cis-Dichloridobis[tris­(2-methyl­phen­oxy)phosphane-κP]palladium(II)

In the title compound, [PdCl(2)(C(21)H(21)O(3)P)(2)], the Pd atom adopts a slightly distorted square-planar coordination geometry, with pairs of the equivalent ligands in cis positions. Adjacent mol­ecules are linked by weak C—H⋯Cl hydrogen bonds. The crystal structure is additionally stabilized by...

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Detalles Bibliográficos
Autores principales: Błaszczyk, Izabela, Trzeciak, Anna M., Gniewek, Andrzej
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2012
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3297231/
https://www.ncbi.nlm.nih.gov/pubmed/22412421
http://dx.doi.org/10.1107/S160053681200342X
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author Błaszczyk, Izabela
Trzeciak, Anna M.
Gniewek, Andrzej
author_facet Błaszczyk, Izabela
Trzeciak, Anna M.
Gniewek, Andrzej
author_sort Błaszczyk, Izabela
collection PubMed
description In the title compound, [PdCl(2)(C(21)H(21)O(3)P)(2)], the Pd atom adopts a slightly distorted square-planar coordination geometry, with pairs of the equivalent ligands in cis positions. Adjacent mol­ecules are linked by weak C—H⋯Cl hydrogen bonds. The crystal structure is additionally stabilized by π–π stacking inter­actions between the aromatic rings [shortest centroid–centroid distance = 3.758 (4) Å].
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spelling pubmed-32972312012-03-12 cis-Dichloridobis[tris­(2-methyl­phen­oxy)phosphane-κP]palladium(II) Błaszczyk, Izabela Trzeciak, Anna M. Gniewek, Andrzej Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the title compound, [PdCl(2)(C(21)H(21)O(3)P)(2)], the Pd atom adopts a slightly distorted square-planar coordination geometry, with pairs of the equivalent ligands in cis positions. Adjacent mol­ecules are linked by weak C—H⋯Cl hydrogen bonds. The crystal structure is additionally stabilized by π–π stacking inter­actions between the aromatic rings [shortest centroid–centroid distance = 3.758 (4) Å]. International Union of Crystallography 2012-02-10 /pmc/articles/PMC3297231/ /pubmed/22412421 http://dx.doi.org/10.1107/S160053681200342X Text en © Błaszczyk et al. 2012 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Błaszczyk, Izabela
Trzeciak, Anna M.
Gniewek, Andrzej
cis-Dichloridobis[tris­(2-methyl­phen­oxy)phosphane-κP]palladium(II)
title cis-Dichloridobis[tris­(2-methyl­phen­oxy)phosphane-κP]palladium(II)
title_full cis-Dichloridobis[tris­(2-methyl­phen­oxy)phosphane-κP]palladium(II)
title_fullStr cis-Dichloridobis[tris­(2-methyl­phen­oxy)phosphane-κP]palladium(II)
title_full_unstemmed cis-Dichloridobis[tris­(2-methyl­phen­oxy)phosphane-κP]palladium(II)
title_short cis-Dichloridobis[tris­(2-methyl­phen­oxy)phosphane-κP]palladium(II)
title_sort cis-dichloridobis[tris­(2-methyl­phen­oxy)phosphane-κp]palladium(ii)
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3297231/
https://www.ncbi.nlm.nih.gov/pubmed/22412421
http://dx.doi.org/10.1107/S160053681200342X
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