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catena-Poly[(diaqua­cadmium)-μ-4,4′-[sulfonyl­bis­(1,4-phenyl­ene­oxy)]­di­acet­ato-κ(4) O,O′:O′′,O′′′]

In the title coordination polymer, [Cd(C(16)H(12)O(8)S)(H(2)O)(2)](n), the Cd(II) ion is situated on a crystallographic twofold rotation axis, being coordinated by four O atoms from two bidentate 4,4′-[sulfonyl­bis­(1,4-phenyl­ene­oxy)]diacetate (L) ligands and two water mol­ecules in a highly disto...

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Autor principal: Ma, Zhan-Ling
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2012
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3297229/
https://www.ncbi.nlm.nih.gov/pubmed/22412419
http://dx.doi.org/10.1107/S160053681200445X
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author Ma, Zhan-Ling
author_facet Ma, Zhan-Ling
author_sort Ma, Zhan-Ling
collection PubMed
description In the title coordination polymer, [Cd(C(16)H(12)O(8)S)(H(2)O)(2)](n), the Cd(II) ion is situated on a crystallographic twofold rotation axis, being coordinated by four O atoms from two bidentate 4,4′-[sulfonyl­bis­(1,4-phenyl­ene­oxy)]diacetate (L) ligands and two water mol­ecules in a highly distorted CdO(6) octa­hedral geometry. Each complete ligand L, which is also generated by twofold symmetry with the S atom lying on the rotation axis, bridges two Cd(II) atoms to form a polymeric zigzag chain propagating in the [10-1] direction. O—H⋯O hydrogen bonds between the coordinated water mol­ecules and carboxyl­ate O atoms are involved in the packing.
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spelling pubmed-32972292012-03-12 catena-Poly[(diaqua­cadmium)-μ-4,4′-[sulfonyl­bis­(1,4-phenyl­ene­oxy)]­di­acet­ato-κ(4) O,O′:O′′,O′′′] Ma, Zhan-Ling Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the title coordination polymer, [Cd(C(16)H(12)O(8)S)(H(2)O)(2)](n), the Cd(II) ion is situated on a crystallographic twofold rotation axis, being coordinated by four O atoms from two bidentate 4,4′-[sulfonyl­bis­(1,4-phenyl­ene­oxy)]diacetate (L) ligands and two water mol­ecules in a highly distorted CdO(6) octa­hedral geometry. Each complete ligand L, which is also generated by twofold symmetry with the S atom lying on the rotation axis, bridges two Cd(II) atoms to form a polymeric zigzag chain propagating in the [10-1] direction. O—H⋯O hydrogen bonds between the coordinated water mol­ecules and carboxyl­ate O atoms are involved in the packing. International Union of Crystallography 2012-02-10 /pmc/articles/PMC3297229/ /pubmed/22412419 http://dx.doi.org/10.1107/S160053681200445X Text en © Zhan-Ling Ma 2012 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Ma, Zhan-Ling
catena-Poly[(diaqua­cadmium)-μ-4,4′-[sulfonyl­bis­(1,4-phenyl­ene­oxy)]­di­acet­ato-κ(4) O,O′:O′′,O′′′]
title catena-Poly[(diaqua­cadmium)-μ-4,4′-[sulfonyl­bis­(1,4-phenyl­ene­oxy)]­di­acet­ato-κ(4) O,O′:O′′,O′′′]
title_full catena-Poly[(diaqua­cadmium)-μ-4,4′-[sulfonyl­bis­(1,4-phenyl­ene­oxy)]­di­acet­ato-κ(4) O,O′:O′′,O′′′]
title_fullStr catena-Poly[(diaqua­cadmium)-μ-4,4′-[sulfonyl­bis­(1,4-phenyl­ene­oxy)]­di­acet­ato-κ(4) O,O′:O′′,O′′′]
title_full_unstemmed catena-Poly[(diaqua­cadmium)-μ-4,4′-[sulfonyl­bis­(1,4-phenyl­ene­oxy)]­di­acet­ato-κ(4) O,O′:O′′,O′′′]
title_short catena-Poly[(diaqua­cadmium)-μ-4,4′-[sulfonyl­bis­(1,4-phenyl­ene­oxy)]­di­acet­ato-κ(4) O,O′:O′′,O′′′]
title_sort catena-poly[(diaqua­cadmium)-μ-4,4′-[sulfonyl­bis­(1,4-phenyl­ene­oxy)]­di­acet­ato-κ(4) o,o′:o′′,o′′′]
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3297229/
https://www.ncbi.nlm.nih.gov/pubmed/22412419
http://dx.doi.org/10.1107/S160053681200445X
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