μ(3)-Chlorido-tris­(bis­{1-[2-(dimethyl­amino)­eth­yl]-3-methyl­imidazol-2-yl­idene}silver(I)) dichloride

In the crystal structure of the title compound, [Ag(3)Cl(C(8)H(15)N(3))(6)]Cl(2), the Ag(I) ion, which is located on a twofold rotation axis, exists in a T-shape coordination environment. Two carbene C atoms of the N-heterocyclic carbene (NHC) ligands are bonded tightly forming a slightly bent [Ag(N...

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Detalles Bibliográficos
Autores principales: Topf, Christoph, Leitner, Sebastian, Monkowius, Uwe
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2012
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3297232/
https://www.ncbi.nlm.nih.gov/pubmed/22412422
http://dx.doi.org/10.1107/S1600536812004473
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author Topf, Christoph
Leitner, Sebastian
Monkowius, Uwe
author_facet Topf, Christoph
Leitner, Sebastian
Monkowius, Uwe
author_sort Topf, Christoph
collection PubMed
description In the crystal structure of the title compound, [Ag(3)Cl(C(8)H(15)N(3))(6)]Cl(2), the Ag(I) ion, which is located on a twofold rotation axis, exists in a T-shape coordination environment. Two carbene C atoms of the N-heterocyclic carbene (NHC) ligands are bonded tightly forming a slightly bent [Ag(NHC)(2)](+) cation [C—Ag—C angle = 162.80 (18)°]. Three of these complex cations are further aggregated by one bridging chloride anion, which is lying on a threefold rotoinversion axis and is only loosely binding to the Ag(+) ions. The N atom of the amine group is not engaged in any coordinative bond.
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spelling pubmed-32972322012-03-12 μ(3)-Chlorido-tris­(bis­{1-[2-(dimethyl­amino)­eth­yl]-3-methyl­imidazol-2-yl­idene}silver(I)) dichloride Topf, Christoph Leitner, Sebastian Monkowius, Uwe Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the crystal structure of the title compound, [Ag(3)Cl(C(8)H(15)N(3))(6)]Cl(2), the Ag(I) ion, which is located on a twofold rotation axis, exists in a T-shape coordination environment. Two carbene C atoms of the N-heterocyclic carbene (NHC) ligands are bonded tightly forming a slightly bent [Ag(NHC)(2)](+) cation [C—Ag—C angle = 162.80 (18)°]. Three of these complex cations are further aggregated by one bridging chloride anion, which is lying on a threefold rotoinversion axis and is only loosely binding to the Ag(+) ions. The N atom of the amine group is not engaged in any coordinative bond. International Union of Crystallography 2012-02-10 /pmc/articles/PMC3297232/ /pubmed/22412422 http://dx.doi.org/10.1107/S1600536812004473 Text en © Topf et al. 2012 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Topf, Christoph
Leitner, Sebastian
Monkowius, Uwe
μ(3)-Chlorido-tris­(bis­{1-[2-(dimethyl­amino)­eth­yl]-3-methyl­imidazol-2-yl­idene}silver(I)) dichloride
title μ(3)-Chlorido-tris­(bis­{1-[2-(dimethyl­amino)­eth­yl]-3-methyl­imidazol-2-yl­idene}silver(I)) dichloride
title_full μ(3)-Chlorido-tris­(bis­{1-[2-(dimethyl­amino)­eth­yl]-3-methyl­imidazol-2-yl­idene}silver(I)) dichloride
title_fullStr μ(3)-Chlorido-tris­(bis­{1-[2-(dimethyl­amino)­eth­yl]-3-methyl­imidazol-2-yl­idene}silver(I)) dichloride
title_full_unstemmed μ(3)-Chlorido-tris­(bis­{1-[2-(dimethyl­amino)­eth­yl]-3-methyl­imidazol-2-yl­idene}silver(I)) dichloride
title_short μ(3)-Chlorido-tris­(bis­{1-[2-(dimethyl­amino)­eth­yl]-3-methyl­imidazol-2-yl­idene}silver(I)) dichloride
title_sort μ(3)-chlorido-tris­(bis­{1-[2-(dimethyl­amino)­eth­yl]-3-methyl­imidazol-2-yl­idene}silver(i)) dichloride
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3297232/
https://www.ncbi.nlm.nih.gov/pubmed/22412422
http://dx.doi.org/10.1107/S1600536812004473
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AT monkowiusuwe m3chloridotrisbis12dimethylaminoethyl3methylimidazol2ylidenesilveridichloride

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