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Bis[N-(3-aminopropyl)propane-1,3-diamine-κ(3) N,N′,N′′]cadmium nitrate perchlorate
The title complex, [Cd(C(6)H(17)N(3))(2)](ClO(4))(NO(3)), was synthesized by the reaction of Cd(NO(3))(2)·4H(2)O, bis(3-aminopropyl)amine and sodium perchlorate in methanol. The asymmetric unit of the title complex consists of one Cd(2+) cation, two tridentate bis(3-aminopropyl)amine ligands,...
Autores principales: | , , , , |
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Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
International Union of Crystallography
2012
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3297233/ https://www.ncbi.nlm.nih.gov/pubmed/22412423 http://dx.doi.org/10.1107/S1600536812004400 |
Sumario: | The title complex, [Cd(C(6)H(17)N(3))(2)](ClO(4))(NO(3)), was synthesized by the reaction of Cd(NO(3))(2)·4H(2)O, bis(3-aminopropyl)amine and sodium perchlorate in methanol. The asymmetric unit of the title complex consists of one Cd(2+) cation, two tridentate bis(3-aminopropyl)amine ligands, one nitrate anion and one perchlorate anion. The Cd(2+) cation is coordinated by six N atoms of the bis(3-aminopropyl)amine ligands in a slightly distorted octahedral coordination geometry. In the crystal, molecules are held together by an intricate network of N—H⋯O interactions. One of the two amine ligands was found to be disordered over two sets of sites, with a ratio of 0.802 (3):0.198 (3), similarly to the nitrate anion, with a ratio of 0.762 (10):0.238 (10). |
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