Cargando…

Bis[N-(3-amino­prop­yl)propane-1,3-di­amine-κ(3) N,N′,N′′]cadmium nitrate perchlorate

The title complex, [Cd(C(6)H(17)N(3))(2)](ClO(4))(NO(3)), was synthesized by the reaction of Cd(NO(3))(2)·4H(2)O, bis­(3-amino­prop­yl)­amine and sodium perchlorate in methanol. The asymmetric unit of the title complex consists of one Cd(2+) cation, two tridentate bis­(3-amino­prop­yl)amine ligands,...

Descripción completa

Detalles Bibliográficos
Autores principales: Goudarziafshar, Hamid, Nikoorazm, Mohsen, Abbasityula, Yunes, Eigner, Václav, Dušek, Michal
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2012
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3297233/
https://www.ncbi.nlm.nih.gov/pubmed/22412423
http://dx.doi.org/10.1107/S1600536812004400
_version_ 1782225845057748992
author Goudarziafshar, Hamid
Nikoorazm, Mohsen
Abbasityula, Yunes
Eigner, Václav
Dušek, Michal
author_facet Goudarziafshar, Hamid
Nikoorazm, Mohsen
Abbasityula, Yunes
Eigner, Václav
Dušek, Michal
author_sort Goudarziafshar, Hamid
collection PubMed
description The title complex, [Cd(C(6)H(17)N(3))(2)](ClO(4))(NO(3)), was synthesized by the reaction of Cd(NO(3))(2)·4H(2)O, bis­(3-amino­prop­yl)­amine and sodium perchlorate in methanol. The asymmetric unit of the title complex consists of one Cd(2+) cation, two tridentate bis­(3-amino­prop­yl)amine ligands, one nitrate anion and one perchlorate anion. The Cd(2+) cation is coordinated by six N atoms of the bis­(3-amino­prop­yl)amine ligands in a slightly distorted octa­hedral coordination geometry. In the crystal, mol­ecules are held together by an intricate network of N—H⋯O inter­actions. One of the two amine ligands was found to be disordered over two sets of sites, with a ratio of 0.802 (3):0.198 (3), similarly to the nitrate anion, with a ratio of 0.762 (10):0.238 (10).
format Online
Article
Text
id pubmed-3297233
institution National Center for Biotechnology Information
language English
publishDate 2012
publisher International Union of Crystallography
record_format MEDLINE/PubMed
spelling pubmed-32972332012-03-12 Bis[N-(3-amino­prop­yl)propane-1,3-di­amine-κ(3) N,N′,N′′]cadmium nitrate perchlorate Goudarziafshar, Hamid Nikoorazm, Mohsen Abbasityula, Yunes Eigner, Václav Dušek, Michal Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers The title complex, [Cd(C(6)H(17)N(3))(2)](ClO(4))(NO(3)), was synthesized by the reaction of Cd(NO(3))(2)·4H(2)O, bis­(3-amino­prop­yl)­amine and sodium perchlorate in methanol. The asymmetric unit of the title complex consists of one Cd(2+) cation, two tridentate bis­(3-amino­prop­yl)amine ligands, one nitrate anion and one perchlorate anion. The Cd(2+) cation is coordinated by six N atoms of the bis­(3-amino­prop­yl)amine ligands in a slightly distorted octa­hedral coordination geometry. In the crystal, mol­ecules are held together by an intricate network of N—H⋯O inter­actions. One of the two amine ligands was found to be disordered over two sets of sites, with a ratio of 0.802 (3):0.198 (3), similarly to the nitrate anion, with a ratio of 0.762 (10):0.238 (10). International Union of Crystallography 2012-02-10 /pmc/articles/PMC3297233/ /pubmed/22412423 http://dx.doi.org/10.1107/S1600536812004400 Text en © Goudarziafshar et al. 2012 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Goudarziafshar, Hamid
Nikoorazm, Mohsen
Abbasityula, Yunes
Eigner, Václav
Dušek, Michal
Bis[N-(3-amino­prop­yl)propane-1,3-di­amine-κ(3) N,N′,N′′]cadmium nitrate perchlorate
title Bis[N-(3-amino­prop­yl)propane-1,3-di­amine-κ(3) N,N′,N′′]cadmium nitrate perchlorate
title_full Bis[N-(3-amino­prop­yl)propane-1,3-di­amine-κ(3) N,N′,N′′]cadmium nitrate perchlorate
title_fullStr Bis[N-(3-amino­prop­yl)propane-1,3-di­amine-κ(3) N,N′,N′′]cadmium nitrate perchlorate
title_full_unstemmed Bis[N-(3-amino­prop­yl)propane-1,3-di­amine-κ(3) N,N′,N′′]cadmium nitrate perchlorate
title_short Bis[N-(3-amino­prop­yl)propane-1,3-di­amine-κ(3) N,N′,N′′]cadmium nitrate perchlorate
title_sort bis[n-(3-amino­prop­yl)propane-1,3-di­amine-κ(3) n,n′,n′′]cadmium nitrate perchlorate
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3297233/
https://www.ncbi.nlm.nih.gov/pubmed/22412423
http://dx.doi.org/10.1107/S1600536812004400
work_keys_str_mv AT goudarziafsharhamid bisn3aminopropylpropane13diaminek3nnncadmiumnitrateperchlorate
AT nikoorazmmohsen bisn3aminopropylpropane13diaminek3nnncadmiumnitrateperchlorate
AT abbasityulayunes bisn3aminopropylpropane13diaminek3nnncadmiumnitrateperchlorate
AT eignervaclav bisn3aminopropylpropane13diaminek3nnncadmiumnitrateperchlorate
AT dusekmichal bisn3aminopropylpropane13diaminek3nnncadmiumnitrateperchlorate