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{4-Bromo-2-[(2-{(ethylsulfanyl)[(2-oxidobenzylidene-κO)amino-κN]methylidene}hydrazinylidene-κN (1))methyl]phenolato-κO}(butan-2-ol-κO)dioxidouranium(VI)
The U(VI) cation in the title complex, [U(C(17)H(14)BrN(3)O(2)S)O(2)(C(4)H(10)O)], exists within a distorted pentagonal–bipyramidal geometry, where the oxide atoms occupy the axial positions [O—U—O = 179.8 (3)°] and the pentagonal plane is defined by the N(2)O(2) atoms of the tetradentate Schiff...
Autores principales: | , , , |
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Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
International Union of Crystallography
2012
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3297237/ https://www.ncbi.nlm.nih.gov/pubmed/22412427 http://dx.doi.org/10.1107/S1600536812005077 |
Sumario: | The U(VI) cation in the title complex, [U(C(17)H(14)BrN(3)O(2)S)O(2)(C(4)H(10)O)], exists within a distorted pentagonal–bipyramidal geometry, where the oxide atoms occupy the axial positions [O—U—O = 179.8 (3)°] and the pentagonal plane is defined by the N(2)O(2) atoms of the tetradentate Schiff base ligand and the O atom of the 2-butanol molecule. In the crystal, centrosymmetric aggregates are formed via pairs of hydroxy–phenolate O—H⋯O hydrogen bonds. The azomethine C=N atoms, the ethylthiolyl group, the 2-butanol molecule and Br atom are disordered over two positions in a 0.627 (3):0.373 (3) ratio. |
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