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Bis[4-amino-N-(pyrimidin-2-yl-κN)benzene­sulfonamidato-κN](4,4′-di­methyl-2,2′-bipyridine-κ(2) N,N′)cadmium dimethyl­formamide disolvate

In the title compound, [Cd(C(10)H(9)N(4)O(2)S)(2)(C(12)H(12)N(2))]·2C(3)H(7)NO, the Cd(II) ion lies on a twofold rotation axis, is six-coordinated by N atoms, and displays a trigonal–prismatic geometry arising from the two sulfadiazinate ligands and one 4,4′-dimethyl-2,2′-bipyridine ligand. Both lig...

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Autores principales: Hossain, G. M. Golzar, Amoroso, A. J.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2012
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3297235/
https://www.ncbi.nlm.nih.gov/pubmed/22412425
http://dx.doi.org/10.1107/S1600536812004412
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author Hossain, G. M. Golzar
Amoroso, A. J.
author_facet Hossain, G. M. Golzar
Amoroso, A. J.
author_sort Hossain, G. M. Golzar
collection PubMed
description In the title compound, [Cd(C(10)H(9)N(4)O(2)S)(2)(C(12)H(12)N(2))]·2C(3)H(7)NO, the Cd(II) ion lies on a twofold rotation axis, is six-coordinated by N atoms, and displays a trigonal–prismatic geometry arising from the two sulfadiazinate ligands and one 4,4′-dimethyl-2,2′-bipyridine ligand. Both ligands are bidentate and coordinate via their N atoms. The O and carbonyl C atoms of the dimethyl­formamide mol­ecule show disorder and were modelled with two different orientations and with site occupancies of 0.584 (10):0.416 (10). The geometry around the sulfadiazine S atom is distorted tetra­hedral. The crystal structure involves N—H⋯O hydrogen bonds which link mol­ecules into a three-dimensional network. Weak C—H⋯O hydrogen bonds are also observed.
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spelling pubmed-32972352012-03-12 Bis[4-amino-N-(pyrimidin-2-yl-κN)benzene­sulfonamidato-κN](4,4′-di­methyl-2,2′-bipyridine-κ(2) N,N′)cadmium dimethyl­formamide disolvate Hossain, G. M. Golzar Amoroso, A. J. Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the title compound, [Cd(C(10)H(9)N(4)O(2)S)(2)(C(12)H(12)N(2))]·2C(3)H(7)NO, the Cd(II) ion lies on a twofold rotation axis, is six-coordinated by N atoms, and displays a trigonal–prismatic geometry arising from the two sulfadiazinate ligands and one 4,4′-dimethyl-2,2′-bipyridine ligand. Both ligands are bidentate and coordinate via their N atoms. The O and carbonyl C atoms of the dimethyl­formamide mol­ecule show disorder and were modelled with two different orientations and with site occupancies of 0.584 (10):0.416 (10). The geometry around the sulfadiazine S atom is distorted tetra­hedral. The crystal structure involves N—H⋯O hydrogen bonds which link mol­ecules into a three-dimensional network. Weak C—H⋯O hydrogen bonds are also observed. International Union of Crystallography 2012-02-10 /pmc/articles/PMC3297235/ /pubmed/22412425 http://dx.doi.org/10.1107/S1600536812004412 Text en © Hossain and Amoroso 2012 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Hossain, G. M. Golzar
Amoroso, A. J.
Bis[4-amino-N-(pyrimidin-2-yl-κN)benzene­sulfonamidato-κN](4,4′-di­methyl-2,2′-bipyridine-κ(2) N,N′)cadmium dimethyl­formamide disolvate
title Bis[4-amino-N-(pyrimidin-2-yl-κN)benzene­sulfonamidato-κN](4,4′-di­methyl-2,2′-bipyridine-κ(2) N,N′)cadmium dimethyl­formamide disolvate
title_full Bis[4-amino-N-(pyrimidin-2-yl-κN)benzene­sulfonamidato-κN](4,4′-di­methyl-2,2′-bipyridine-κ(2) N,N′)cadmium dimethyl­formamide disolvate
title_fullStr Bis[4-amino-N-(pyrimidin-2-yl-κN)benzene­sulfonamidato-κN](4,4′-di­methyl-2,2′-bipyridine-κ(2) N,N′)cadmium dimethyl­formamide disolvate
title_full_unstemmed Bis[4-amino-N-(pyrimidin-2-yl-κN)benzene­sulfonamidato-κN](4,4′-di­methyl-2,2′-bipyridine-κ(2) N,N′)cadmium dimethyl­formamide disolvate
title_short Bis[4-amino-N-(pyrimidin-2-yl-κN)benzene­sulfonamidato-κN](4,4′-di­methyl-2,2′-bipyridine-κ(2) N,N′)cadmium dimethyl­formamide disolvate
title_sort bis[4-amino-n-(pyrimidin-2-yl-κn)benzene­sulfonamidato-κn](4,4′-di­methyl-2,2′-bipyridine-κ(2) n,n′)cadmium dimethyl­formamide disolvate
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3297235/
https://www.ncbi.nlm.nih.gov/pubmed/22412425
http://dx.doi.org/10.1107/S1600536812004412
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