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catena-Poly[(diaquacadmium)-μ-4,4′-[sulfonylbis(1,4-phenyleneoxy)]diacetato-κ(4) O,O′:O′′,O′′′]
In the title coordination polymer, [Cd(C(16)H(12)O(8)S)(H(2)O)(2)](n), the Cd(II) ion is situated on a crystallographic twofold rotation axis, being coordinated by four O atoms from two bidentate 4,4′-[sulfonylbis(1,4-phenyleneoxy)]diacetate (L) ligands and two water molecules in a highly disto...
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Formato: | Online Artículo Texto |
Lenguaje: | English |
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International Union of Crystallography
2012
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Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3297229/ https://www.ncbi.nlm.nih.gov/pubmed/22412419 http://dx.doi.org/10.1107/S160053681200445X |
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author | Ma, Zhan-Ling |
author_facet | Ma, Zhan-Ling |
author_sort | Ma, Zhan-Ling |
collection | PubMed |
description | In the title coordination polymer, [Cd(C(16)H(12)O(8)S)(H(2)O)(2)](n), the Cd(II) ion is situated on a crystallographic twofold rotation axis, being coordinated by four O atoms from two bidentate 4,4′-[sulfonylbis(1,4-phenyleneoxy)]diacetate (L) ligands and two water molecules in a highly distorted CdO(6) octahedral geometry. Each complete ligand L, which is also generated by twofold symmetry with the S atom lying on the rotation axis, bridges two Cd(II) atoms to form a polymeric zigzag chain propagating in the [10-1] direction. O—H⋯O hydrogen bonds between the coordinated water molecules and carboxylate O atoms are involved in the packing. |
format | Online Article Text |
id | pubmed-3297229 |
institution | National Center for Biotechnology Information |
language | English |
publishDate | 2012 |
publisher | International Union of Crystallography |
record_format | MEDLINE/PubMed |
spelling | pubmed-32972292012-03-12 catena-Poly[(diaquacadmium)-μ-4,4′-[sulfonylbis(1,4-phenyleneoxy)]diacetato-κ(4) O,O′:O′′,O′′′] Ma, Zhan-Ling Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the title coordination polymer, [Cd(C(16)H(12)O(8)S)(H(2)O)(2)](n), the Cd(II) ion is situated on a crystallographic twofold rotation axis, being coordinated by four O atoms from two bidentate 4,4′-[sulfonylbis(1,4-phenyleneoxy)]diacetate (L) ligands and two water molecules in a highly distorted CdO(6) octahedral geometry. Each complete ligand L, which is also generated by twofold symmetry with the S atom lying on the rotation axis, bridges two Cd(II) atoms to form a polymeric zigzag chain propagating in the [10-1] direction. O—H⋯O hydrogen bonds between the coordinated water molecules and carboxylate O atoms are involved in the packing. International Union of Crystallography 2012-02-10 /pmc/articles/PMC3297229/ /pubmed/22412419 http://dx.doi.org/10.1107/S160053681200445X Text en © Zhan-Ling Ma 2012 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
spellingShingle | Metal-Organic Papers Ma, Zhan-Ling catena-Poly[(diaquacadmium)-μ-4,4′-[sulfonylbis(1,4-phenyleneoxy)]diacetato-κ(4) O,O′:O′′,O′′′] |
title |
catena-Poly[(diaquacadmium)-μ-4,4′-[sulfonylbis(1,4-phenyleneoxy)]diacetato-κ(4)
O,O′:O′′,O′′′] |
title_full |
catena-Poly[(diaquacadmium)-μ-4,4′-[sulfonylbis(1,4-phenyleneoxy)]diacetato-κ(4)
O,O′:O′′,O′′′] |
title_fullStr |
catena-Poly[(diaquacadmium)-μ-4,4′-[sulfonylbis(1,4-phenyleneoxy)]diacetato-κ(4)
O,O′:O′′,O′′′] |
title_full_unstemmed |
catena-Poly[(diaquacadmium)-μ-4,4′-[sulfonylbis(1,4-phenyleneoxy)]diacetato-κ(4)
O,O′:O′′,O′′′] |
title_short |
catena-Poly[(diaquacadmium)-μ-4,4′-[sulfonylbis(1,4-phenyleneoxy)]diacetato-κ(4)
O,O′:O′′,O′′′] |
title_sort | catena-poly[(diaquacadmium)-μ-4,4′-[sulfonylbis(1,4-phenyleneoxy)]diacetato-κ(4)
o,o′:o′′,o′′′] |
topic | Metal-Organic Papers |
url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3297229/ https://www.ncbi.nlm.nih.gov/pubmed/22412419 http://dx.doi.org/10.1107/S160053681200445X |
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