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Bis[4-amino-N-(pyrimidin-2-yl-κN)benzenesulfonamidato-κN](4,4′-dimethyl-2,2′-bipyridine-κ(2) N,N′)cadmium dimethylformamide disolvate
In the title compound, [Cd(C(10)H(9)N(4)O(2)S)(2)(C(12)H(12)N(2))]·2C(3)H(7)NO, the Cd(II) ion lies on a twofold rotation axis, is six-coordinated by N atoms, and displays a trigonal–prismatic geometry arising from the two sulfadiazinate ligands and one 4,4′-dimethyl-2,2′-bipyridine ligand. Both lig...
Autores principales: | , |
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Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
International Union of Crystallography
2012
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3297235/ https://www.ncbi.nlm.nih.gov/pubmed/22412425 http://dx.doi.org/10.1107/S1600536812004412 |
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author | Hossain, G. M. Golzar Amoroso, A. J. |
author_facet | Hossain, G. M. Golzar Amoroso, A. J. |
author_sort | Hossain, G. M. Golzar |
collection | PubMed |
description | In the title compound, [Cd(C(10)H(9)N(4)O(2)S)(2)(C(12)H(12)N(2))]·2C(3)H(7)NO, the Cd(II) ion lies on a twofold rotation axis, is six-coordinated by N atoms, and displays a trigonal–prismatic geometry arising from the two sulfadiazinate ligands and one 4,4′-dimethyl-2,2′-bipyridine ligand. Both ligands are bidentate and coordinate via their N atoms. The O and carbonyl C atoms of the dimethylformamide molecule show disorder and were modelled with two different orientations and with site occupancies of 0.584 (10):0.416 (10). The geometry around the sulfadiazine S atom is distorted tetrahedral. The crystal structure involves N—H⋯O hydrogen bonds which link molecules into a three-dimensional network. Weak C—H⋯O hydrogen bonds are also observed. |
format | Online Article Text |
id | pubmed-3297235 |
institution | National Center for Biotechnology Information |
language | English |
publishDate | 2012 |
publisher | International Union of Crystallography |
record_format | MEDLINE/PubMed |
spelling | pubmed-32972352012-03-12 Bis[4-amino-N-(pyrimidin-2-yl-κN)benzenesulfonamidato-κN](4,4′-dimethyl-2,2′-bipyridine-κ(2) N,N′)cadmium dimethylformamide disolvate Hossain, G. M. Golzar Amoroso, A. J. Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the title compound, [Cd(C(10)H(9)N(4)O(2)S)(2)(C(12)H(12)N(2))]·2C(3)H(7)NO, the Cd(II) ion lies on a twofold rotation axis, is six-coordinated by N atoms, and displays a trigonal–prismatic geometry arising from the two sulfadiazinate ligands and one 4,4′-dimethyl-2,2′-bipyridine ligand. Both ligands are bidentate and coordinate via their N atoms. The O and carbonyl C atoms of the dimethylformamide molecule show disorder and were modelled with two different orientations and with site occupancies of 0.584 (10):0.416 (10). The geometry around the sulfadiazine S atom is distorted tetrahedral. The crystal structure involves N—H⋯O hydrogen bonds which link molecules into a three-dimensional network. Weak C—H⋯O hydrogen bonds are also observed. International Union of Crystallography 2012-02-10 /pmc/articles/PMC3297235/ /pubmed/22412425 http://dx.doi.org/10.1107/S1600536812004412 Text en © Hossain and Amoroso 2012 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
spellingShingle | Metal-Organic Papers Hossain, G. M. Golzar Amoroso, A. J. Bis[4-amino-N-(pyrimidin-2-yl-κN)benzenesulfonamidato-κN](4,4′-dimethyl-2,2′-bipyridine-κ(2) N,N′)cadmium dimethylformamide disolvate |
title | Bis[4-amino-N-(pyrimidin-2-yl-κN)benzenesulfonamidato-κN](4,4′-dimethyl-2,2′-bipyridine-κ(2)
N,N′)cadmium dimethylformamide disolvate |
title_full | Bis[4-amino-N-(pyrimidin-2-yl-κN)benzenesulfonamidato-κN](4,4′-dimethyl-2,2′-bipyridine-κ(2)
N,N′)cadmium dimethylformamide disolvate |
title_fullStr | Bis[4-amino-N-(pyrimidin-2-yl-κN)benzenesulfonamidato-κN](4,4′-dimethyl-2,2′-bipyridine-κ(2)
N,N′)cadmium dimethylformamide disolvate |
title_full_unstemmed | Bis[4-amino-N-(pyrimidin-2-yl-κN)benzenesulfonamidato-κN](4,4′-dimethyl-2,2′-bipyridine-κ(2)
N,N′)cadmium dimethylformamide disolvate |
title_short | Bis[4-amino-N-(pyrimidin-2-yl-κN)benzenesulfonamidato-κN](4,4′-dimethyl-2,2′-bipyridine-κ(2)
N,N′)cadmium dimethylformamide disolvate |
title_sort | bis[4-amino-n-(pyrimidin-2-yl-κn)benzenesulfonamidato-κn](4,4′-dimethyl-2,2′-bipyridine-κ(2)
n,n′)cadmium dimethylformamide disolvate |
topic | Metal-Organic Papers |
url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3297235/ https://www.ncbi.nlm.nih.gov/pubmed/22412425 http://dx.doi.org/10.1107/S1600536812004412 |
work_keys_str_mv | AT hossaingmgolzar bis4aminonpyrimidin2ylknbenzenesulfonamidatokn44dimethyl22bipyridinek2nncadmiumdimethylformamidedisolvate AT amorosoaj bis4aminonpyrimidin2ylknbenzenesulfonamidatokn44dimethyl22bipyridinek2nncadmiumdimethylformamidedisolvate |