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Bis[N-(3-amino­prop­yl)propane-1,3-di­amine-κ(3) N,N′,N′′]cadmium nitrate perchlorate

The title complex, [Cd(C(6)H(17)N(3))(2)](ClO(4))(NO(3)), was synthesized by the reaction of Cd(NO(3))(2)·4H(2)O, bis­(3-amino­prop­yl)­amine and sodium perchlorate in methanol. The asymmetric unit of the title complex consists of one Cd(2+) cation, two tridentate bis­(3-amino­prop­yl)amine ligands,...

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Detalles Bibliográficos
Autores principales: Goudarziafshar, Hamid, Nikoorazm, Mohsen, Abbasityula, Yunes, Eigner, Václav, Dušek, Michal
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2012
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3297233/
https://www.ncbi.nlm.nih.gov/pubmed/22412423
http://dx.doi.org/10.1107/S1600536812004400
Descripción
Sumario:The title complex, [Cd(C(6)H(17)N(3))(2)](ClO(4))(NO(3)), was synthesized by the reaction of Cd(NO(3))(2)·4H(2)O, bis­(3-amino­prop­yl)­amine and sodium perchlorate in methanol. The asymmetric unit of the title complex consists of one Cd(2+) cation, two tridentate bis­(3-amino­prop­yl)amine ligands, one nitrate anion and one perchlorate anion. The Cd(2+) cation is coordinated by six N atoms of the bis­(3-amino­prop­yl)amine ligands in a slightly distorted octa­hedral coordination geometry. In the crystal, mol­ecules are held together by an intricate network of N—H⋯O inter­actions. One of the two amine ligands was found to be disordered over two sets of sites, with a ratio of 0.802 (3):0.198 (3), similarly to the nitrate anion, with a ratio of 0.762 (10):0.238 (10).