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{4,4′-Dibromo-6,6′-dimethoxy-2,2′-[1,2-phenylenebis(nitrilomethanylylidene)]-κ(4) O (1),N,N′,O (1′)}nickel(II)
In the title complex, [Ni(C(22)H(16)Br(2)N(2)O(4))], the Ni(II) ion is coordinated by two N atoms and two O atoms of a tetradentate Schiff base ligand, forming a slightly distorted square-planar coordination environment. The dihedral angle between the two bromo-substituted benzene rings is 10.1 (3)...
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Formato: | Online Artículo Texto |
Lenguaje: | English |
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International Union of Crystallography
2012
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Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3297239/ https://www.ncbi.nlm.nih.gov/pubmed/22412429 http://dx.doi.org/10.1107/S1600536812004321 |
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author | Sun, Yongling |
author_facet | Sun, Yongling |
author_sort | Sun, Yongling |
collection | PubMed |
description | In the title complex, [Ni(C(22)H(16)Br(2)N(2)O(4))], the Ni(II) ion is coordinated by two N atoms and two O atoms of a tetradentate Schiff base ligand, forming a slightly distorted square-planar coordination environment. The dihedral angle between the two bromo-substituted benzene rings is 10.1 (3)°. |
format | Online Article Text |
id | pubmed-3297239 |
institution | National Center for Biotechnology Information |
language | English |
publishDate | 2012 |
publisher | International Union of Crystallography |
record_format | MEDLINE/PubMed |
spelling | pubmed-32972392012-03-12 {4,4′-Dibromo-6,6′-dimethoxy-2,2′-[1,2-phenylenebis(nitrilomethanylylidene)]-κ(4) O (1),N,N′,O (1′)}nickel(II) Sun, Yongling Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the title complex, [Ni(C(22)H(16)Br(2)N(2)O(4))], the Ni(II) ion is coordinated by two N atoms and two O atoms of a tetradentate Schiff base ligand, forming a slightly distorted square-planar coordination environment. The dihedral angle between the two bromo-substituted benzene rings is 10.1 (3)°. International Union of Crystallography 2012-02-10 /pmc/articles/PMC3297239/ /pubmed/22412429 http://dx.doi.org/10.1107/S1600536812004321 Text en © Yongling Sun 2012 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
spellingShingle | Metal-Organic Papers Sun, Yongling {4,4′-Dibromo-6,6′-dimethoxy-2,2′-[1,2-phenylenebis(nitrilomethanylylidene)]-κ(4) O (1),N,N′,O (1′)}nickel(II) |
title | {4,4′-Dibromo-6,6′-dimethoxy-2,2′-[1,2-phenylenebis(nitrilomethanylylidene)]-κ(4)
O
(1),N,N′,O
(1′)}nickel(II) |
title_full | {4,4′-Dibromo-6,6′-dimethoxy-2,2′-[1,2-phenylenebis(nitrilomethanylylidene)]-κ(4)
O
(1),N,N′,O
(1′)}nickel(II) |
title_fullStr | {4,4′-Dibromo-6,6′-dimethoxy-2,2′-[1,2-phenylenebis(nitrilomethanylylidene)]-κ(4)
O
(1),N,N′,O
(1′)}nickel(II) |
title_full_unstemmed | {4,4′-Dibromo-6,6′-dimethoxy-2,2′-[1,2-phenylenebis(nitrilomethanylylidene)]-κ(4)
O
(1),N,N′,O
(1′)}nickel(II) |
title_short | {4,4′-Dibromo-6,6′-dimethoxy-2,2′-[1,2-phenylenebis(nitrilomethanylylidene)]-κ(4)
O
(1),N,N′,O
(1′)}nickel(II) |
title_sort | {4,4′-dibromo-6,6′-dimethoxy-2,2′-[1,2-phenylenebis(nitrilomethanylylidene)]-κ(4)
o
(1),n,n′,o
(1′)}nickel(ii) |
topic | Metal-Organic Papers |
url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3297239/ https://www.ncbi.nlm.nih.gov/pubmed/22412429 http://dx.doi.org/10.1107/S1600536812004321 |
work_keys_str_mv | AT sunyongling 44dibromo66dimethoxy2212phenylenebisnitrilomethanylylidenek4o1nno1nickelii |