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Bis[N-(3-aminopropyl)propane-1,3-diamine-κ(3) N,N′,N′′]cadmium nitrate perchlorate
The title complex, [Cd(C(6)H(17)N(3))(2)](ClO(4))(NO(3)), was synthesized by the reaction of Cd(NO(3))(2)·4H(2)O, bis(3-aminopropyl)amine and sodium perchlorate in methanol. The asymmetric unit of the title complex consists of one Cd(2+) cation, two tridentate bis(3-aminopropyl)amine ligands,...
Autores principales: | , , , , |
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Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
International Union of Crystallography
2012
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3297233/ https://www.ncbi.nlm.nih.gov/pubmed/22412423 http://dx.doi.org/10.1107/S1600536812004400 |
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author | Goudarziafshar, Hamid Nikoorazm, Mohsen Abbasityula, Yunes Eigner, Václav Dušek, Michal |
author_facet | Goudarziafshar, Hamid Nikoorazm, Mohsen Abbasityula, Yunes Eigner, Václav Dušek, Michal |
author_sort | Goudarziafshar, Hamid |
collection | PubMed |
description | The title complex, [Cd(C(6)H(17)N(3))(2)](ClO(4))(NO(3)), was synthesized by the reaction of Cd(NO(3))(2)·4H(2)O, bis(3-aminopropyl)amine and sodium perchlorate in methanol. The asymmetric unit of the title complex consists of one Cd(2+) cation, two tridentate bis(3-aminopropyl)amine ligands, one nitrate anion and one perchlorate anion. The Cd(2+) cation is coordinated by six N atoms of the bis(3-aminopropyl)amine ligands in a slightly distorted octahedral coordination geometry. In the crystal, molecules are held together by an intricate network of N—H⋯O interactions. One of the two amine ligands was found to be disordered over two sets of sites, with a ratio of 0.802 (3):0.198 (3), similarly to the nitrate anion, with a ratio of 0.762 (10):0.238 (10). |
format | Online Article Text |
id | pubmed-3297233 |
institution | National Center for Biotechnology Information |
language | English |
publishDate | 2012 |
publisher | International Union of Crystallography |
record_format | MEDLINE/PubMed |
spelling | pubmed-32972332012-03-12 Bis[N-(3-aminopropyl)propane-1,3-diamine-κ(3) N,N′,N′′]cadmium nitrate perchlorate Goudarziafshar, Hamid Nikoorazm, Mohsen Abbasityula, Yunes Eigner, Václav Dušek, Michal Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers The title complex, [Cd(C(6)H(17)N(3))(2)](ClO(4))(NO(3)), was synthesized by the reaction of Cd(NO(3))(2)·4H(2)O, bis(3-aminopropyl)amine and sodium perchlorate in methanol. The asymmetric unit of the title complex consists of one Cd(2+) cation, two tridentate bis(3-aminopropyl)amine ligands, one nitrate anion and one perchlorate anion. The Cd(2+) cation is coordinated by six N atoms of the bis(3-aminopropyl)amine ligands in a slightly distorted octahedral coordination geometry. In the crystal, molecules are held together by an intricate network of N—H⋯O interactions. One of the two amine ligands was found to be disordered over two sets of sites, with a ratio of 0.802 (3):0.198 (3), similarly to the nitrate anion, with a ratio of 0.762 (10):0.238 (10). International Union of Crystallography 2012-02-10 /pmc/articles/PMC3297233/ /pubmed/22412423 http://dx.doi.org/10.1107/S1600536812004400 Text en © Goudarziafshar et al. 2012 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
spellingShingle | Metal-Organic Papers Goudarziafshar, Hamid Nikoorazm, Mohsen Abbasityula, Yunes Eigner, Václav Dušek, Michal Bis[N-(3-aminopropyl)propane-1,3-diamine-κ(3) N,N′,N′′]cadmium nitrate perchlorate |
title | Bis[N-(3-aminopropyl)propane-1,3-diamine-κ(3)
N,N′,N′′]cadmium nitrate perchlorate |
title_full | Bis[N-(3-aminopropyl)propane-1,3-diamine-κ(3)
N,N′,N′′]cadmium nitrate perchlorate |
title_fullStr | Bis[N-(3-aminopropyl)propane-1,3-diamine-κ(3)
N,N′,N′′]cadmium nitrate perchlorate |
title_full_unstemmed | Bis[N-(3-aminopropyl)propane-1,3-diamine-κ(3)
N,N′,N′′]cadmium nitrate perchlorate |
title_short | Bis[N-(3-aminopropyl)propane-1,3-diamine-κ(3)
N,N′,N′′]cadmium nitrate perchlorate |
title_sort | bis[n-(3-aminopropyl)propane-1,3-diamine-κ(3)
n,n′,n′′]cadmium nitrate perchlorate |
topic | Metal-Organic Papers |
url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3297233/ https://www.ncbi.nlm.nih.gov/pubmed/22412423 http://dx.doi.org/10.1107/S1600536812004400 |
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