{4-Bromo-2-[(2-{(ethyl­sulfan­yl)[(2-oxidobenzyl­idene-κO)amino-κN]methylidene}hydrazinyl­idene-κN (1))meth­yl]phenolato-κO}(butan-2-ol-κO)dioxidouranium(VI)

The U(VI) cation in the title complex, [U(C(17)H(14)BrN(3)O(2)S)O(2)(C(4)H(10)O)], exists within a distorted penta­gonal–bipyramidal geometry, where the oxide atoms occupy the axial positions [O—U—O = 179.8 (3)°] and the penta­gonal plane is defined by the N(2)O(2) atoms of the tetra­dentate Schiff...

Descripción completa

Detalles Bibliográficos
Autores principales: Takjoo, Reza, Ahmadi, Mehdi, Ng, Seik Weng, Tiekink, Edward R. T.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2012
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3297237/
https://www.ncbi.nlm.nih.gov/pubmed/22412427
http://dx.doi.org/10.1107/S1600536812005077
_version_ 1782225845958475776
author Takjoo, Reza
Ahmadi, Mehdi
Ng, Seik Weng
Tiekink, Edward R. T.
author_facet Takjoo, Reza
Ahmadi, Mehdi
Ng, Seik Weng
Tiekink, Edward R. T.
author_sort Takjoo, Reza
collection PubMed
description The U(VI) cation in the title complex, [U(C(17)H(14)BrN(3)O(2)S)O(2)(C(4)H(10)O)], exists within a distorted penta­gonal–bipyramidal geometry, where the oxide atoms occupy the axial positions [O—U—O = 179.8 (3)°] and the penta­gonal plane is defined by the N(2)O(2) atoms of the tetra­dentate Schiff base ligand and the O atom of the 2-butanol mol­ecule. In the crystal, centrosymmetric aggregates are formed via pairs of hy­droxy–phenolate O—H⋯O hydrogen bonds. The azomethine C=N atoms, the ethyl­thiolyl group, the 2-butanol mol­ecule and Br atom are disordered over two positions in a 0.627 (3):0.373 (3) ratio.
format Online
Article
Text
id pubmed-3297237
institution National Center for Biotechnology Information
language English
publishDate 2012
publisher International Union of Crystallography
record_format MEDLINE/PubMed
spelling pubmed-32972372012-03-12 {4-Bromo-2-[(2-{(ethyl­sulfan­yl)[(2-oxidobenzyl­idene-κO)amino-κN]methylidene}hydrazinyl­idene-κN (1))meth­yl]phenolato-κO}(butan-2-ol-κO)dioxidouranium(VI) Takjoo, Reza Ahmadi, Mehdi Ng, Seik Weng Tiekink, Edward R. T. Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers The U(VI) cation in the title complex, [U(C(17)H(14)BrN(3)O(2)S)O(2)(C(4)H(10)O)], exists within a distorted penta­gonal–bipyramidal geometry, where the oxide atoms occupy the axial positions [O—U—O = 179.8 (3)°] and the penta­gonal plane is defined by the N(2)O(2) atoms of the tetra­dentate Schiff base ligand and the O atom of the 2-butanol mol­ecule. In the crystal, centrosymmetric aggregates are formed via pairs of hy­droxy–phenolate O—H⋯O hydrogen bonds. The azomethine C=N atoms, the ethyl­thiolyl group, the 2-butanol mol­ecule and Br atom are disordered over two positions in a 0.627 (3):0.373 (3) ratio. International Union of Crystallography 2012-02-10 /pmc/articles/PMC3297237/ /pubmed/22412427 http://dx.doi.org/10.1107/S1600536812005077 Text en © Takjoo et al. 2012 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Takjoo, Reza
Ahmadi, Mehdi
Ng, Seik Weng
Tiekink, Edward R. T.
{4-Bromo-2-[(2-{(ethyl­sulfan­yl)[(2-oxidobenzyl­idene-κO)amino-κN]methylidene}hydrazinyl­idene-κN (1))meth­yl]phenolato-κO}(butan-2-ol-κO)dioxidouranium(VI)
title {4-Bromo-2-[(2-{(ethyl­sulfan­yl)[(2-oxidobenzyl­idene-κO)amino-κN]methylidene}hydrazinyl­idene-κN (1))meth­yl]phenolato-κO}(butan-2-ol-κO)dioxidouranium(VI)
title_full {4-Bromo-2-[(2-{(ethyl­sulfan­yl)[(2-oxidobenzyl­idene-κO)amino-κN]methylidene}hydrazinyl­idene-κN (1))meth­yl]phenolato-κO}(butan-2-ol-κO)dioxidouranium(VI)
title_fullStr {4-Bromo-2-[(2-{(ethyl­sulfan­yl)[(2-oxidobenzyl­idene-κO)amino-κN]methylidene}hydrazinyl­idene-κN (1))meth­yl]phenolato-κO}(butan-2-ol-κO)dioxidouranium(VI)
title_full_unstemmed {4-Bromo-2-[(2-{(ethyl­sulfan­yl)[(2-oxidobenzyl­idene-κO)amino-κN]methylidene}hydrazinyl­idene-κN (1))meth­yl]phenolato-κO}(butan-2-ol-κO)dioxidouranium(VI)
title_short {4-Bromo-2-[(2-{(ethyl­sulfan­yl)[(2-oxidobenzyl­idene-κO)amino-κN]methylidene}hydrazinyl­idene-κN (1))meth­yl]phenolato-κO}(butan-2-ol-κO)dioxidouranium(VI)
title_sort {4-bromo-2-[(2-{(ethyl­sulfan­yl)[(2-oxidobenzyl­idene-κo)amino-κn]methylidene}hydrazinyl­idene-κn (1))meth­yl]phenolato-κo}(butan-2-ol-κo)dioxidouranium(vi)
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3297237/
https://www.ncbi.nlm.nih.gov/pubmed/22412427
http://dx.doi.org/10.1107/S1600536812005077
work_keys_str_mv AT takjooreza 4bromo22ethylsulfanyl2oxidobenzylidenekoaminoknmethylidenehydrazinylidenekn1methylphenolatokobutan2olkodioxidouraniumvi
AT ahmadimehdi 4bromo22ethylsulfanyl2oxidobenzylidenekoaminoknmethylidenehydrazinylidenekn1methylphenolatokobutan2olkodioxidouraniumvi
AT ngseikweng 4bromo22ethylsulfanyl2oxidobenzylidenekoaminoknmethylidenehydrazinylidenekn1methylphenolatokobutan2olkodioxidouraniumvi
AT tiekinkedwardrt 4bromo22ethylsulfanyl2oxidobenzylidenekoaminoknmethylidenehydrazinylidenekn1methylphenolatokobutan2olkodioxidouraniumvi

Ejemplares similares