Bis{4-bromo-2-[(naphthalen-1-yl­imino)­meth­yl]phenolato-κ(2) N,O}copper(II)

The title complex, [Cu(C(17)H(11)BrNO)(2)], lies on a centre of inversion. The chelating Schiff base anions define a square-planar N(2)O(2) donor set. The nearly perpendicular orientation of the naphthyl residues of the chelate ring [dihedral angle = 82.12 (12)°] precludes the Cu(II) centre from add...

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Autores principales: Shahverdizadeh, Gholam Hossein, Ng, Seik Weng, Tiekink, Edward R. T., Mirtamizdoust, Babak
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2012
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3297236/
https://www.ncbi.nlm.nih.gov/pubmed/22412426
http://dx.doi.org/10.1107/S1600536812004989
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author Shahverdizadeh, Gholam Hossein
Ng, Seik Weng
Tiekink, Edward R. T.
Mirtamizdoust, Babak
author_facet Shahverdizadeh, Gholam Hossein
Ng, Seik Weng
Tiekink, Edward R. T.
Mirtamizdoust, Babak
author_sort Shahverdizadeh, Gholam Hossein
collection PubMed
description The title complex, [Cu(C(17)H(11)BrNO)(2)], lies on a centre of inversion. The chelating Schiff base anions define a square-planar N(2)O(2) donor set. The nearly perpendicular orientation of the naphthyl residues of the chelate ring [dihedral angle = 82.12 (12)°] precludes the Cu(II) centre from additional coordination. In the refinement, the naphthyl rings were found to be disordered over two positions.; the major component has a site occupancy of 0.667 (4).
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spelling pubmed-32972362012-03-12 Bis{4-bromo-2-[(naphthalen-1-yl­imino)­meth­yl]phenolato-κ(2) N,O}copper(II) Shahverdizadeh, Gholam Hossein Ng, Seik Weng Tiekink, Edward R. T. Mirtamizdoust, Babak Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers The title complex, [Cu(C(17)H(11)BrNO)(2)], lies on a centre of inversion. The chelating Schiff base anions define a square-planar N(2)O(2) donor set. The nearly perpendicular orientation of the naphthyl residues of the chelate ring [dihedral angle = 82.12 (12)°] precludes the Cu(II) centre from additional coordination. In the refinement, the naphthyl rings were found to be disordered over two positions.; the major component has a site occupancy of 0.667 (4). International Union of Crystallography 2012-02-10 /pmc/articles/PMC3297236/ /pubmed/22412426 http://dx.doi.org/10.1107/S1600536812004989 Text en © Shahverdizadeh et al. 2012 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Shahverdizadeh, Gholam Hossein
Ng, Seik Weng
Tiekink, Edward R. T.
Mirtamizdoust, Babak
Bis{4-bromo-2-[(naphthalen-1-yl­imino)­meth­yl]phenolato-κ(2) N,O}copper(II)
title Bis{4-bromo-2-[(naphthalen-1-yl­imino)­meth­yl]phenolato-κ(2) N,O}copper(II)
title_full Bis{4-bromo-2-[(naphthalen-1-yl­imino)­meth­yl]phenolato-κ(2) N,O}copper(II)
title_fullStr Bis{4-bromo-2-[(naphthalen-1-yl­imino)­meth­yl]phenolato-κ(2) N,O}copper(II)
title_full_unstemmed Bis{4-bromo-2-[(naphthalen-1-yl­imino)­meth­yl]phenolato-κ(2) N,O}copper(II)
title_short Bis{4-bromo-2-[(naphthalen-1-yl­imino)­meth­yl]phenolato-κ(2) N,O}copper(II)
title_sort bis{4-bromo-2-[(naphthalen-1-yl­imino)­meth­yl]phenolato-κ(2) n,o}copper(ii)
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3297236/
https://www.ncbi.nlm.nih.gov/pubmed/22412426
http://dx.doi.org/10.1107/S1600536812004989
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