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{4,4′-Dibromo-6,6′-dimeth­oxy-2,2′-[1,2-phenyl­enebis(nitrilo­methanylyl­idene)]-κ(4) O (1),N,N′,O (1′)}nickel(II)

In the title complex, [Ni(C(22)H(16)Br(2)N(2)O(4))], the Ni(II) ion is coordinated by two N atoms and two O atoms of a tetra­dentate Schiff base ligand, forming a slightly distorted square-planar coordination environment. The dihedral angle between the two bromo-substituted benzene rings is 10.1 (3)...

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Detalles Bibliográficos
Autor principal: Sun, Yongling
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2012
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3297239/
https://www.ncbi.nlm.nih.gov/pubmed/22412429
http://dx.doi.org/10.1107/S1600536812004321
Descripción
Sumario:In the title complex, [Ni(C(22)H(16)Br(2)N(2)O(4))], the Ni(II) ion is coordinated by two N atoms and two O atoms of a tetra­dentate Schiff base ligand, forming a slightly distorted square-planar coordination environment. The dihedral angle between the two bromo-substituted benzene rings is 10.1 (3)°.