://dx.doi.org/10.1107/S1600536812004576 |
| _version_ | 1782225843459719168 |
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| author | Zhang, Xi-Juan Guo, Ming-Lin |
| author_facet | Zhang, Xi-Juan Guo, Ming-Lin |
| author_sort | Zhang, Xi-Juan |
| collection | PubMed |
| description | In the title complex, [Zn(C(8)H(3)NO(6))(C(4)H(6)N(2))(2)](n), the carboxylate groups of the 3-nitrophthalate dianion ligand coordinate the Zn(II) ion in a bis-monodentate mode. The Zn(II) ion shows distorted tetrahedral coordination as it is bonded to two O atoms from the carboxylate groups of symmetry-related 3-nitrophthalate anions and two N atoms of two independent 1-methylimidazole molecules. The bridging 3-nitrophthalate ligand allows the formation of one-dimensional chains in the c direction. The crystal structure is further stabilized by weak intermolecular C—H⋯O hydrogen bonds. |
| format | Online Article Text |
| id | pubmed-3297226 |
| institution | National Center for Biotechnology Information |
| language | English |
| publishDate | 2012 |
| publisher | International Union of Crystallography |
| record_format | MEDLINE/PubMed |
| spelling | pubmed-32972262012-03-12 catena-Poly[[bis(1-methyl-1H-imidazole-κN (3))zinc]-μ-3-nitrophthalato-κ(2) O (1):O(2)] Zhang, Xi-Juan Guo, Ming-Lin Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the title complex, [Zn(C(8)H(3)NO(6))(C(4)H(6)N(2))(2)](n), the carboxylate groups of the 3-nitrophthalate dianion ligand coordinate the Zn(II) ion in a bis-monodentate mode. The Zn(II) ion shows distorted tetrahedral coordination as it is bonded to two O atoms from the carboxylate groups of symmetry-related 3-nitrophthalate anions and two N atoms of two independent 1-methylimidazole molecules. The bridging 3-nitrophthalate ligand allows the formation of one-dimensional chains in the c direction. The crystal structure is further stabilized by weak intermolecular C—H⋯O hydrogen bonds. International Union of Crystallography 2012-02-10 /pmc/articles/PMC3297226/ /pubmed/22412416 http://dx.doi.org/10.1107/S1600536812004576 Text en © Zhang and Guo 2012 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
| spellingShingle | Metal-Organic Papers Zhang, Xi-Juan Guo, Ming-Lin catena-Poly[[bis(1-methyl-1H-imidazole-κN (3))zinc]-μ-3-nitrophthalato-κ(2) O (1):O(2)] |
| title |
catena-Poly[[bis(1-methyl-1H-imidazole-κN
(3))zinc]-μ-3-nitrophthalato-κ(2)
O
(1):O(2)] |
| title_full |
catena-Poly[[bis(1-methyl-1H-imidazole-κN
(3))zinc]-μ-3-nitrophthalato-κ(2)
O
(1):O(2)] |
| title_fullStr |
catena-Poly[[bis(1-methyl-1H-imidazole-κN
(3))zinc]-μ-3-nitrophthalato-κ(2)
O
(1):O(2)] |
| title_full_unstemmed |
catena-Poly[[bis(1-methyl-1H-imidazole-κN
(3))zinc]-μ-3-nitrophthalato-κ(2)
O
(1):O(2)] |
| title_short |
catena-Poly[[bis(1-methyl-1H-imidazole-κN
(3))zinc]-μ-3-nitrophthalato-κ(2)
O
(1):O(2)] |
| title_sort | catena-poly[[bis(1-methyl-1h-imidazole-κn
(3))zinc]-μ-3-nitrophthalato-κ(2)
o
(1):o(2)] |
| topic | Metal-Organic Papers |
| url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3297226/ https://www.ncbi.nlm.nih.gov/pubmed/22412416 http://dx.doi.org/10.1107/S1600536812004576 |
| work_keys_str_mv | AT zhangxijuan catenapolybis1methyl1himidazolekn3zincm3nitrophthalatok2o1o2 AT guominglin catenapolybis1methyl1himidazolekn3zincm3nitrophthalatok2o1o2 |