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catena-Poly[[(isoquinoline-κN)(triphenylphospane-κP)copper(I)]-μ-thiocyanato-κ(2) N:S]
In the title coordination compound, [Cu(NCS)(C(9)H(7)N)(C(18)H(15)P)](n), the Cu(I) atom is tetrahedrally coordinated by one N atom from an isoquinoline ligand, one P atom from a triphenylphospane ligand, and one N and one S atom from two thiocyanate anions. The thiocyanide anions bridge the Cu(...
| Autores principales: | , , , , |
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| Formato: | Online Artículo Texto |
| Lenguaje: | English |
| Publicado: |
International Union of Crystallography
2012
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| Materias: | |
| Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3297240/ https://www.ncbi.nlm.nih.gov/pubmed/22412430 http://dx.doi.org/10.1107/S1600536812004837 |
| _version_ | 1782225846632710144 |
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| author | Li, Jian-Bao Zhou, Li-Li Wu, Man-Hua Jin, Qiong-Hua Zhang, Cun-Lin |
| author_facet | Li, Jian-Bao Zhou, Li-Li Wu, Man-Hua Jin, Qiong-Hua Zhang, Cun-Lin |
| author_sort | Li, Jian-Bao |
| collection | PubMed |
| description | In the title coordination compound, [Cu(NCS)(C(9)H(7)N)(C(18)H(15)P)](n), the Cu(I) atom is tetrahedrally coordinated by one N atom from an isoquinoline ligand, one P atom from a triphenylphospane ligand, and one N and one S atom from two thiocyanate anions. The thiocyanide anions bridge the Cu(I) atoms into a chain along [100]. π–π interactions between the pyridine and benzene rings of the isoquinoline ligands connect the chains [centroid-to-centroid distance = 3.722 (3) Å]. |
| format | Online Article Text |
| id | pubmed-3297240 |
| institution | National Center for Biotechnology Information |
| language | English |
| publishDate | 2012 |
| publisher | International Union of Crystallography |
| record_format | MEDLINE/PubMed |
| spelling | pubmed-32972402012-03-12 catena-Poly[[(isoquinoline-κN)(triphenylphospane-κP)copper(I)]-μ-thiocyanato-κ(2) N:S] Li, Jian-Bao Zhou, Li-Li Wu, Man-Hua Jin, Qiong-Hua Zhang, Cun-Lin Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the title coordination compound, [Cu(NCS)(C(9)H(7)N)(C(18)H(15)P)](n), the Cu(I) atom is tetrahedrally coordinated by one N atom from an isoquinoline ligand, one P atom from a triphenylphospane ligand, and one N and one S atom from two thiocyanate anions. The thiocyanide anions bridge the Cu(I) atoms into a chain along [100]. π–π interactions between the pyridine and benzene rings of the isoquinoline ligands connect the chains [centroid-to-centroid distance = 3.722 (3) Å]. International Union of Crystallography 2012-02-10 /pmc/articles/PMC3297240/ /pubmed/22412430 http://dx.doi.org/10.1107/S1600536812004837 Text en © Li et al. 2012 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
| spellingShingle | Metal-Organic Papers Li, Jian-Bao Zhou, Li-Li Wu, Man-Hua Jin, Qiong-Hua Zhang, Cun-Lin catena-Poly[[(isoquinoline-κN)(triphenylphospane-κP)copper(I)]-μ-thiocyanato-κ(2) N:S] |
| title |
catena-Poly[[(isoquinoline-κN)(triphenylphospane-κP)copper(I)]-μ-thiocyanato-κ(2)
N:S] |
| title_full |
catena-Poly[[(isoquinoline-κN)(triphenylphospane-κP)copper(I)]-μ-thiocyanato-κ(2)
N:S] |
| title_fullStr |
catena-Poly[[(isoquinoline-κN)(triphenylphospane-κP)copper(I)]-μ-thiocyanato-κ(2)
N:S] |
| title_full_unstemmed |
catena-Poly[[(isoquinoline-κN)(triphenylphospane-κP)copper(I)]-μ-thiocyanato-κ(2)
N:S] |
| title_short |
catena-Poly[[(isoquinoline-κN)(triphenylphospane-κP)copper(I)]-μ-thiocyanato-κ(2)
N:S] |
| title_sort | catena-poly[[(isoquinoline-κn)(triphenylphospane-κp)copper(i)]-μ-thiocyanato-κ(2)
n:s] |
| topic | Metal-Organic Papers |
| url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3297240/ https://www.ncbi.nlm.nih.gov/pubmed/22412430 http://dx.doi.org/10.1107/S1600536812004837 |
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